Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Review paper

Miroslav Štemprok

Drill hole CS-1 penetrating the Cínovec/Zinnwald granite cupola (Czech Republic): an A-type granite with important hydrothermal mineralization

Journal of Geosciences, volume 61 (2016), issue 4, 395 - 423

DOI: http://doi.org/10.3190/jgeosci.226

Abushkevich VS, Syritso LF (2007) Isotopic-geochemical Model of the Li-F granites of the Khangilai Ore Knot in Eastern Transbaikalia. Nauka, Sankt-Petersburg, pp 1-147 (in Russian)

Ackerman L, Haluzová E, Creaser RA, Pašava J, Veselovský F, Breiter K, Erban V, Drábek M (in print) Temporal evolution of mineralization events in the Bohemian Massif inferred from Re-Os geochronology of molybdenite. Miner Depos, doi: 10.1007/s00126-016-0685-5
http://doi.org/10.1007/s00126-016-0685-5

Ballouard C, Poujol M, Boulvais P, Branquet Y, Tartese R, Vigneresse J-L (2016) Nb-Ta fractionation in peraluminous granites: a marker of the magmatic-hydrothermal transition. Geology 44: 231-234
http://doi.org/10.1130/G37475.1

Beus AA, Zalashkova NY (1964) Postmagmatic high-temperature metasomatic processes in granitic rocks. Int Geol Rev 6: 668-681
http://doi.org/10.1080/00206816409473947

Beus AA, Severov EA, Sitnin AA (1962). Albitized and Greisenized Granites (Apogranites). Nauka, Moscow, pp 1-195 (in Russian)

Bonin B (2007) A-type granites and related rocks: evolution of a concept, problems and prospects. Lithos 97: 1-29
http://doi.org/10.1016/j.lithos.2006.12.007

Bowden P, Kinnaird JA, Abaa SI, Ike EC, Turaki UM (1984) Geology and mineralization of the Nigerian anorogenic ring complexes. Geol Jb B 56: 3-65

Breiter K (2012) Nearly contemporaneous evolution of the A-type and S-type fractionated granites in the Krušné hory/Erzgebirge Mts., Central Europe. Lithos 151: 105-121
http://doi.org/10.1016/j.lithos.2011.09.022

Breiter K, Škoda R (2012) Vertical zonality of fractionated granite plutons reflected in zircon chemistry: the Cínovec A-type versus the Beauvoir S-type. Geol Carpath 63: 383-398
http://doi.org/10.2478/v10096-012-0030-6

Breiter K, Ďurišová J, Korbelová,Vaňková M, Vašinová M (2015a) Quartz, micas and ore minerals as expression of vertical zoning in the drill hole CS-1. In: Breiter K (ed) Workshop on the Vertical Zoning of Ore-bearing Granite Plutons in Light of Modern Analytical Methods, October 6, 2015, Abstracts. Prague , pp 7-9 (in Czech)

Breiter K, Hrstka T, Rambousek P, Knésl I (2015b) Basis for a new model of ore-bearing process at Cínovec. In: Breiter K (ed) Workshop on the Vertical Zoning of Ore-bearing Granite Plutons in Light of Modern Analytical Methods, October 6, 2015, Abstracts. Prague, pp 15-18 (in Czech)

Burnham CW (1979) Magmas and hydrothermal fluids. In: Barnes HL (ed) Geochemistry of Hydrothermal Ore Deposits. John Wiley and Sons, New York, pp 63-118

Chappell BW, White AJR (1974) Two contrasting granite types. Pacific Geol 8: 173-174

Chappell BW, Hine R (2006) The Cornubian Batholith: an example of magmatic fractionation on a crustal scale. Resour Geol 56: 203-244
http://doi.org/10.1111/j.1751-3928.2006.tb00281.x

