Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original Paper

Jiří Sejkora, Petr Ondruš, Fikar, František Veselovský, Mach, Ananda Gabašová, Radek Škoda, Beran

Supergene minerals at the Huber stock and Schnöd stock deposits, Krásno ore district, the Slavkovský les area, Czech Republic

Journal of the Czech Geological Society, volume 51 (2006), issue 1-2, 57 - 101

DOI: http://doi.org/10.3190/JCGS.989

Anthony, J. W. - Bideaux, R. A. - Bladh, K. W. - Nichols, M. C. (2000): Handbook of mineralogy. Volume IV. Arsenates, phosphates, Vanadates. - 680 pp., Mineral Data Publishing. Tucson, USA.

Artl, T. - Armbruster, T. (1999): Single-rystal X-ray structure refinement of cornwallite, Cu^sub 5^(AsO^sub 4^)^sub 2^(OH)^sub 4^: A comparison with its polymorph cornubite and the PO^sub 4^-analogue pseudomalachite. - N. Jb. Miner. Mh.; 10, 468-480.

Aurivillius, B. (1964): The crystal structure of bismuth oxide fluoride. II. A refinement of the previously published structure. - Acta Chem. Scand.; 18, 1823-1830.
http://doi.org/10.3891/acta.chem.scand.18-1823

Beran, P. (1999): Nerosty cino-wolframových lozisek Slavkovského lesa (Minerals of tin-tungsten deposits from Slavkovský les area). - Regional museum and library in Sokolov. Sokolov, 287 pp. (in Czech).

Beran, P. - Sejkora, J. (2006): The Krásno Sn-W ore district near Horní Slavkov: mining history, topographical, geological and mineralogical characteristics. - Journ. Czech Geol. Soc., 51: 3-42
http://doi.org/10.3190/jcgs.987

Braithwaite, R. S. W. (1983): Infrared spectroscopic analysis of the olivenite-adamite series, and a phosphate substitution in olivenite. - Mineral. Mag.; 47, 51-57.
http://doi.org/10.1180/minmag.1983.047.342.09

Breilhaupt, A. (1849): Die Paragenesis der Mineralien. - Verlag von J. G. Engelhardt, Freiberg.

Buerger, M. J. - Dollase, W. A. - Garaycochea-Wittke. 1. (1967): The structure and composition of the mineral pharmacosiderite. - Zeit. Krist.; 125, 92-108.

Burnham, Ch. W. (1962): Lattice constant refinement. - Carnegie Inst. Washington Year Book 61: 132-135.

Burns, R C. - Hawthorne. F. C. (1995): Rietveld refinement of the crystal structure of olivenite: a twinned monoclinic structure. - Can. Mineral.; 33, 885-888.

Burns, P.C. - Smith, J. V. - Steele, I. M. (2000): Arizona porphyry copper/hydrothermal deposits I. The structure of chenevixite nad luetheite. - Mineral. Mag.; 64, 4, 25-30.
http://doi.org/10.1180/002646100549102

Čech, F. - Jansa, J. - Novák, F. (1976): Kaftkite, FeAsO₄. 3.5 H₂O, a new mineral. - N. Jb. Miner. Mh.; 426-436.

Dolomanova. Y. I. - Sendorova, V. M. - Yanchenko, M. T. (1962): Zavaritskite (BiOF), a new oxifluoride mineral. - Doklady Acad. Nauk SSSR, Ser. geol.; 146, 680-682. (in Russian).

Drozen, J. (1967): Geologické pomery loziska Hubský pen, Výrocní zpráva za rok 1966. - (Annual report for 1966, project "Geology of the Huber stock deposit"). - Nepublik. zpr., Rudné doly n.p. Príbram , Geofond Praha P22656. (in Czech).

Fjellvag, H. - Gronvold, F. - Stolen, S. - Andresen, A. F.- Mueller-Kaefer, R. - Simon, A. (1988): Low-temperature structural distortion in CuS. - Zeit. Krist.; 184, 111-121.

Glückseling, A. M. (1862): Das Vorkommen der Mineralien im Egere Kreise Böhmens. - Versammlung deutscher Ntfr. und Ärzte, Karlsbad.

Golic, L. - Graunar, M. - Lazarini, F. (1982): Catena-di-mue-hydroxomue3-oxo-dibismuth(III) sulfate. - Acta Cryst.; B38, 2881-2883
http://doi.org/10.1107/S056774088201019X

Grice, J. D. (2002): A solution to the crystal structures of bismutite and beyerite. - Can. Mineral.; 40, 693-698.
http://doi.org/10.2113/gscanmin.40.2.693

Hawthorne, F. C. (1976): Hydrogen positions in scorodite. - Acta Cryst.; B32, 2891-2892.
http://doi.org/10.1107/S0567740876009138

Hawthorne, F. C. - Groat, L. E. - Eby, R. K. (1989): Antlerite, Cu₃SO₄(OH)₄, a heteropolyhedral wallpaper structure. - Can. Miner., 27: 205-209.

