Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original paper

Jiří Sejkora, Martin Števko, Radek Škoda, Eva Víšková, Jiří Toman, Sebastián Hreus, Jakub Plášil, Zdeněk Dolníček

Dobšináite, Ca₂Ca(AsO₄)₂·2H₂O, a new member of the roselite group from Dobšiná (Slovak Republic)

Journal of Geosciences, volume 66 (2021), issue 2, 127 - 135

DOI: http://doi.org/10.3190/jgeosci.324

Anthony JW, Bideaux RA, Bladh KW, Nichols MC (2000) Handbook of Mineralogy, Vol. IV, Arsenates, Phosphates, Vanadates. Mineral Data Publishing, Tucson, Arizona 680 pp.

Bariand P, Herpin P (1960) Un arséniate de calcium et de magnésium, isomorphe de la β rosélite. Bull Soc franç Minéral Cristallogr 83: 118-121
http://doi.org/10.3406/bulmi.1960.5390

Borodin LS, Kazakova ME (1954) Belovite-(Ce): a new mineral from an alkaline pegmatite. Dokl Akad Nauk SSSR 96: 613-616

Bothe Jr JV, Brown PW (1999) The stabilities of calcium arsenates at 23 ± 1°C. J Hazard Mater 69(2): 197-207

Burnham CW (1962) Lattice constant refinement. Carnegie Institute Washington Yearbook 61: 132-135

Chukhlantsev VG (1956) The solubility products of a number of arsenates. J Anal Chem USSR, 11: 565

Grecula P, Abonyi A, Abonyiová M, Antaš J, Bartalský B, Bartalský J, Dianiška I, Ďuďa R, Gargulák M, Gazdačko Ľ, Hudáček J, Kobulský J, Lörincz L, Macko J, Návesňák D, Németh Z, Novotný L, Radvanec M, Rojkovič I, Rozložník L, Varček C, Zlocha Z (1995) Mineral deposits of the Slovak Ore Mountains, Vol 1. Geocomplex, Bratislava, 1-834

Halahyjová-Andrusovová G (1959) Mineralogical a paragenetic study of the ore deposits around Dobšiná. Manuscript, ŠGÚDŠ-Geofond, Bratislava, 1--140 (in Slovak)

Halahyjová-Andrusovová G (1964a) About the genesis of the ore veins near Dobšiná. Geol Práce Správy 33: 53-69 (in Slovak)

Halahyjová-Andrusovová G (1964b) About the structures of Ni-Co-Fe sulfarsenides and arsenides from Dobšiná. Geol Sbor Slov Akad Vied 15: 87-91 (in Slovak)

Hawthorne FC, Ferguson RB (1977) The crystal structure of roselite. Canad Mineral 15: 36-42

Hernandez-Barcenas G, Castillo F, Avalos-Borja M, Martinez-Villegas NV (2017) Synthesis of calcium arsenates (guerinite, haidingerite and pharmacolite) morphologically similar to those found in contaminated soils. Rev Inter Contam Ambient 33(1): 153-163

Herwig S, Hawthorne FC (2006) The topology of hydrogen bonding in brandtite, collinsite and fairfieldite. Canad Mineral 44: 1181-1196
http://doi.org/10.2113/gscanmin.44.5.1181

Keller P, Lissner F, Schleid T (2004) The crystal structures of zincroselite and gaitite: Two natural polymorphs of Ca₂Zn[AsO₄]₂·2H₂O from Tsumeb, Namibia. Eur J Mineral 16: 353-359
http://doi.org/10.1127/0935-1221/2004/0016-0353

Kiefer S, Majzlan J, Chovan M, Števko M (2017) Mineral compositions and phase relations of the complex sulfarsenides and arsenides from Dobšiná (Western Carpathians, Slovakia). Ore Geol Rev 80: 894-908
http://doi.org/10.1016/j.oregeorev.2017.07.026

Kiefer S, Števko M, Vojtko R, Ozdín D, Gerdes A, Creaser RA, Szczerba M, Majzlan J (2020) Geochronological constraints on the carbonate-sulfarsenide veins in Dobšiná, Slovakia: U/Pb ages of hydrothermal carbonates, Re/Os age of gersdorffite, and K/Ar ages of fuchsite. J Geosci 65(4): 229-247
http://doi.org/10.3190/jgeosci.314

Kolitsch U, Fleck M (2006) Third update on compounds with krohnkite-type chains: the crystal structure of wendwilsonite [Ca₂Mg(AsO₄)₂·2H₂O] and the new triclinic structure types of synthetic AgSc(CrO₄)₂·2H₂O and M₂Cu(Cr₂O₇)₂·2H₂O (M = Rb, Cs). Eur J Mineral 18: 471-482
http://doi.org/10.1127/0935-1221/2006/0018-0471

Kraus W, Nolze G (1996) POWDER CELL - a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns. J Appl Crystallogr 29: 301-303
http://doi.org/10.1107/S0021889895014920

Mahapatra PP, Mahapatra LM, Nanda CN (1984) Dissolution of Ca₃(AsO₄)₂·2H₂O in the system CaO-As₂O₅-H₂O at 35, 40, 45 and 50 °C and the related thermodynamic data. Thermochim Acta 76(3): 301-309
http://doi.org/10.1016/0040-6031(84)87027-6

Mandarino JA (1981) The Gladstone-Dale relationship: Part IV. The compatibility concept and its application. Canad Mineral 19: 441-450

