Journal of


  (Formerly Journal of the Czech Geological Society)

Original paper

María Florencia Márquez-Zavalía, Anna Vymazalová, Miguel Ángel Galliski, Yasushi Watanabe, Hiroyasu Murakami

Indium-bearing paragenesis from the Nueva Esperanza and Restauradora veins, Capillitas mine, Argentina

Journal of Geosciences, volume 65 (2020), issue 2, 97 - 109

  Abstract References Affiliations

Anders E, Grevesse N (1989) Abundances of elements: meteoritic and solar. Geochim Cosmochim Acta 53: 197-214

Armstrong JT (1993) Caltech 1993 JEOL license of CITZAF, version 3.5

Bauer ME, Seifert T, Burisch M, Krause J, Richter N, Gutzmer J (2019) Indium-bearing sulfides from the Hämmerlein skarn deposit, Erzgebirge, Germany: evidence for late-stage diffusion of indium into sphalerite. Miner Depos 54:175-192

Benites D, Torró L, Vallance J, Quispe P, Sáez J, Rosas S, Fernández-Baca A, Gamarra J, Camprubí A, Fontboté L (2019) Ore mineralogy of the In-bearing Ayawilca Zn-Ag-Sn-Cu project, Pasco, Peru. In: Life with Ore Deposits on Earth, vol. 4. Proceedings of the 15th Biennial SGA Meeting, Glasgow, pp 1681-1684

Bindi L, Putz H, Paar WH, Stanley CJ (2017) Omariniite, Cu8Fe2ZnGe2S12, the germanium-analogue of stannoidite, a new mineral species from Capillitas, Argentina. Mineral Mag 81: 1151-1159

Burke EAJ, Kieft C (1980) Roquesite and Cu-In-bearing sphalerite from Långban, Bergslagen, Sweden. Canad Mineral 18: 361-363

Cook NJ, Ciobanu CL, Pring A, Skinner W, Danyushevsky L, Shimizu M, Saini-Eidukat B, Melcher F (2009) Trace and minor elements in sphalerite: a LA-ICP-MS study. Geochim Cosmochim Acta 73: 4761-4791

Cook NJ Ciobanu CL, Danyushevsky LV, Gilbert S (2011a) Minor and trace elements in bornite and associated Cu-(Fe)-sulphides: A LA-ICP-MS study. Geochim Cosmochim Acta 75: 6473-6496

Cook NJ, Sundblad K, Valkama M, Nygård R, Ciobanu CL, Danyushevsky L (2011b) Indium mineralisation in A-type granites in southeastern Finland: insights into mineralogy and partitioning between coexisting minerals. Chem Geol 284: 62-73

Cook NJ, Ciobanu CL, Brugger J, Etschmann B, Howard DL, de Jonge MD, Ryan C, Paterson D (2012) Determination of the oxidation state of Cu in substituted Cu-In-Fe-bearing sphalerite via μ-XANES spectroscopy. Amer Miner 97: 476-479

Effenberger H, Lengauer CL, Libowitzky E, Putz H, Topa D (2015) Lislkirchnerite, IMA 2015-064. CNMNC Newsletter No. 27, October 2015, page 1230. Mineral Mag 79: 1229-1236

Gallard-Esquivel C, Cepedal A, Fuertes-Fuente M, Martin-Izard A (2018) Enrichment in critical metals (In-Ge) and Te-Se in epithermal deposits of the ’La Carolina’ district, San Luis, Argentina. Mineral Mag 82: S61-S87

George L, Cook N, Ciobanu C (2017) Minor and trace elements in natural tetrahedrite-tennantite: effects on element partitioning among base metal sulphides. Minerals 7: 17-42

Gómez C, Luna L, Garrido M, Bonuccelli R (2008) Manifestación de indio en el Macizo Nordpatagónico: proyecto San Roque, pro¬vincia de Rio Negro. In: 9° Congreso de Mineralogía y Metalogenia, San Salvador de Jujuy, pp 125-128

Goonan TG (2012) Materials flow of indium in the United States in 2008 and 2009. U.S. Geological Survey Circular 1377: pp 1-12, available at

Guido D, Jovic S, Schalamuk I (2005) A new metallogenic association (Sn-Cd-In-Zn-Ag- Au) in the Deseado Auroargentiferous pro¬vince, Deseado Massif, Patagonia, Argentina. Mineral Deposit Research 2: 965-968

Heinrich CA (2005) The physical and chemical evolution of low-salinity magmatic fluids at the porphyry to epithermal transition: a thermodynamic study. Miner Depos 39: 864-889

JICA (Japan International Cooperation Agency) (1978-1981) Informe de estudios básicos sobre la explotación de recursos minerales en la zona norte de la República Argentina. Cuatro etapas. Dirección General de Fabricaciones Militares, informe inédito, Buenos Aires, pp 1-520

Johan Z (1988) Indium and germanium in the structure of sphalerite: an example of coupled substitution with copper. Mineral Petrol 39: 211-229