Hodge, L. C. (1970): Russellite: a second occurrence. - Miner. Mag., 37: 705-707.
http://doi.org/10.1180/minmag.1970.037.290.08

Hoffmann, J. (1903): Historisch - mineralogische Skizze von Schlaggenwald. - Programm der k. u k. Staatsrealschule in Elbogen 1903, Loket.

Klvaňa, J. (1886): Nerosty království Ceského. - (Minerals of the Kingdom of Bohemia). - Uherské Hradistè. (in Czech).

Kniep, R. -Mootz, D. - Vegas, A. (1977): Variscite. - Acta Cryst.; B33, 263-265.
http://doi.org/10.1107/S056774087700329X

Knight, K. S. (1992): The crystal structure of russelite; a re-determination using neutron powder diffraction of synthetic Bi₂WO₆. - Miner. Mag.; 56, 399-409.
http://doi.org/10.1180/minmag.1992.056.384.13

Kolitsch, U. - Slade, P. G. - Tiekink, E. R. T. - Pring, A. (1999): The structure of antimonian dussertite and the role of antimony in oxysalt minerals. - Miner. Mag.; 63, 17-26.
http://doi.org/10.1180/002646199548277

Korbel, P. (1991): Supergene minerals from Horní Slavkov. - Sbor. Nár. Muz. (Praha); B 47, 1-4, 1-24.

Kosatka, M. (1988): Geologická situace centrální cásti Huberova pne na lozisku Krásno (Geological situation of central part of Hubs' stock in Krásno deposit). - Msc. these, Faculty of Science, Charles University, Prague, (in Czech).

Kratochvil, J. (1957-1964): Topografická mineralogie Cech VI (S-T). - [Topographic mineralogy of Bohemia VI (part S-T)]. - Nakladatelství CSAV Praha. (in Czech).

Krejčí, J. (1855): O prahorách ceskích. - (On ancient rock formations in Bohemia). - Ziva, 3, Praha. (in Czech).

Locock, A. J. - Burns, P. C. (2003): Crystal structures and synthesis of the copper-dominant members of the autunite and meta-autunite groups: torbernite, zeunerite, metatorbernite and metazeunerite. - Can. Mineral., 41: 489-502.
http://doi.org/10.2113/gscanmin.41.2.489

Losos, Z. - Beran, A. (2004): OH defects in cassiterite. - Mineral. Petrol., 81:219-234.
http://doi.org/10.1007/s00710-004-0040-x

Mach, Z. (1979): Chalkosiderit a Barium-farmakosiderit z Krásna u Horního Slavkova. (Chalcosiderite and Barium-pharmacosiderite from Krásno near Horní Slavkov). - Cas. Mineral. Geol., 79: 90-91 (in Czech).

Mach, Z. - Korbel, P. (1990): Sekundárni minerely z Huberova pne u Krásna u Horního Slavkova. - (Secondary minerals from the Huber stock at Krásno near Horní Slavkov). - Príroda Karlovarska I., Karlovarské muzeum v Karlových Varech, (in Czech).

Mellini. M. - Merlino, S. (1979): Posnjakite, (Cu₄(OH)₆(H₂O)O) octahedral sheets in its structure. - Zeit. Krist.; 149, 249-257.

Menchetti, S. - Sabelli, C. (1976): Crystal chemistry of the alunite series: crystal structure refinement of alunite and synthetic jarosite. - N. Jb. Miner. Mh.; 406-417.

Mereiter, K. - Preisinger, A.(1986): Kristallstrukturdaten der Wismutminerale Atelestit, Mixit und Pucherit. - Öster. Akad, Wissen., Math.-Naturwissen. Klasse, Sitzungsberichte, 123: 79-81.

Merlino. S. - Perchiazzi, N. - Franco. D. (2003): Brochantite, Cu₄SO₄(OH)₆: OD character, polytypism and crystal structures. - Eur. J. Miner.; 15, 267-275.

Moore, P. B. - Ito, J. (1974): I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species. II. Redefiniton of overite, an isotype of segelerite. III. Isotypy of robertsite, mitridatite and arseniosiderite. - Amer. Mineral.; 59, 48-59.

Mrázek. Z. (1981): Crandallit a mixit z Horniho Slavkova. (Crandallite and mixite from Horni Slavkov). - Sbor. Vys. sk. chem. techn., G20, 43-47. (in Czech).