Chlupáčová M (2015) Densities, porosity and radioactivity of the granites of the Cínovec-Krupka granite elevation. In: Breiter K (ed) Workshop on the Vertical Zoning of Ore-bearing Granite Plutons in Light of Modern Analytical Methods, October 6, 2015, Abstracts. Prague , pp 11-12 (in Czech)

Chlupáčová M, Štemprok M (1965) Distribution of densities of granitic rocks in the Cínovec Massif. Věst ÚÚG 40: 1-17 (in Czech)

Cobbing EJ, Pitfield PEJ, Darbyshire DPF, Mallick DIJ (1992) The Granites of the South-East Asian Tin Belt. British Geological Survey Overseas Memoirs 10: pp 1-369

Cocherie A, Johan V, Rossi P, Štemprok M (1991) Trace element variation and tetrad effect studied in a Variscan lithium albite granite. Case of the Cínovec granite (Czechoslovakia). In: Pagel M, Leroy JL (eds) Source, Transport and Deposition of Metals. Balkema, Rotterdam, pp 745-749

Cuney M, Barbey P (2014) Uranium, rare metals, and granulite-facies metamorphism. Geosci Frontiers 5: 729-745
http://doi.org/10.1016/j.gsf.2014.03.011

Cuney M, Marignac C, Weisbrod A (1992) The Beauvoir topaz-lepidolite albite granites (Massif Central, France): the disseminated magmatic Sn-Li-Ta-Nb-Be mineralization. Econ Geol 87: 1766-1794
http://doi.org/10.2113/gsecongeo.87.7.1766

Čabla V, Tichý K (1965) New results of geological exploration at Cínovec. Sbor geol Ved, Lož Geol Mineral 5: 107-129 (in Czech)

Černý P, Blevin P L, Cuney M, London D (2005) Granite related ore deposits. Econ Geol 10^th Ann Vol: 337-370
http://doi.org/10.5382/AV100.12

Dolejš D, Štemprok M (2001) Magmatic and hydrothermal evolution of Li-F granites, Cínovec and Krásno intrusions, Krušne hory Batholith, Czech Republic. Bull Czech Geol Surv 76: 77-99

Dolejš D, Bendl J, Štemprok M (2016) Rb-Sr isotopic composition of granites in the Western Krušné hory/Erzgebirge Pluton, Central Europe: record of variation in source lithology, mafic magma input and postmagmatic hydrothermal overprint. Miner Petrol 110: 601-622
http://doi.org/10.1007/s00710-016-0434-6

Dostal J, Kontak DJ, Gerel O, Shellnutt JG, Fayek M (2015). Cretaceous ongonites (topaz-bearing albite-rich microleucogranites) from Ongon Khairkhan, Central Mongolia: products of extreme magmatic fractionation and pervasive metasomatic fluid-rock interaction. Lithos 236-237: 173-189
http://doi.org/10.1016/j.lithos.2015.08.003

Fiala F (1968) Granitoids of the Slavkovský (Císařský) les. Sbor Geol Věd, Geol 14: 93-160

Gerstenberger H (1989) Autometasomatic Rb enrichments in highly evolved granites causing lowered Rb-Sr isochron intercepts. Earth Planet Sci Lett 93: 65-75
http://doi.org/10.1016/0012-821X(89)90184-2

Gottesmann B, Tischendorf G (1978) Klassifikation, Chemismus und Optik trioktaedrischer Glimmer. Z geol Wiss 6: 681-708

Groves DI, Mc Carthy TS (1978) Fractional crystallization and the origin of tin deposits in granitoids. Miner Depos 13: 11-26

Hoefs J (1997) Stable Isotope Geochemistry, 4^th edition. Springer Verlag, Berlin, pp 1-201

Hollocher K (2016) NORM4. macro-enabled version for multiple samples. Accessed on January 10, 2017, at http://minerva.union.edu/hollochk/c_petrology/other_files/norm4.xlsm