Jovic SM (2009) Geología y Metalogénesis de las mineralizaciones polimetálicas del área El Tranquilo (Cerro León), sector central del macizo del Deseado, Provincia de Santa Cruz. Unpublished Ph.D. thesis, National University of La Plata, La Plata, pp 1-278

Jovic SM, Guido DM, Melgarejo JC, Páez GN, Ruiz R, Schalamuk IB (2011) The indium-bearing minerals of the Pingüino po¬lymetallic vein system, Deseado Massif, Pa-tagonia, Argentina. Canad Mineral 49: 931-946

Jovic SM, López L, Guido D, Redigonda J, Páez G, Ruiz R, Pemuy Vidal C (2015) Presencia de indio en sistemas epitermales polimetálicos de Patagonia. Rev Asoc Geol Argent 71: 433-437

López L, Jovic S, Guido D, Páez G, Ruiz R, Permuy Vidal C (2015) Geochemical distribution and supergene behavior of indium at the Pingüino epithermal polymetallic vein system, Patagonia, Argentina. Ore Geol Rev 64: 747-755

Márquez-Zavalía MF (1988) Mineralogía y génesis del yacimiento Capillitas (Catamarca, República Argentina). Unpublished Ph.D. Thesis, National University of Salta, Salta, pp 1-258

Márquez-Zavalía MF (1999) El yacimiento Capillitas, provincia de Catamarca. In: Zappettini EO (ed) Yacimientos Minerales de la República Argentina. Instituto de Geología y Recursos Minerales SEGEMAR, Buenos Aires, Anales 35, pp 1643-1652

Márquez Zavalía MF (2005) Indium minerals from Capillitas mine, northwestern Argentina. In: Gordon Research Conference on Inorganic Geochemistry: Metals in Ore-forming Systems: Sources, Transport, Deposition. Unpublished abstract, Proctor Academy, Andover, New Hampshire, USA

Márquez-Zavalía MF (2008) La rodocrosita de Mina Capillitas “Piedra” nacional Argentina - Rosa del Inca. In: Zappettini EO (ed) Sitios de Interés Geológico de la República Argentina. Editorial CSIGA. Instituto de Geología y Recursos Minerales, Servicio Geológico Minero Argentino - SEGEMAR, Buenos Aires, Anales 46, 85-98

Márquez-Zavalía MF, Craig JR (2004) Tellurium and precious metal mineralization at Mina Capillitas, northwestern Argentina. Neu Jb Mineral, Mh 2004(4): 176-192

Márquez-Zavalía MF, Heinrich CA (2016) Fluid evolution in a volcanic-hosted epithermal carbonate-base-metal-gold vein system: Alto de la Blenda, Farallón Negro, Argentina. Miner Depos 51: 873-902

Márquez-Zavalía M F, Galliski M A, Drábek M, Vymazalová A, Watanabe Y, Murakami H, Bernhardt H-J (2014) Ishiharaite, (Cu, Ga, Fe, In, Zn)S, a new mineral from Capillitas Mine, northwestern Argentina. Canad Mineral 52: 969-980

Murakami H, Ishihara S (2013) Trace elements of indium-bearing sphalerite from tin-polymetallic deposits in Bolivia, China and Japan: a femto-second LA-ICPMS study. Ore Geol Rev 53: 223-243

Oen IS, Kager P, Kieft C (1980) Oscillatory zoning of a discontinuous solid-solution series sphalerite-stannite. Amer Miner 65: 1220-1232

Ohta E (1980) Mineralization of Izumo and Sorachi veins of the Toyoha mine, Hokkaido, Japan. Bull Geol Surv Japan 31: 99-113 (in Japanese with English abstract)

Ohta E (1989) Occurrence and chemistry of indium-containing minerals from the Toyoha mine, Hokkaido, Japan. Min Geol 41: 279-295

Paar WH, de Brodtkorb MK, Sureda RJ, Topa D (1998) A microprobe study of complex Ag-Sn ores from Pirquitas, Jujuy province, Argentina. Abstracts for the Plenary Lectures, Symposia, and Special Sessions of the 17th General Meeting of the International Mineralogical Association, Toronto, 1998, p A118.

Paar WH, Roberts AC, Berlepsch P, Armbruster T, Topa D, Zagler G (2004) Putzite, (Cu4.7Ag3.3)8GeS6, a new mineral species from Capillitas, Catamarca, Argentina: description and crystal structure. Canad Mineral 42: 1757-1769

Pattrick RAD, Dorung M, Polya DA (1993) TEM study of indium- and copper-bearing growth-banded sphalerite. Canad Mineral 31: 105-117

Pouchou JL, Pichoir F (1985) PAP (ϕρZ) correction procedure for improved quantitative microanalysis. In: Armstrong JT (ed) Microbeam Analysis. San Francisco Press, San Francisco, pp 104-106

Putz H, Paar WH, Topa D, Makovicky E, Roberts AC (2006) Catamarcaite, Cu6GeWS8, a new species of germanium-tungsten sulfide from Capillitas, Catamarca, Argentina: description, paragenesis and crystal structure. Canad Mineral 44: 1481-1497