Mutter, G. - Eysel, W. - Greis, O. - Schmetzer, K. (1984): Crystal chemistry of natural and ion-exchanged pharmacosiderites. - N. Jb. Miner. Mh., 4, 183-192.

Natta, G. -Baccaredda, M. (1933): Tetrossidodi antimonioeantimoniati. -Zeit. Krist., 85:, 271-296.

Neder. R. B. - Burghammer, M. - Grasl. T. - Schulz, H. - Bram. A. - Fiedler, S. (1999): Refinement of the kaolinite structure from singlecrystal synchrotron data. - Clays and Clay Minerals; 47, 487-494.
http://doi.org/10.1346/CCMN.1999.0470411

Ondruš, P. (1993): ZDS - A computer program for analysis of X-ray powder diffraction patterns. - Materials Science Forum, 133-136: 297-300, EPDIC-2. Enchede.
http://doi.org/10.4028/www.scientific.net/MSF.133-136.297

Ondruš, P. -Jansa, J. -Novák, F. - Vavřín, I. (1994): Origin and relationships of bismuth secondary minerals at the Moldava deposit in the Krusné hory Mts. - Vest. Ces. geol. Úst., 69: 79-86.

Ondruš, P. -Skála, R. (1997): New quasi-emirical channel Search/Match algorithm for ICDD PDF2 Database: A tool for qualitative phase analysis integrated in the ZDS-System software package for X-ray powder diffraction analysis - Fifth European Powder Diffraction Conference EPDIC-5, 193. Parma.

Pavlů, D. ( 1984): Djurleite and stanoidite from the tin-tungsten deposit at Krâsno nad Teplou (Czechoslovakia). - Vest. Ústf. Úst. geol., 59: 351-354.

Peacor, D. R. - Dunn, P. J. (1985): Sodium-pharmacosiderite a new analog of pharmacosiderite from Australia and new occurrences of Barium-pharmacosiderite. - Min. Record, 16: 121-124.

Philibert, J. A. (1963): A metod for calculation of the absorption correction in electron probe microanalysis. - In: H. R. Petee - V. E. Colser -A. Engstrom (edit.): X-ray Optics and X-ray Microanal. Academic Prew., New York, London.
http://doi.org/10.1016/B978-1-4832-3322-2.50039-1

Pouchou, J. L. -Pichoir, F. (1985): "PAP" procedure for improved quantitative microanalysis. - Microbeam Analysis, 20: 104-105.

Povondra, P. -Řídkošil, T. (1980): Brochantit z Piesku a Lubietové u Banské Bystrice (Brochantite from Piesky and Lubietová near Banská Bystrica). ~ Acta Univ. Carol. - Geol., 1-2, 1-8. Praha (in Czech).

Rae. A. D. - Thompson. J. G. - Withers, R. L. (1991): Structure refinement of commensurately modulated bismuth tungstate Bi₂WO₆. - Acta Cryst.; B47, 870-881.

Restori, R. - Schwarzenbach, D. (1986): Charge density in Cuprite, Cu₂O. - Acta Cryst.; B42, 201-208.
http://doi.org/10.1107/S0108768186098336

Rezek, K. (1987): Varlamoffite from the locality Bajan Obo in Mongolia (Varlamoffit z lokality Bajan Obo v Mongolsku). - Vest. Ústf. Úst. geol, 62:291-295. (in Czech).

Rodríguez-Carvajal, J. (2005): Computer Program FullProf, ver. December 2005. - Laboratoire Leon Bril-louin (CEA-CNRS), France.

Rosický: V. ( 1916): Topaz ze Slavkova v Cechách. - (Topaz from Slavkov in Bohemia). - Rozpr. Ces. Akad, Vedy Sloves. Umení, Tr. II., 25: 7, Praha. (in Czech).

Sabelli. C. (1980): The crystal structure of chalcophyllite. - Zeit. Krist.; 151, 129-140.

Schmetzer. K. - Horn, W. - Bank, H. (1981): Alumopharmakosiderit, KAl₄(OH)₄(AsO₄)₃] . 6,5 H₂O, ein neues Mineral. - N. Jb. Miner. Mh., 3, 97-102.

Sejkora, J. (1992): Mineralogie oxidických fázi s bismutem (Mineralogy of oxygen-containing bismuth phases). - Msc. these, 154 pp., Faculty of Science, Charles University, Prague, (in Czech).