Hösel G, Tischendorf G, Wasternack J, Breiter K, Kuschka E, Pälchen W, Rank G, Štemprok M (1997) Erläuterungen zur Karte Mineralische Rohstoffe Erzgebirge-Vogtland/Krušné hory 1: 100 000, Karte 2, Metalle, Fluorit/Baryt - Verbreitung und Auswirkung auf die Umwelt, Landesamt für Umwelt und Geologie, Bergbau in Sachsen, Freiberg, pp1-144

Jacobson RRE, MacLeod WN, Black R (1958) Ring complexes in the Younger granite province of Northern Nigeria. Geological Society, London, Memoirs1: pp 1-71

Johan Z, Johan V (2005) Accessory minerals of the Cínovec (Zinnwald) granite cupola, Czech Republic: indicators of petrogenetic evolution. Mineral Petrol 83: 113-150
http://doi.org/10.1007/s00710-004-0058-0

Johan Z, Strnad L, Johan V (2012) Evaluation of the Cínovec/Zinnwald granite cupola, Czech Republic; composition of feldspars and micas, a clue to the origin of W, Sn mineralization. Canad Mineral 50: 1131-1148
http://doi.org/10.3749/canmin.50.4.1131

Kovalenko VI, Kuzmin MI, Ceden C, Vladykin NV (1970) Lithium-fluorine quartz keratophyre (ongonite): a new variety of subvolcanic magmatic dykes. Ezhegodnik 1969, Siberian Institute of Geochemistry, Irkutsk, pp 85-99 (in Russian)

Lange H, Tischendorf G, Pälchen W, Klemm I, Ossenkopf E (1972) Fortschritte der Metallogenie im Erzgebirge. B. Zur Petrographie und Geochemie der Granite des Erzgebirges. Geologie 21: 491-521

Le Bas MJ, Streckeisen A (1991) The IUGS systematics of igneous rocks. J Geol Soc, London 148: 825-833
http://doi.org/10.1144/gsjgs.148.5.0825

Lehmann B (1982) Metallogeny of tin: magmatic differentiation versus geochemical heritage. Econ Geol 17: 50-59
http://doi.org/10.2113/gsecongeo.77.1.50

Magna T, Janoušek V, Kohút M, Oberli F, Wiechert U (2010) Fingerprinting sources of orogenic plutonic rocks from Variscan belt with lithium isotopes and possible link to subduction-related origin of some A-type granites. Chem Geol 274: 94- 107
http://doi.org/10.1016/j.chemgeo.2010.03.020

Martin RF (2006) A-type granites of crustal origin ultimately results from open-system fenitization type reactions in an extensional environment. Lithos 91: 125-136
http://doi.org/10.1016/j.lithos.2006.03.012

Martin RF, Bowden P (1981) Peraluminous granites produced by rock-fluid interaction in the Rirwain anorogenic ring complex, Nigeria, Mineralogical evidence. Canad Mineral 19: 65-82

Mlčoch B, Skácelová Z (2010) Geometry of the Altenberg-Teplice Caldera revealed by the bore hole and seismic data in the Czech part. J Geosci 55: 217-229
http://doi.org/10.3190/jgeosci.071

Monecke T, Dulski P, Kempe U (2007) Origin of convex tetrads in rare earth element patterns of hydrothermally altered siliceous igneous rocks from the Zinnwald Sn-W deposit, Germany. Geochim Cosmochim Acta 71: 335-353
http://doi.org/10.1016/j.gca.2006.09.010

Oelsner O (1952) Die pegmatitisch-pneumatolytischen Lagerstätten des Erzgebirges mit Ausnahme der Kontaktlagerstätten. Freiberg Forsch H C 9: 1-80

Pirajno F (2009) Hydrothermal Processes and Mineral Systems. Springer and Geological Survey of Western Australia, Perth, pp 1-1250
http://doi.org/10.1007/978-1-4020-8613-7

