Journal of


  (Formerly Journal of the Czech Geological Society)

Original paper

Barbara L. Dutrow, Darrell J. Henry

Tourmaline compositions and textures: reflections of the fluid phase

Journal of Geosciences, volume 63 (2018), issue 2, 99 - 110


  Abstract References Affiliations

Aranovich Ly Newton RC (1996) H2O activity in concentrated NaCl solutions at high pressures and temperatures measured by the brucite-periclase equilibrium. Contrib Mineral Petrol 125: 200-212

Bačík P, Koděra P, Uher P, Ozdín D, Jánošík M (2015) Chlorine-enriched tourmalines in hydrothermally altered diorite porphyry from the Biely Vrch porphyry gold deposit (Slovakia). Canad Mineral 53: 673-691

Baksheev I, Prokef’ev VY, Yapaskurt VO, Vigasina MF, Zorina LD, Solov’ev VN (2011) Ferric-iron-rich tourmaline from the Darasum gold deposit, Transbaikalia, Russia. Canad Mineral 49: 263-276

Berryman E, Wunder B, Wirth R, Rhede D, Schettler G, Franz G, Heinrich W (2015) An experimental study on K and Na incorporation in dravitic tourmaline and insight into the origin of diamondiferous tourmaline from the Kokchetav Massif, Kazakhstan. Contrib Mineral Petrol 169: 1-16

Berryman E, Wunder B, Rhede D, Schettler G, Franz G, Heinrich W (2016) P-T-X controls on Ca and Na distribution between Mg-Al tourmaline and fluid. Contrib Mineral Petrol 171: 31

Berryman E, Kutzschbach M, Trumbull R, Meixner A, Van Hinsberg V, Kasemann S, Franz G (2017) Tourmaline as a petrogenetic indicator in the Pfitsch Formation, Western Tauern Window, Eastern Alps. Lithos 283-284:138-155

Boudreaux AP (2014) Mineralogy and Geochemistry of the Erongo Granite and Interior Quartz-Tourmaline Orbicules and NYF-type Miarolitic Pegmatites, Namibia. Unpublished MSci. Thesis, University of New Orleans, New Orleans, pp 1-246

Cavarretta G, Puxeddu M (1990) Schorl-dravite-ferridravite tourmalines deposited by hydrothermal magmatic fluids during early evolution of the Larderello Geothermal Field, Italy. Econ Geol 85: 1236-1251

Cook RB (2013) Tourmaline: a giant of a “mineral”. Rocks Mineral 88: 316-321

Corthouts TL, Lageson DR, Shaw CA (2015) Polyphase deformation, dynamic metamorphism, and metasomatism of Mount Everest’s summit limestone, east central Himalaya, Nepal/Tibet. Lithosphere 8: 38-57

Dietrich RV (1985) The Tourmaline Group. Van Nostrand Reinbold Co, New York, pp 1-300

Dingwell D, Pichavant M, Holtz F (1996) Experimental studies of boron in granitic melts. In: Grew ES, Anovitz LM (eds) Boron: Mineralogy, Petrology and Geochemistry. Mineralogical Society of America Reviews in Mineralogy 33: 331-385

Duchoslav M, Marks MAW, Drost K, McCammon C, Marschall HR, Wenzel T, Markl G (2017) Changes in tourmaline composition during magmatic and hydrothermal processes leading to tin-ore deposition: the Cornubian Batholith, SW England. Ore Geol Rev 83: 215-234.

Dutrow BL, Henry DJ (2000) Complexly zoned fibrous tourmaline, Cruzeiro mine, Minas Gerais, Brazil: a record of evolving magmatic and hydrothermal fluids. Canad Mineral 38: 131-143

Dutrow BL, Henry DJ (2016) Fibrous tourmaline: a sensitive probe of fluid compositions and petrologic environments. Canad Mineral 54: 311-335

Dutrow BL, Foster CT, Henry DJ (1999) Tourmaline-rich pseudomorphs in sillimanite zone metapelites: demarcation of an infiltration front. Amer Miner 84: 794-805

Etzel TM (2016) Oxygen Isotope Composition and Tourmaline Mineral Chemistry of the Coso and Darajat Geothermal Systems. Unpublished M.Sci. Thesis, University of Utah, Salt Lake City, pp 1-139

Etzel TM, Moore JN, Bowman JR, Jones CG, Intani RG, Golla G, Nash G (2015) Tourmaline in geothermal systems: an example from Darajat, Indonesia. GRC Trans 29: 529-536

Grice JD, Ercit T (1993) Ordering of Fe and Mg in the tourmaline crystal structure - the correct formula. Neu Jb Mineral, Abh 165: 245-266

Griffin WL, Slack JF, Ramsden AR, Win TT, Ryan CG (1996) Trace elements in tourmalines from massive sulfide deposits and tourmalinites: geochemical controls and exploration applications. Econ Geol 91: 657-675

Hawthorne FC, Henry DJ (1999) Classification of the minerals of the tourmaline group. Eur J Mineral 11: 201-215