Putz H, Paar WH, Topa D (2009) A contribution to the knowledge of the mineralization at mina Capillitas, Catamarca. Rev Asoc Geol Argent 64: 514-524

Reich F, Richter HT (1863a) Vorläufige Notiz über ein neues Metall. J Prakt Chem 89: 441

Reich F, Richter HT (1863b) Über das Indium. J Prakt Chem 90: 172-176

Royal Society of Chemistry (2020) Indium. Accessed on May 1, 2020, at

Sahlström F, Blake K, Corral I, Chang Z (2017a) Hyperspectral cathodoluminescence study of indium-bearing sphalerite from the Mt Carlton high-sulphidation epithermal deposit, Queensland, Australia. Eur J Mineral 29: 985-993

Sahlström F, Arribas A, Dirks P, Corral I, Chang Z (2017b) Mineralogical distribution of germanium, gallium and indium at the Mt. Carlton high-sulfidation epithermal deposit, NE Australia, and comparison with similar deposits worldwide. Minerals 7: 213-240

Schalamuk I, de Barrio R, Zubia M, Genini A, Echeveste H (1999) Provincia Auroargentífera del Deseado, Santa Cruz. In: Zappettini EO (ed) Yacimientos Minerales de la República Argentina. Instituto de Geología y Recursos Minerales SEGEMAR, Buenos Aires, Anales 35, pp 1177-1188

Schwarz-Schampera U, Herzig PM (2002) Indium. Geology, Mineralogy and Economics. Springer-Verlag, Berlin, Heidelberg, pp 1-257

Seifert T, Sandmann D (2006) Mineralogy and geochemistry of indium-bearing polymetallic vein-type deposits: implications for host minerals from the Freiberg district, Eastern Erzgebirge, Germany. Ore Geol Rev 28: 1-31

Semenyak BI, Nedashkovskii AP, Nikulin NN (1994) Indium minerals in the ores of the Pravourmiiskoe deposit (Russian Far East). Geol Ore Depos 36: 207-213

Shimizu T, Morishita Y (2012) Petrography, chemistry, and near-infrared microthermometry of indium-bearing sphalerite from the Toyoha polymetallic deposit, Japan. Econ Geol 107: 723-735

Sibson RH, (1981) Fluid flow accompanying faulting: field evidence and models. In: Simpson DH, Richards PO (eds) Earthquake Prediction: an International Review. American Geophysical Union, Maurice Ewing Series 4: 593-603

Sillitoe RH (1973) The tops and bottoms of porphyry copper deposits. Econ Geol 68: 799-815

Sillitoe RH (1996) Granites and metal deposits. Episodes 19: 126-133

Sinclair WD, Kooiman GJA, Martin DA, Kjarsgaard IM (2006) Geology, geochemistry and mineralogy of indium resources at Mount Pleasant, New Brunswick, Canada. Ore Geol Rev 28: 123-145

Taylor SR, McLennan SM (1985) The Continental Crust: Its Composition and Evolution. Blackwell, Oxford, pp 1-312

Torró L, Melgarejo JC, Gemmrich L, Mollinedo D, Cazorla M, Martínez A, Pujol-Solà N, Farré-de-Pablo J, Camprubí A, Artiaga D, Torres B, Alfonso P, Arce O (2019a) Spatial and temporal control on the distribution of indium in xenothermal vein-deposits: the Huari Huari district, Potosí, Bolivia. Minerals 9: 304

Torró L, Cazorla M, Melgarejo JC, Camprubí A, Tarrés M, Gemmrich L, Campeny M, Artiaga D, Torres B, Martínez A, Mollinedo Alfonso P, Arce-Burgoa OR (2019b) Indium mineralization in the volcanic dome-hosted Ánimas-Chocaya-Siete Suyos polymetallic deposit, Potosí, Bolivia. Minerals 9: 604

Whitney DL, Evans BW (2010) Abbreviations for names of rock-forming minerals. Amer Miner 95: 185-187

Zappettini EO, de Brodtkorb MK, Godeas M, Bernhardt H-J (2004) Presencia de esfalerita rica en indio en el yacimiento El Peladar; provincia de Jujuy. In: 7° Congreso de Mineralogía y Metalogénesis, Río Cuarto, Córdoba, pp 131-132

Zhang Q, Zhu X, He Y, Jiang J, Wang D (2006) Indium enrichment in the Meng’entaolegai Ag-Pb-Zn deposit, Inner Mongolia, China. Resour Geol 56: 337-346

Journal of Geosciences, Published by © Czech Geological Society, with support from the Czech Geological Survey.
Webdesign inspired by aTeo. Hosted at the server of the Institute of Petrology and Structural Geology, Charles University, Prague.
ISSN: 1803-1943 (online), 1802-6222 (print)
email: jgeosci(at)
cover_rotated.gif, 15kB

SNIP (Scopus, 2020): 1.283

IF (ISI, 2020): 1.525

5 YEAR IF (ISI, 2020): 1.446

Policy: Open Access

ISSN: 1802-6222

E-ISSN: 1803-1943