Pollard P J, Taylor RG, Cuff C (1988) Genetic modeling of greisens-style tin systems. In: Hutchison CS (ed) Geology of Tin Deposits in Asia and the Pacific. Springer, Berlin, pp 59-72
http://doi.org/10.1007/978-3-642-72765-8

Rambousek P, Knésl I (2015) Preliminary statistical evaluation of analytical data from the drill hole CS-1 and its implication for metallogenic development of Sn-W, Li (Nb-Ta) mineralization. In: Breiter K (ed) Workshop on the Vertical Zoning of Ore-bearing Granite Plutons in Light of Modern Analytical Methods, October 6, 2015, Abstracts. Prague, pp 4 (in Czech)

Rieder M, Huka M, Kučerová D, Minařík L, Obermajer J, Povondra P (1970) Chemical composition and physical of lithium-iron micas from the Krušne hory Mts. (Erzgebirge), part A: chemical composition. Contrib Mineral Petrol 27: 131-158
http://doi.org/10.1007/BF00371980

Rieder M, Cavazzini C, D’yakonov YS, Frank-Kamenitskii VA, Gottardi G, Guggenheim S, Koval PV, Müller G, Neiva AMR, Radoslovich EW, Robert J-L, Sassi FP, Takeda H, Weiss Z, Wones DR (1998) Nomenclature of the micas. Canad Mineral 36: 905-912
http://doi.org/10.1346/CCMN.1998.0460513

Romer RL, Kroner U (2015) Phanerozoic tin and tungsten mineralization - tectonic controls on the distribution of enriched protoliths and heat sources for crustal melting. Gondwana Res 31: 60-95

Romer RL, Thomas R, Stein HJ, Rhede D (2007) Dating multiply overprinted Sn-mineralized granites - examples from the Erzgebirge, Germany. Miner Depos 42: 337-359
http://doi.org/10.1007/s00126-006-0114-2

Romer RL, Förster H-J, Štemprok M (2010a) Age constrains for the late-Variscan magmatism in the Altenberg-Teplice Caldera (Eastern Erzgebirge/Krušné hory). Neu Jb Mineral, Abh 187: 289-305
http://doi.org/10.1127/0077-7757/2010/0179

Romer RL, Schneider JC, Linnemann U (2010b) Post-Variscan deformation and hydrothermal mineralization in Saxo-Thuringia and beyond: a geochronological review. In: Linnemann U, Romer RL (eds), Pre-Mesozoic Geology of Saxo-Thuringia: From Cadomian Active Margin to the Variscan Orogen. Schweitzerbartsche Verlag, Stuttgart, pp 347-360

Rub MG, Pavlov VA, Rub AK, Štemprok M., Drábková E, Drábek M (1983) Vertical zoning of the Cínovec granite massif of lithium-fluorine granites (ČSSR). In: Bogatikov OA, Borsuk AM (eds) Correlation of Magmatic Rocks of Czechoslovakia with Some Districts of the USSR. Nauka, Moscow, pp 108-137 (in Russian)

Rub AK, Štemprok M, Rub MG (1997) Tantalum mineralization in rare-metal granites of the Cínovec Massif (Czechia), Dokl Akad Nauk, Geologiya 352: 795-798 (in Russian)

Rub AK, Štemprok M, Rub MG (1998) Tantalum mineralization in the apical part of the Cínovec (Zinnwald) granite stock. Mineral Petrol 63: 199-222
http://doi.org/10.1007/BF01164151

Rudnick RL, Gao S (2003) Composition of the continental crust. In: Rudnick RJ (ed) The Crust. Treatise on Geochemistry, Vol. 3. Elsevier-Pergamon, Oxford, 1-64

Rykl D, Štemprok M (1992) Hydrothermal reactions of NaCl and KCl brines with the Cínovec granite at 400 °C and 50 MPa: an experimental study. Bull Czech Geol Surv 67: 155-168