Nefedov EI (1953) Report on new minerals discovered by him. In: Mokievsky VA: The scientific session of the Federov institute together with the All-Union Mineralogical Society. Zap Vsesojuz Mineral Obšč 82 (4): 3l1-317 (in Russian)

Nelson OA, Haring MM (1937) Calcium Arsenates. An Investigation into the Three-Component System Calcium Oxide-Arsenic Oxide-Water. J Amer Chem Soc 59(11): 2216-2223

Nishimura T, Robins RG (1998) A re-evaluation of the solubility and stability regions of calcium arsenites and calcium arsenates in aqueous solution at 25 °C. Mineral Process Extr Metall Rev 18(3-4): 283-308
http://doi.org/10.1080/08827509808914159

Ondruš P (1993) A computer program for analysis of X-ray powder diffraction patterns. Materials Science Forum, EPDIC-2, Enchede, 133-136, 297-300
http://doi.org/10.4028/www.scientific.net/MSF.133-136.297

Pearce GW, Avens AW (1937) Further Phase Rule Studies of the Calcium Arsenates. J Amer Chem Soc 59(7): 1258-1261

Pierrot R (1964) Contribution à la minéralogie des arséniates calciques et calcomagnésiens naturels. Bull Minéral 87(2): 169-211
http://doi.org/10.3406/bulmi.1964.5727

Plumhoff AM, Plášil J, Dachs E, Benisek A, Sejkora J, Števko M, Rumsey MS, Majzlan J (2020) Thermodynamic properties, crystal structure and phase relations of pushcharovskite [Cu(AsO₃OH)(H₂O)·0.5H₂O], geminite [Cu(AsO₃OH)(H₂O)] and liroconite [Cu₂Al(AsO₄)(OH)₄·4H₂O]. Eur J Mineral 32(3): 285-304

Pouchou JL, Pichoir F (1985) “PAP” (φρZ) procedure for improved quantitative microanalysis. In: Armstrong JT (ed) Microbeam Analysis. San Francisco Press, San Francisco, 104-106

Raičević S, Stanić V, Kaludjerović-Radoičić T (2007) Theoretical assessment of calcium arsenates stability: Application in the treatment of arsenic contaminated waste. Mater Sci Forum 555: 131-136
http://doi.org/10.4028/www.scientific.net/MSF.555.131

Rozložník L (1959) Tectonic conditions of the ore deposits around Dobšiná. Acta Geol Geogr Univ Comen, Geol 2: 167-175 (in Slovak)

Rozložník L (1965) An analysis of the structural and metallogenetic elements between Dobšiná and Mlynky. Sbor Geol vied, Záp Karp 4: 29-93 (in Slovak).

Sejkora J, Řídkošil T, Šrein V (1999) Zálesíite, a new mineral of the mixite group, from Zálesí, Rychlebské hory Mts., Czech Republic. Neu Jb Mineral, Abh 175(2): 105-124

Sejkora J, Hawthorne FC, Cooper MA, Grice JD, Vajdak J, Jambor JL (2009) Burgessite, Co₂(H₂O)₄[AsO₃(OH)]₂·H₂O, a new arsenate mineral species from the Keeley mine, South Lorrain township, Ontario, Canada. Canad Mineral 47(1): 159-164
http://doi.org/10.3749/canmin.47.1.159

Sejkora J, Plášil J, Kampf AR (2018) Honzaite, (Ni,Co)₂(AsO₃OH)₂(H₂O)₅, a new Ni-dominant analogue of burgessite, from Jáchymov, Czech Republic. Eur J Mineral 30(5): 989-997
http://doi.org/10.1127/ejm/2018/0030-2770

Sejkora J, Plášil J, Čejka J, Dolníček Z, Pavlíček R (2020) Molecular structure of the arsenate mineral chongite from Jáchymov - a vibrational spectroscopy study. J Geosci 65: 111-120
http://doi.org/10.3190/jgeosci.292

Shannon RD (1976) Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides. Acta Crystallogr A32: 751-767
http://doi.org/10.1107/S0567739476001551

Steciuk G, Sejkora J, Čejka J, Plášil J, Hloušek J (2021) Krupičkaite, Cu₆[AsO₃(OH)]₆·8H₂O, a new copper arsenate mineral from Jáchymov (Czech Republic). J Geosci 66: 37-50
http://doi.org/10.3190/jgeosci.318

Števko M, Sejkora J (2020) Sb-enriched association of Ni arsenides and sulfarsenides from the Zemberg-Terézia vein system near Dobšiná (Western Carpathians, Slovak Republic). Bull Mineral Petrolog 28: 105-115
http://doi.org/10.46861/bmp.28.105

Vansant FK, van Der Veken BJ, Desseyn HD (1973) Vibrational analysis of arsenic and its anions I. Description of the Raman spectra. J Molecul Struct 15: 425-437
http://doi.org/10.1016/0022-2860(73)80012-2

Yakhontova LK, Sidorenko GA (1956) The new mineral arsenate-belovite. Zap Vsesojuz Mineral Obšč SSSR 85: 297-302 (in Russian)

Yang H, Jenkins RA, Downs RT, Evans SH, Tait KT (2011) Rruffite, Ca₂Cu(AsO₄)₂·2H₂O, a new member of the roselite group, from Tierra Amarilla, Chile. Canad Mineral 49: 877-884
http://doi.org/10.3749/canmin.49.3.877

Zhu YN, Zhang XH, Xie QL, Wang DQ, Cheng GW (2006) Solubility and stability of calcium arsenates at 25 °C. Water Air Soil Pollut 169(1): 221-238
http://doi.org/10.1007/s11270-006-2099-y