Journal of


  (Formerly Journal of the Czech Geological Society)

Original paper

Štefan Ferenc, Adrián Biroň, Tomáš Mikuš, Ján Spišiak, Šimon Budzák

Initial replacement stage of primary uranium (UIV) minerals by supergene alteration: association of uranyl-oxide hydroxy-hydrates and “calciolepersonnite” from the Krátka Dolina Valley (Gemerská Poloma, Gemeric Unit, Western Carpathians, Slovakia)

Journal of Geosciences, volume 63 (2018), issue 3, 277 - 291


  Abstract References Map Affiliations

Bajaník Š, Hanzel V, Mello J, Pristaš J, Reichwalder P, Snopko L, Vozár J, Vozárová A (1983) Explanation to geological map of the Slovenské Rudohorie Mts. - eastern part, 1 : 50 000. State Geological Institute of D. Štúr, Bratislava, pp 1-223 (in Slovak)

Bajaník Š, Ivanička J, Mello J, Reichwalder P, Pristaš J, Snopko L, Vozár J, Vozárová A (1984) Geological map of the Slovenské Rudohorie Mts. - eastern part, 1 : 50 000. State Geological Institute of D. Štúr, Bratislava (in Slovak)

Bartlett JR, Cooney RP (1989) On the determination of uranium-oxygen bond lengths in dioxouranium (VI) compounds by Raman spectroscopy. J Mol Struct 193: 295-300

Belova LN (1975) Zones of Oxidation of Hydrothermal Uranium Deposits. Nedra, Moscow, pp 1-173 (in Russian)

Belova LN (2000) Formation conditions of oxidation zones of uranium deposits and uranium mineral accumulations in the gipergenesis zone. Geol Ore Dep 42: 103-110

Billiet V, de Jong WF (1935) Schoepite and becquerelite. Naturw Tijdschr Ned-Indië 17: 157-162 (in Dutch)

Bruker AXS (2010) Difrac.Eva - User Manual. Bruker AXS, Karlsruhe, pp 1-134

Burns PC (1997) A new uranyl oxide hydrate sheet in vandendriesscheite: implications for mineral paragenesis and the corrosion of spent nuclear fuel. Amer Miner 82: 1176-1186

Burns PC, Li Y (2002) The structures of becquerelite and Sr-exchanged becquerelite. Amer Miner 87: 550-557

Christ CL, Clark JR (1960) Crystal chemical studies of some uranyl oxide hydrates. Amer Miner 45: 1026-1061

Čejka J, Sejkora J, Skála R, Čejka J, Novotná M, Ederová J (1998) Contribution to the crystal chemistry of synthetic becquerelite, billietite and protasite. Neu Jb Mineral, Abh 174: 159-180

Deliens M, Piret P (1982) Bijvoetite et lepersonnite, carbonates hydratés d’uranyle et de terres rares de Shinkolobwe, Zaire. Canad Mineral 20: 231-238

Donát A, Miháľ F, Novotný L (2000) Geological-Exploration Works on the Au in Lower Paleozoic of Spišsko-Gemerské Rudohorie Mts. Unpublished Report, State Geological Institute of D. Štúr, Bratislava, pp 1-209 (in Slovak)

Downs RT, Hall-Wallace M (2003) The American Mineralogist Crystal Structure Database. Amer Miner 88: 247-250

Faryad SW (1991a) Metamorphism of the Early Paleozoic salic to intermediate volcanic rocks. Miner Slov 23: 325-332 (in Slovak)

Faryad SW (1991b) Metamorphism of the Early Paleozoic sedimentary rocks in Gemericum. Miner Slov 23: 315-324 (in Slovak)

Ferenc Š, Rojkovič I, Maťo Ľ (2003) Uranyl minerals of Western Carpathians. In: Zimák J (ed) Mineralogy of Bohemian Massif and Western Carpathians. Palacký University, Olomouc, pp 17-23 (in Slovak)

Finch JR (1994) Paragenesis and Crystal Chemistry of the Uranyl Oxide Hydrates. Unpublished PhD. Thesis, University of New Mexico, Albuquerque, pp 1-257

Finch JR, Ewing RC (1992) The corrosion of uraninite under oxidizing conditions. J Nucl Mater 190: 133-156

Finch R, Murakami T (1999) Systematics and paragenesis of uranium minerals. In: Burns PC, Finch R (eds) Uranium: Mineralogy, Geochemistry and the Environment. Mineralogical Society of America Reviews in Mineralogy 38: pp 91-179

Frondel JW, Cuttitta F (1953) Studies of uranium minerals (XII); The status of billietite and becquerelite. Amer Miner 38: 1019-1024

Frost RL, Čejka J, Weier ML (2007) Raman spectroscopic study of the uranyl oxyhydroxide hydrates: becquerelite, billietite, curite, schoepite and vandendriesscheite. J Raman Spectrosc 38: 460-466