Seifert T (2009) Metallogeny and Petrogenesis of Lamprophyres in the Mid-European Variscides: Post-collisional Magmatism and Its Relationship to Late-Variscan Ore Forming Processes in the Erzgebirge (Bohemian Massif). IOS Press, Amsterdam, pp 1-304

Seifert T, Pavlova GG (2016) New ⁴⁰Ar/³⁹Ar ages of Sn- and W-polymetallic mineralization in the Erzgebirge/Krušné hory (DE, CZ). In: Goldschmidt Conference Yokohama, June 26 - July 1^st, 2016, Abstracts, pp 2792

Seifert T, Atanasova P, Gutzmer J, Pfänder J (2011) Mineralogy, geochemistry and age of greisen mineralization in the Li-Rb-Cs-Sn-W deposit Zinnwald, Erzgebirge, Germany. Mineral Mag 75 (Suppl): 1833

Seltmann R, Štemprok M (1994) Textural evidence for the existence of two-phase granites in the Younger Intrusive Complex granites of the Krušné hory/Erzgebirge province. J Czech Geol Soc 39: 103-104
Direct link

Seltmann R, Förster H-J, Gottesmann B, Sala M, Wolf D, Štemprok M (1998) The Zinnwald greisen deposit related to post-collisional A-type silicic magmatism in the Variscan Eastern Krušne hory/Erzgebirge. In: Breiter K (ed) Genetic Significance of Phosphorus in Fractionated Granites. Excursion guide. Czech Geological Survey, Prague, pp 33-49

Shcherba GN (1960) Formation of rare-metal deposits of Central Kazakhstan. Izdatelstvo Akademii Nauk Kazakhskoi SSR, Alma Ata, pp 1-260 (in Russian)

Shcherba GN, Gukova VD, Kudryashov AV, Senchilo NP (1964) Greisens, vein quartz and potash feldspars of molybdenum-tungsten deposits. Izdatelstvo Akadademii Nauk Kazakhskoi SSR, Alma-Ata, pp.1-307 (in Russian)

Steiger RH, Jäger E (1977) Subcommission on geochronology: convention on the use of decay constants in geo- and cosmochronology. Earth Planet Sci Lett 36: 359-362
http://doi.org/10.1016/0012-821X(77)90060-7

Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. In: Saunders AD, Norry MJ (eds) Magmatism in the Ocean Basins. Geological Society of London Special Publications 42: 313-345
http://doi.org/10.1144/GSL.SP.1989.042.01.19

Syritso LF (2002) Mesozoic Granitoids of Eastern Transbaikalia and Problems of Rare Metal Mineralization. Izdatelstvo St.-Petersburgskogo Universiteta, St. Petersburg, pp 1-357 (in Russian)

Syritso LF, Tabuns EV, Volkova EV, Badanina EV, Vysotskii YuA (2001) Model for the genesis of Li-F granites in the Orlovka Massif, Eastern Transbaikalia. Petrology 9: 268-289

Škvor V (1974) Geology of the Czech part of the Krušné hory and Smrčiny. Knihovna Ústředního ústavu geologického 48: pp 1-119 (in Czech)

Štemprok M (1964) Traces of sulphide and greisen mineralization in the deep parts of the Cínovec (Zinnwald) granite massif. Věst ÚÚG 39: 211-213

Štemprok M (1965) Petrography and the vertical extent of mineralization in the Cínovec granite cupola. Sbor Geol Věd, lož Geol Mineral 5: 7-106 (in Czech)

Štemprok M (1989) Rare-earth elements in the rocks of the Cínovec granite cupola (Czechoslovakia). Bull Czech Geol Survey 64: 1-15

Štemprok M (1991) Ongonite from Ongon Khairkhan, Mongolia. Mineral Petrol 43: 255-273
http://doi.org/10.1007/BF01164530

Štemprok M, Seifert T (2011) An overview of the association between lamprophyric intrusions and rare-metal mineralization. Mineralogia 42: 121-162
http://doi.org/10.2478/v10002-011-0011-x