Sejkora, J. - Škoda, R. - Ondruš, P. (2006d): New naturally occurring mineral phases from the area Krásno - Horní Slavkov, western Bohemia, Czech Republic. - Journ. Czech Geol. Soc., 51: 159-188
http://doi.org/10.3190/jcgs.992

Sejkora, J. - Škoda, R. - Ondrus, P. - Beran, P. - Süsser, C. (2006c): Mineralogy of phosphate accumulations in the Huber stock, Krásno ore district, Slavkovský les area, Czech Republic. - Joum. Czech Geol. Soc., 51: 103-147
http://doi.org/10.3190/jcgs.990

Sidorenko, G. A.- Komvushkin, V.V.- Gorshkov, A. I.- Rudnizkaya, E. S. - Dikov, J. P.- Kauchova, L. V. - Sivzov, A. V. ( 1993): On the mineral nature of varlamoffite. - Miner. Zhum., 15: 94-101 (in Russian).

Sieber. N. H. W. - Tillmanns, E. - Hofmeister, W. (1987a): Structure of hentschelite, CuFe₂(PO₄)₂(OH)₂, a new member of the lazulite group. - Acta Cryst.; C43, 1855-1857.
http://doi.org/10.1107/S0108270187089868

Sieber, N. H. W. - Tillmanns. E. - Medenbach, O. (1987b): Hentschelite, CuFe₂(PO₄)₂(OH)₂, a new member of the lazulite group, and reichenbachite Cu₅(PO₄)₂(OH₄), a polymorph of pseudomalachite, two new copper phosphate minerals from Reichenbach, Germany. - Amer. Mineral.; 72, 404-408.
http://doi.org/10.1107/S0108270187089868

Sharko, E. D. (1970): On the mineral nature and properties of "varlamoffite" (product of stannite oxidation). - Zap. Vsesojuz. miner. Obsch., 99: 232-246.

Shoemaker, G. L. -Anderson,J. B. -Kostiner, E. (1977): Refinement of the crystal structure of pseudomalachite. - Amer. Mineral.; 62,1042-1048.

Slavíček, P. ( 1984): Chalkantit z Krásna nad Teplou a z Telnice v Krusných horách. - (Chalcanthite from Krásno nad Teplou and from Telnice in the Krusné hory Mts). -Cas. Mineral. Geol., 84: 316. (in Czech).

Slavík. F. (1903): Mové nálezy minerálu u Slavkova. - (New mineral finds near Slavkov). - Rozpr. Ces. Akad., Vedy Sloves. Umeni, Tr. II., 12: 35, Praha. (in Czech).

Stanley, C. J. - Roberts, A. C- Harris, D. C. - Criddle, A. J.- Symanski J. T. (1992): Cannonite, Bi₂O(OH)₂SO₄, a new mineral from Marysvale, Utah, USA. - Mineral. Mag.; 56, 605-609.
http://doi.org/10.1180/minmag.1992.056.385.17

Tad, A. - Blüml, A. (1974): Mineralogický výzkum sekundárních nerostù loziska Krásno. - (Mineralogical research of secondary minerals from the Krásno deposit). - Nepublik. zpr., archiv Rudných dolu s.p. Príbram. (in Czech).

Taylor, R. G. - Morgan, W. R. - Phillips. D.N.(1970): On the occurrence of varlamoffite at the Sardine tin mine. North Queensland, Australia. - Miner. Mag., 37: 624-628.
http://doi.org/10.1180/minmag.1970.037.289.14

Vilminot, S. - Richard-Plouet, M. - Andre, G. - Swierczynski, D. Guillot, M. - Bouree-Vigneron, F. - Drillon, M. (2003): Magnetic structure and properties of Cu₃(OH)₄SO₄ made of triple chains of spins s = 1/2. - Journal Solid State Chem.; 170, 255-264.
http://doi.org/10.1016/S0022-4596(02)00081-6

Yakubovich, O. V.-Mel'nikov, O. K. (1993): Libethenite, Cu₂(PO₄)(OH): synthesis, crystal structure refinement, comparative crystal chemistry. - Kristallografiya; 38, 1, 63-70. (in Russian).

Yeh, C.-Lu, Z.W. -Froyen,S.-Zunger,A.(1992): zinc-blende-Wurtzile polytypism in semiconductors. - Phys. Review, Serie 3.B - Conden. Matter; 46, 10086-10097.

Zepharovich, V. (1857): Mineralogisches Lexikon für das Kaiserthum Österreich, Wien.

Zigan, F. -Joswig. W. -Schuster, H. U. - Mason, S. A. (1977): Verfeinerung der Struktur von Malachit, Cu₂(OH)₂CO₃, durch Neutronenbeugung. - Zeit. Krist.; 145,412-426.

Zigan, F. - Schuster, H. D. (1972): Verfeinerung der Struktur von Azurit, CU ₃(OH)₂(CO₃)₂, durch Neutronenbeugung. - Zeit. Krist.; 135, 416-436.