Göb S, Gühring JE, Bau M, Markl G (2013) Remobilization of U and REE and the formation of secondary minerals in oxidized U deposits. Amer Miner 98: 530-548

Grecula P, Kobulský J, Gazdačko Ľ, Németh Z, Hraško Ľ, Novotný L, Maglay J (2009) Geological map of the Spišsko-Gemerské Rudohorie Mts., 1 : 50 000. State Geological Institute of D. Štúr, Bratislava (in Slovak)

Grecula P, Kobulský J, Gazdačko Ľ, Németh Z, Hraško Ľ, Novotný L, Maglay J, Pramuka S, Radvanec M, Kucharič Ľ, Bajtoš P, Záhorová Ľ (2011) Explanations to geological map of the Spišsko-Gemerské Rudohorie Mts., 1 : 50 000. State Geological Institute of D. Štúr, Bratislava, pp 1-308 (in Slovak)

Holland TJB, Redfern SAT (1997) Unit cell refinement from powder diffraction data: the use of regression diagnostics. Mineral Mag 61: 65-77

Ivanička J, Snopko L, Snopková P, Vozárová A (1989) Gelnica Group - Lower Unit of Spišsko-Gemerské Rudohorie Mts. (West Carpathians), Early Paleozoic. Geol Zbor Geol Carpath 40: 483-501

Kohút M, Stein H, Uher P, Aimmerman A (2013) Re-Os and U-Th-Pb dating of the Rochovce granite and its mineralization (Western Carpathians, Slovakia). Geol Carpath 64: 71-79

Krivovichev SV, Plášil J (2013) Mineralogy and crystallography of uranium. In: Burns PC, Sigmon GE (eds) Uranium: From Cradle to Grave, Mineralogical Association of Canada Short Courses 43: pp 15-119

Langmuir D (1978) Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits. Geochim Cosmochim Acta 42: 547-569

Li Y, Burns PC (2000) Investigation of crystal-chemistry variability in lead uranyl oxide hydrates II. Fourmarierite. Canad Mineral 38: 737-749

Libowitzky E (1999) Correlation of O-H stretching frequencies and O-H···O hydrogen bond lengths in minerals. Monatsh Chem 130: 1047-1059

Maheľ M, Vozár J (1971) Contribution to knowledge of Permian and Triassic in the North-Gemeric syncline. Geol Práce, Spr 56: 47-66 (in Slovak)

Németh Z, Putiš M, Grecula P (2000) Tectonic evolution of Gemericum (the Western Carpathians) outlined by the results of petrotectonic research. Miner Slov 32: 169-172

Novotný L, Čížek P (1979) New occurrence of uranium-gold mineralization to the south of Prakovce in Spišsko-Gemerské Rudohorie Mts. Miner Slov 11: 188-190 (in Slovak)

Novotný L, Háber M, Križáni I, Rojkovič I, Miháľ F (1999) Gold in the Early Paleozoic rocks in the central part of the Spišsko-Gemerské Rudohorie Mts. Miner Slov 31: 211-216 (in Slovak)

Olds TA, Plášil J, Kampf AR, Škoda R, Burns PC, Čejka J, Bourgoin V, Boulliard JC (2017a) Gauthierite, KPb[(UO2)7O5(OH)7]·8H2O, a new uranyl-oxide hydroxy-hydrate mineral from Shinkolobwe with a novel uranyl-anion sheet-topology. Eur J Mineral 29: 129-141

Olds TA, Lussier AJ, Oliver AG, Petříček V, Plášil J, Kampf AR, Burns PC, Dembowski M, Carson SM, Steele IM (2017b) Shinkolobweite, IMA 2016-095. CNMNC Newsletter No. 36, April 2017, p 404; Mineral Mag 81: 403-409

Olds TA, Plášil J, Kampf AR, Spano T, Haynes P, Carlson SM, Burns PC, Simonetti A, Mills OP (2018) Leesite K(H2O)2[(UO2)4O2(OH)5]·3H2O, a new K-bearing schoepite-family mineral from the Jomac mine, San Juan County, Utah, U.S.A. Amer Miner 103: 143-150

Pagoaga MK, Appleman DE, Stewart JM (1987) Crystal structures and crystal chemistry of the uranyl oxide hydrates becquerelite, billietite, and protasite. Amer Miner 72: 1230-1238

Piret-Meunier J, Piret P (1982) Nouvelle determination de la structure cristalline de la becquerelite. Bull Minéral 105: 606-610

Plášil J (2014) Oxidation-hydration weathering of uraninite: the current state-of-knowledge. J Geosci 59: 99-114

Plášil J (2017) Uranyl-oxide hydroxy-hydrate minerals: their structural complexity and evolution trends. Eur J Mineral 30: 1-15

Plášil J, Sejkora J, Škoda R, Škácha P (2014) The recent weathering of uraninite from Červená vein, Jáchymov (Czech Republic): a fingerprint of the primary mineralization onto the alteration association. J Geosci 59: 223-253