Hazarika P, Mishra B, Pruseth K (2015) Diverse tourmaline compositions from orogenic gold deposits in the Hutti-Maski Greenstone Blet, India: implications for sources of ore-forming fluids. Econ Geol 110: 337-353

Helgeson HC (1992) Effects of complex formation in flowing fluids on the hydrothermal solubilities of minerals as a function of fluid pressure and temperature in the critical and supercritical regions of the system H2O. Geochim Cosmochim Acta 56: 3191-3207

Henry DJ, Dutrow BL (1992) Tourmaline in a low grade clastic metasedimentary rock; an example of the petrogenetic potential of tourmaline. Contrib Mineral Petrol 112: 203-218

Henry DJ, Dutrow BL (1996) Metamorphic tourmaline and its petrologic applications. In: Grew ES, Anovitz LM (eds) Boron: Mineralogy, Petrology and Geochemistry. Mineralogical Society of America Reviews in Mineralogy 33: 503-557

Henry DJ, Dutrow BL (2011) The incorporation of fluorine in tourmaline: internal crystallographic controls or external environmental influences? Canad Mineral 49: 41-56

Henry DJ, Dutrow BL (2012) Tourmaline at diagenetic to low-grade metamorphic conditions: its petrologic applicability. Lithos 154: 16-32

Henry DJ, Guidotti CV (1985) Tourmaline as a petrogenetic indicator mineral - an example from the staurolite-grade metapelites of NW Maine. Amer Miner 70: 1-15

Henry DJ, Kirkland BL, Kirkland DW (1999) Sector-zoned tourmaline from the cap rock of a salt dome. Eur J Mineral 11: 263-280

Henry DJ, Dutrow BL, Selverstone, J. (2004) Compositional asymmetry in replacement tourmaline - an example from the Tauern Window, Eastern Alps. Amer Miner 88: 1399-1399

Henry DJ, Sun H, Slack JF, Dutrow BL (2008) Tourmaline in meta-evaporites and highly magnesian rocks; perspectives from Namibian tourmalinites. Eur J Mineral 20: 889-904

Henry DJ, Novák M, Hawthorne FC, Ertl A, Dutrow BL, Uher P, Pezzotta F (2011) Nomenclature of the tourmaline-supergroup minerals. Amer Miner 96: 895-913

Jones C, Moore J, Bowman J, Walters M (2016) Higher temperature hydrothermal metamorphism at the Geysers Geothermal Field, California: an investigation of mineral chemistry and vein paragenesis from an active contact metamorphic environment. Proceedings of the 41st Workshop on Geothermal Reservoir Engineering, Stanford Geothermal Program, SGP-TR-209. Stanford University, Stanford, CA, pp 1-18

Kawakami T (2001) Tourmaline breakdown in the migmatites zone of the Ryoke metamorphic belt, SW, Japan. J Metamorph Geol 19: 61-75

Kister P, Vieillard P, Cuney M, Quirt D, Laverret E (2005) Thermodynamic constraints on the mineralogical and fluid composition evolution in a clastic sedimentary basin: the Athabasca Basin (Saskatchewan, Canada). Eur J Mineral 17: 325-341

Leeman W, Sisson J (1996) Geochemistry of boron and its implications for crustal and mantle processes. In: Grew ES, Anovitz LM (eds) Boron: Mineralogy, Petrology and Geochemistry. Mineralogical Society of America Reviews in Mineralogy 33: pp 645-707

Lensing-Bergdorf M, Watenphul A, Schlüter J, Mihailova B (2017) Crystal chemistry of tourmalines from the Erongo Mountains, Namibia, studied by Raman spectroscopy. Eur J Mineral 29: 1-11

London D, Morgan GB, Wolf MD (1996) Boron in granitic rocks and their contact aureoles. In: Grew ES, Anovitz LM (eds) Boron: Mineralogy, Petrology and Geochemistry. Mineralogical Society of America Reviews in Mineralogy 33: 299-330

Lussier AJ, Hawthorne FC (2011) Oscillatory zoned liddicoatite from Anjanabonoina, central Madagascar. II. Compositional variation and mechanisms of substitution. Canad Mineral 49: 89-104

Lynch G, Ortega S (1997) Hydrothermal alteration and tourmaline-albite equilibria at the Coxheath porphyry Cu-Mo-Au deposit, Nova Scotia. Canad Mineral 35: 79-94

Marschall H, Jiang S-J (2011) Tourmaline isotopes: no element left behind. Elements 7: 313-319

Marschall H, Förster G (eds) (2018) Boron Isotopes - The Fifth Element. Springer, Berlin, pp 1-288 pp

Marschall HR, Korsakov AV, Luvizotto GL, Nasdala L, Ludwig T (2009) On the occurrence and boron isotopic composition of tourmaline in (ultra)high-pressure metamorphic rocks. J Geol Soc, London 166: 811-823

Moore JN, Christenson BW, Allis RG, Browne PRL, Lutz SJ (2004) The mineralogical consequences and behavior of descending acid-sulfate waters: an example from the Karaha-Telaga Bodas geothermal system, Indonesia. Canad Mineral 42: 1483-1499

