Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original paper

Anatoly V. Kasatkin, Jakub Plášil, Emil Makovicky, Radek Škoda, Atali A. Agakhanov, Mikhail V. Tsyganko

Pokhodyashinite, CuTlSb₂(Sb_1-xTl_x)AsS_7-x, a new thallium sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia

Journal of Geosciences, volume 67 (2022), issue 1, 41 - 51

DOI: http://doi.org/10.3190/jgeosci.342

Balić-Žunić T, Makovicky E, Moëlo Y (1995) Contributions to the crystal chemistry of thallium sulphosalts III. The crystal structure of lorándite (TlAsS₂) and its relation to weissbergite (TlSbS₂). Neu Jb Mineral, Abh 168: 213- 235

Berlepsch P (1996) Crystal structure and crystal chemistry of the homeotypes edenharterite (TlPbAs₃S₆) and jentschite (TlPbAs₂SbS₆) from Lengenbach, Binntal (Switzerland). Schweiz Miner Petrogr Mitt 76: 147-157

Berlepsch P, Makovicky E, Balić-Žunić T (2000) Contribution to the crystal chemistry of Tl-sulfosalts. VI. Modular-level structure relationship between edenharterite TlPbAs₃S₆ and jentschite TlPbAs₂SbS₆. Neu Jb Mineral, Mh 2000: 315-332

Biagioni C, Sejkora J, Moëlo Y, Marcoux E, Mauro D, Dolníček Z (2022) Tennantite-(Cu), Cu₁₂As₄S₁₃, from Layo, Arequipa Department, Peru: a new addition to the tetrahedrite group minerals. Mineral Mag, in press, https://doi.org/10.1180/mgm.2022.26.
http://doi.org/10.1180/mgm.2022.26

Boev T, Jovanovski G, Makreski P (2012) Geology and mineralogy of Allchar Sb-As-Tl-Au deposit. Geol Maced 3: 215-233

Bourgoin V, Favreau G, Bouillard J.-C. (2011) Jas Roux (Hautes-Alpes): un gisement exceptionnel à minéraux de thallium. Le Cahier des Micromonteurs 113: 2-92 (in French)

Fleet ME (1973) The crystal structure and bonding of lorandite, Tl₂As₂S₄. Z Kristallogr 138: 147-160
http://doi.org/10.1524/zkri.1973.138.138.147

Kasatkin AV, Makovicky E, Plášil J, Škoda R, Agakhanov AA, Karpenko VY, Nestola F (2018a) Tsygankoite, Mn₈Tl₈Hg₂(Sb₂₁Pb₂Tl)_Σ24S₄₈, a New Sulfosalt from the Vorontsovskoe Gold Deposit, Northern Urals, Russia. Minerals 8: 218
http://doi.org/10.3390/min8050218

Kasatkin AV, Nestola F, Agakhanov AA, Škoda R, Karpenko VY, Tsyganko MV, Plášil J (2018b) Vorontsovite, (Hg₅Cu)_Σ6TlAs₄S₁₂, and Ferrovorontsovite, (Fe₅Cu)_Σ6TlAs₄S₁₂: The Tl- and Tl-Fe-Analogues of Galkhaite from the Vorontsovskoe Gold Deposit, Northern Urals, Russia. Minerals 8: 185
http://doi.org/10.3390/min8050185

Kasatkin AV, Makovicky E, Plášil J, Škoda R, Chukanov NV, Stepanov SY, Agakhanov AA, Nestola F (2019) Gladkovskyite, MnTlAs₃S₆, a new thallium sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia. J Geosci 64: 207-218
http://doi.org/10.3190/jgeosci.290

Kasatkin AV, Makovicky E, Plášil J, Škoda R, Agakhanov AA, Stepanov SY, Palamarchuk RS (2020a) Luboržákite, Mn₂AsSbS₅, a new member of pavonite homologous series from Vorontsovskoe gold deposit, Northern Urals, Russia. Mineral Mag 84: 738-745
http://doi.org/10.1180/mgm.2020.48

Kasatkin AV, Makovicky E, Plášil J, Škoda R, Agakhanov AA, Tsyganko MV (2020b) Pokhodyashinite, IMA 2019-130. CNMNC Newsletter No. 55. Mineral Mag 84: 485-488

Kasatkin AV, Plášil J, Makovicky E, Chukanov NV, Škoda R, Agakhanov AA, Stepanov SY, Palamarchuk RS (2021a) Auerbakhite, MnTl₂As₂S₅, a new thallium sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia. J Geosci 66: 89-96
http://doi.org/10.3190/jgeosci.321

Kasatkin AV, Stepanov SY, Tsyganko MV, Škoda R, Nestola F, Plášil J, Makovicky E, Agakhanov AA, Palamarchuk RS (2021b) Mineralogy of the Vorontsovskoe gold deposit (Northern Urals). Part 3: Sulfosalts. Mineralogiya 7(2): 5-49 (in Russian).
http://doi.org/10.35597/2313-545X-2021-7-2-1