Plášil J, Kampf AR, Olds TA, Sejkora J, Škoda R, Burns PC, Čejka J (2017) Kroupaite, IMA 2017-031. CNMNC Newsletter No. 38, August 2017, p 1036; Mineral Mag 81: 1033-1038

Poller U, Uher P, Janák M, Plašienka D, Kohút M (2001) Late Cretaceous age of the Rochovce Granite, Western Carpathians, constrained by U-Pb single-zircon dating in combination with cathodoluminescence imaging. Geol Carpath 52: 41-47

Protas J (1957) Propriétés et synthèse d’un oxyde hydraté d’uranium et de calcium de Shinkolobwe, Katanga. C R Acad Sci Paris 244: 91-93

Putiš M, Sergeev S, Ondrejka M, Larionov A, Siman P, Spišiak J, Uher P, Paderin I (2008) Cambrian-Ordovician metaigneous rocks associated with Cadomian fragments in the West-Carpathian basement dated by SHRIMP on zircons: a record the Gondwana active margin setting. Geol Carpath 59: 3-18

Radvanec M, Grecula P (2016) Geotectonic and metallogenetic evolution of Gemericum (inner Western Carpathians) from Ordovician to Jurassic. Miner Slov 48: 105-118

Radvanec M, Konečný P, Ondrejka M, Putiš M, Uher P, Németh Z (2009) The Gemeric granites as an indicator of the crustal extension above the Late-Variscan subduction zone during the Early Alpine riftogenesis (Western Carpathians): an interpretation from the monazite and zircon ages dates by CHIME and SHRIMP methods. Miner Slov 41: 381-394

Rojkovič I (1997) Uranium Mineralization in Slovakia. Comenius University, Bratislava, pp 1-117

Rojkovič I, Novotný L (1993) Uranium mineralization in Gemericum. Miner Slov 25: 368-370 (in Slovak)

Rojkovič I, Puškelová Ľ, Khun M, Medveď J (1995) U-REE-Au in veins and black shales of the Gemericum, Slovakia. In: Pašava J, Kříbek B, Žák K (eds) Mineral Deposits: From Their Origin to Their Environmental Impacts. Balkema, Rotterdam, pp 789-792

Rojkovič I, Háber M, Novotný L (1997) U-Au-Co-Bi-REE mineralization in the Gemeric Unit (Western Carpathians, Slovakia). Geol Carpath 48: 303-313

Rojkovič I, Konečný P, Novotný L, Puškelová Ľ, Streško V (1999) Quartz-apatite-REE vein mineralization in Early Paleozoic rocks of the Gemeric Superunit, Slovakia. Geol Carpath 50: 215-227

Sejkora J, Plášil J, Bureš B (2013) Unusual association of supergene uranium minerals from the Jan Evangelista vein, Jáchymov (Czech Republic). Bull mineral-petrolog Odd Nár Muz (Praha) 21: 143-156 (in Czech)

Snopko L, Ivanička J (1978) Considerations on the paleogeography in the Lower Paleozoic of Spišsko-Gemerské Rudohorie Mts. In: Vozár J (ed) Paleogeographical Evolution of the Western Carpathians. Geological Institution of D. Štúr, Bratislava, pp 269-280 (in Slovak)

Ščerbina VV (1963) Geochemistry of uranium in the oxidation zone. In: Vinogradov AP (ed.) Basic Features of Uranium Geochemistry. Publishing House of the AS USSR, Moscow, pp 220-237 (in Russian)

Števko M, Uher P, Ondrejka M, Ozdín D, Bačík P (2014) Quartz-apatite-REE phosphates-uraninite vein mineralization near Čučma (eastern Slovakia): a product of early Alpine hydrothermal activity in the Gemeric Superunit, Western Carpathians. J Geosci 59: 209-222

Vaes JF (1947) Six noveaux minéraux d’urane provenant de Shinkolobwe (Katanga). Ann Soc géol Belg 70: 212-225

Varček C (1977) Some rare mineralization types in the Spišsko-Gemerské Rudohorie Mts. In: Háber M (ed) Ore-Forming Processes in the Western Carpathians. Universitas Comeniana, Bratislava, pp 93-99 (in Slovak)

Vozárová A (1993) Variscan metamorphism and crustal evolution of the Gemericum. Západ Karpaty, Sér Mineral Petrogr Geochém Metalogen 16: 55-117 (in Slovak)

Vozárová A, Šarinová K, Sergeev S, Larionov A, Presnyakov S (2010) Late Cambrian/Ordovician magmatic arc type volcanism in the Southern Gemericum basement, Western Carpathians, Slovakia: U-Pb (SHRIMP) data from zircons. Int J Earth Sci 99: 17-37

Vozárová A, Rodionov N, Šarinová K, Presnyakov S (2017) New zircon ages on the Cambrian-Ordovician volcanism of the Southern Gemericum basement (Western Carpathians, Slovakia): SHRIMP dating, geochemistry and provenance. Int J Earth Sci 106: 2147-2170

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