Štemprok M, Šulcek Z (1969) Geochemical profile through an ore-bearing lithium granite. Econ Geol 64: 392-404
http://doi.org/10.2113/gsecongeo.64.4.392

Štemprok M, Novák JK, David J (1994) The association between granites and tin-tungsten mineralization in the eastern Krušné hory (Erzgebirge), Czech Republic. In: von Geohlen K, Klemm DD (ed) Mineral Deposits of the Erzgebirge/Krušné hory (Germany/Czech Republic). Monograph Series on Mineral Deposits 31, Gebrueder Borntraeger, Berlin-Stuttgart, pp 97-129

Štemprok M, Holub FV, Novák JK (2003) Multiple magmatic pulses of the Eastern Volcano-Plutonic Complex, Krušné hory/Erzgebirge Batholith and their phosphorus contents. Bull Geosci 78: 277-296

Štemprok M, Dolejš D, Müller A, Seltmann R (2008) Textural evidence of magma decompression, devolatilization and disequilibrium quenching: an example from the Western Krušné hory/Erzgebirge granite pluton. Contrib Mineral Petrol 155: 93-109
http://doi.org/10.1007/s00410-007-0229-1

Štemprok M, Dolejš D, Holub FV (2014) Late Variscan calc-alkaline lamprophyres in the Krupka ore district, Eastern Krušné hory/Erzgebirge: their relationship to Sn-W mineralization. J Geosci 59: 41-68
http://doi.org/10.3190/jgeosci.156

Tauson LV (1977) Geochemical Types and Potential Ore-bearing Capacity of Granitoids. Nauka, Moscow, pp 1- 279 (in Russian)

Taylor RG (1979) Geology of Tin Deposits. Elsevier, Amsterdam, pp 1-543

Taylor RP, Fallick AE (1997) The evolution of fluorine-rich felsic magmas: source dichotomy, magmatic convergence and the origin of topaz granites. Terra Nova 9: 105-108

Tindle AG (2001) Chemical formula recalculation for columbite-tantalite & ferrotapiolite analyses. Accessed January 4, 2017 at http://www.open.ac.uk/earth-research/tindle/AGTWebData/Mica-bio.xls

Tindle AG, Webb PC (1990) Estimation of lithium contents in trioctahedral micas using microprobe data: application to micas from granitic rocks. Eur J Mineral 2: 595-610
http://doi.org/10.1127/ejm/2/5/0595

Tischendorf G (1997) On Li-bearing micas: estimating Li from electron microprobe analyses and an improved diagram for graphical presentation. Mineral Mag 61: 804-834
http://doi.org/10.1180/minmag.1997.061.409.05

Tischendorf G, Just G, Gottesmann B (1988) Distribution of elements at a contact albite granite/rhyolite, Zinnwald, Erzgebirge (G.D.R.). Chem Erde 48: 155-162

Walther D, Breitkreuz C, Rapprich V, Kochergina YV, Chlupáčová M, Lapp M, Stanek K, Magna T (2016) The Late Carboniferous Schönfeld-Altenberg Depression on the NW margin of the Bohemian Massif (Germany/Czech Republic): volcanosedimentary and magmatic evolution. J Geosci 61: 371-393.
http://doi.org/10.3190/jgeosci.219

Webster J, Thomas R, Förster H-J, Seltmann R, Tappen C (2004) Geochemical evolution of halogen-enriched granite magmas and mineralizing fluids of the Zinnwald tin-tungsten mining district, Erzgebirge, Germany. Mineral Depos 39: 452-472
http://doi.org/10.1007/s00126-004-0423-2

Weiss D (1983) Methods of Chemical Analysis of Mineral Resources, vol. 2-3. Czech Geological Survey, Prague, pp 157-302 (in Czech)

Zhao Z, Masuda A, Shabani MB (1993) REE tetrad effects in rare-metal granites. Chinese J Geochem 12: 206-219
http://doi.org/10.1007/BF02843360