Morgan GB IV, London D (1989) Experimental reactions of amphibole with boron-bearing fluids at 200 MPa: implications for tourmaline stability and partial melting in mafic rocks. Contrib Mineral Petrol 102: 281-297

Morton A, Whitham AG, Fanning CM (2005) Provenance of Late Cretaceous to Paleocene submarine fan sandstones in the Norwegian Sea: integration of heavy mineral, mineral chemical and zircon age data. Sediment Geol 182: 3-28

Norton D (1978) Source-lines, source-regions, and path-lines for fluids in hydrothermal systems related to cooling plutons. Econ Geol 73: 21-28

Norton D, Dutrow BL (2001) Complex behavior of magma-hydrothermal processes: role of supercritical fluid. Geochim Cosmochim Acta 65: 4009-4017

Pesquera A, Torres-Ruiz J, Garcia-casco A, Gil-crespo PP (2013) Evaluating the controls on tourmaline formation in granitic systems: a case study on peraluminous granites from the Central Iberian Zone (CIZ), Western Spain. J Petrol 54: 609-634

Pesquera A, Gil-crespo PP, Torres-Ruiz F, Torres-Ruiz J, Roda-Robles E (2016) A multiple regression method for estimating Li in tourmaline from electron microprobe analyses. Mineral Mag 80: 1129-1133

Pezzotta F, Laurs BM (2011) Tourmaline: the kaleidoscopic gemstone. Elements 7: 333-338

Slack J (1996) Tourmaline associations with hydrothermal ore deposits. In: Grew ES, Anovitz LM (eds) Boron: Mineralogy, Petrology and Geochemistry. Mineralogical Society of America Reviews in Mineralogy 33: pp 558-643

Slack JF, Trumbull RB (2011) Tourmaline as a recorder of ore-forming processes. Elements 7: 321-326

Trumbull R, Krienitz MS, Gottesmann B, Wiedenbeck M (2008) Chemical and boron-isotope variations in tourmalines from an S-type granite and its source rocks: the Erongo granite and tourmalinites in the Damara Belt, Namibia. Contrib Mineral Petrol 155: 1-18

Trumbull RB, Slack JF, Krienitz MS, Belkin HE, Wiedenbeck M (2011) Fluid sources and metallogenesis in the Blackbird Co-Cu-Au-Bi-Y-REE district, Idaho, U.S.A.: insights from major-element and boron isotopic compositions of tourmaline. Canad Mineral 49: 225-244

van Hinsberg VJ (2011) Preliminary experimental data on trace-element partitioning between tourmaline and silicate melt. Canad Mineral 49: 153-163

van Hinsberg VJ, Schumacher JC (2007) Intersector element partitioning in tourmaline: a potentially powerful single crystal thermometer. Contrib Mineral Petrol 153: 289-301

van Hinsberg VJ, Schumacher JC (2011) Tourmaline as a petrogenetic indicator mineral in the Haut-Allier metamorphic suite, Massif Central, France. Canad Mineral 49: 177-194

van Hinsberg VJ, Henry DJ, Marschall HR (2011a) Tourmaline: an ideal indicator of its host environment. Canad Mineral 49: 1-16

van Hinsberg VJ, Henry DJ, Dutrow BL (2011b) Tourmaline as a petrologic forensic mineral: a unique recorder of its geologic past. Elements 7: 327-332

van Hinsberg VJ, Franz G, Wood BJ (2017) Determining subduction-zone fluid composition using a tourmaline mineral probe. Geochem Persp Let 3: 160-169

von Goerne G, Franz G (2000) Synthesis of Ca-tourmaline in the system CaO-MgO-Al2O3-SiO2-B2O3-H2O-HCl. Mineral Petrol 69: 161-182

von Goerne G, Franz G, Robert JL (1999) Upper thermal stability of tourmaline plus quartz in the system MgO-Al2O3-SiO2-B2O3-H2O and Na2O-MgO-Al2O3-SiO2-B2O3-H2O-HCl in hydrothermal solutions and siliceous melts. Canad Mineral 37: 1025-1039

von Goerne G, Franz G, van Hinsberg VJ (2001) Synthesis of tourmaline solid solutions in the system Na2O-MgO-Al2O3-SiO2-B2O3-H2O-HCl and the distribution of Na between tourmaline and fluid at 300 to 700 °C and 200 MPa. Contrib Mineral Petrol 141: 160-173

von Goerne G, Franz G, van Hinsberg VJ (2011) Experimental determination of Na-Ca distribution between tourmaline and fluid in the system CaO-Na2O-MgO-Al2O3-SiO2-B2O3-H2O. Canad Mineral 49: 137-152

Žáček V, Petrov A, Hyršl J (1998) Chemistry and origin of povondraite-bearing rocks from Alto Chapare, Cochabamba, Bolivia. J Czech Geol Soc 43: 59-67
Direct link

Žáček V, Petrov A, Hyršl J, Ondruš P (2000) Tourmalines of povondraite - “oxy-dravite” series from Alto Chapare, Cochabamba, Bolivia. Geolines 10: 78-79 

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