Kasatkin AV, Plášil J, Makovicky E, Hornfeck W, Chukanov NV, Škoda R, Agakhanov AA, Tsyganko MV (2022a) Gungerite, TlAs₅Sb₄S₁₃, a new thallium sulfosalt with a giant structure containing covalent As-As bonds. Amer Miner, in press, https://doi.org/10.2138/am-2022-8003.
http://doi.org/10.2138/am-2022-8003

Kasatkin AV, Stepanov SYu, Tsyganko MV, Škoda R, Nestola F, Plášil J, Makovicky E, Agakhanov AA, Palamarchuk RS (2022b) Mineralogy of the Vorontsovskoe gold deposit (Northern Urals). Mineralogy 8(1): 5-93 .
http://doi.org/10.35597/2313-545X-2022-8-1-1

Kraus W, Nolze G (1996) POWDER CELL - a program for the representation and manipulation of crystal struc¬tures and calculation of the resulting X-ray powder patterns. J Appl Cryst 29: 301-303
http://doi.org/10.1107/S0021889895014920

Makovicky E, (2018) Modular crystal chemistry of thallium sulfosalts. Minerals 8: 478
http://doi.org/10.3390/min8110478

Makovicky E, Plášil J, Kasatkin AV, Škoda R (2021) The crystal structure of Tl_2.36Sb_5.98As_4.59S₁₇, the lead-free endmember of the chabournéite homeotypic group. Canad Mineral 59: 533-549
http://doi.org/10.3749/canmin.2000093

Matsushita Y, Takéuchi Y (1994) Refinement of the crystal structure of hutchinsonite, TlPbAs₅S₉. Z Kristallogr 209: 475-478
http://doi.org/10.1524/zkri.1994.209.6.475

Merlet C (1994) An Accurate Computer Correction Program for Quantitative Electron Probe Microanalysis. Microchim Acta 114/115: 363-376
http://doi.org/10.1007/BF01244563

Murzin VV, Bushmakin AF, Sustavov SG, Shcherbachov DK (1996) Clerite MnSb₂S₄ - a new mineral from Vorontsovskoe gold deposit in the Urals. Zap Ross Mineral Obsh 125(3): 95-101 (in Russian)

Murzin VV, Naumov EA, Azovskova OB, Varlamov DA, Rovnushkin MY, Pirajno E (2017) The Vorontsovskoe Au-Hg-As ore deposit (Northern Urals, Russia): Geological setting, ore mineralogy, geochemistry, geochronology and genetic model. Ore Geol Rev 85: 271-298
http://doi.org/10.1016/j.oregeorev.2016.10.037

Petříček V, Dušek M, Palatinus L (2020) Jana2020. The crystallographic computing system. Institute of Physics, Praha, Czech Republic.

Raber T, Roth P (2018) The Lengenbach quarry in Switzerland: Classic locality for rare thallium sulfosalts. Minerals 8: 409
http://doi.org/10.3390/min8090409

Rigaku (2019) CrysAlis CCD and CrysAlis RED. Rigaku-Oxford Diffraction Ltd, Yarnton, Oxfordshire, UK

Sazonov VN, Murzin VV, Grigor’ev NA (1998) Vorontsovsk Gold Deposit: An Example of Carlin-type Mineralization in the Urals, Russia. Geol Ore Deposits 40: 139-151.

Sheldrick GM (2015) SHELXT - integrated space-group and crystal-structure determination. Acta Crystallogr A71: 3-8.
http://doi.org/10.1107/S2053273314026370

Stepanov SY, Sharpenok LN, Antonov AV (2017) Fluid-Exposive breccias of the Vorontsovskoe Gold Deposit (The North Urals). Zap Ross Mineral Obsh 1: 29-43 (in Russian)

Stepanov SY, Palamarchuk RS, Varlamov DA, Kiseleva DV, Sharpyonok LN, Škoda R, Kasatkin AV (2021) The Features of Native Gold in Ore‐bearing Breccias with Realgar‐orpiment Cement of the Vorontsovskoe Deposit (Northern Urals, Russia). Minerals 11: 541.
http://doi.org/10.3390/min11050541

Takéuchi Y, Ghose S, Nowacki W (1965) The crystal structure of hutchinsonite, (Tl, Pb)₂As₅S₉. Z Kristallogr 121: 321-348
http://doi.org/10.1524/zkri.1965.121.5.321

Vikentyev IV, Tyukova EE, Murzin VV, Vikentyeva OV, Pavlov LG (2016) The Vorontsovsk gold deposit. Geology, gold modes, genesis. Yekaterinburg, Fort Dialog-Iset: 1-204 (in Russian)

Zemann A, Zemann J (1979) Zur Kenntnis der Kristallstruktur von Lorandit, TlAsS₂. Acta Crystallogr 12: 1002-1006
http://doi.org/10.1107/S0365110X59002833