Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original Paper

Jakub Plášil, Jiří Sejkora, Jiří Čejka, Radek Škoda, Viktor Goliáš

Supergene mineralization of the Medvědín uranium deposit, Krkonoše Mountains, Czech Republic

Journal of Geosciences, volume 54 (2009), issue 1, 15 - 56

DOI: http://doi.org/10.3190/jgeosci.029

Artl T, Ambruster T (1999) Single X-ray structure refinement of cornwallite, Cu₅(AsO₄)₂(OH)₄: a comparison with its polymorph cor-nubite and the PO₄-analogue pseudomalachite. Neu J Mineral, Mh 10: 468-480

Aruga A, Nakai I (1985) Structure of Ca-rich agardite. Acta Cryst C41: 161-163

Belova LN, Doynikova OA (2003) Conditions of formation of uranium minerals in the oxidation zone of uranium depos-its. Geolog Rud Mestor 45: 148-151 (in Russian)

Brugger J, Burns c p, Meisser N (2003) Contribution to the acid drainage of uranium minerals: marecottite and the zippeite group. Amer Miner 88: 676-685
http://doi.org/10.2138/am-2003-0421

Burnham CW (1962) Lattice constant refinement. Carn Inst Wash Year Book 61: 132-135

Burns PC (2000) A new uranyl phosphate chain in the structure of parsonsite. Amer Miner 85: 801-805
http://doi.org/10.2138/am-2000-5-621

Burns PC (2005) U⁶⁺ minerals and inorganic compounds: insights into an expanded structural hierar-chy of crystal structures. Canad Mineral 43: 1839-1894
http://doi.org/10.2113/gscanmin.43.6.1839

Burns PC, Miller ML, Ewing RC (1996) U⁶⁺ minerals and inorganic phases: a comparison and hierar-chy of crystal structures. Canad Mineral 34: 845-880

Chernikov AA (1981) Behaviour of uranium in the supergene zone. Nedra, Moscow, pp 1-207 (in Russian)

Coelho AA, Cheary RW (1997) X-ray Line Profile Fitting Program, XFIT. Program.

Coutinho JMV, Atencio D (2000) Phosphuranylite from Minas Gerais, Brazil and its identity with yingjiangite. In: 4^th International Mineralogy in Museums Conference, Melbourne: 35

Čejka J (1999) Infrared spectroscopy and thermal analysis of the uranyl minerals. In: Burns PC, Ewing RC (eds) Ura-nium: Mineralogy, Geochemistry and the Environment. Mineralogical Society of America and Geochemical Society Reviews in Mineralogy and Geochemistry 38, Washington, pp 521-622
http://doi.org/10.1515/9781501509193-017

Čejka J, Urbanec Z, Mrázek Z (1986) Secondary uranium minerals in the collection of the National Museum in Prague XII. Uranyl silicates. Čas Nár muz, ř přírod 45: 30-44 (in Czech)

Čejka J Jr, Muck A, Čejka J (1984) To the infrared spectroscopy of natural uranyl phosphates. Phys Chem Miner 11: 172-177
http://doi.org/10.1007/BF00387848

Dai YS, Hughes JM (1989) Crystal-structure refinements of vanadinite and pyromorphite. Canad Mineral 27: 189-192

Dai YS, Hughes JM, Moore PB (1991) The crystal structures of mimetite and clinomimetite Pb₅(AsO₄)₃Cl. Canad Mineral 29: 369-376

Deliens M (1977) Associations de minéraux secondaires d’uranium à Shinkolobwe (région du Shaba, Zaïre). Bull Soc Fr Minéral Cristallogr 100: 32-38
http://doi.org/10.3406/bulmi.1977.7115

Demartin F, Diella V, Donzelli S, Gramaciolli CM, Pilati T (1991) The importance of accurate crystal structure deter-mination of uranium minerals. I. Phosphuranylite KCa(H₃O)₃(UO₂)₇(PO₄)₄O₄.8H₂O. Acta Crystallogr B47: 439-466

Dietrich JÉ, Orlic M, Permingeat F (1969) L’agardite, une nouvelle espéce minerále, et le probléme du chlorotile. Bull Soc Fr Minéral Cristallogr 92: 420-434
http://doi.org/10.3406/bulmi.1969.6392

Finch RJ, Ewing RC (1992): The corrosion of uraninite under oxidizing conditions. J Nucl Mater 190: 133-156
http://doi.org/10.1016/0022-3115(92)90083-W

Finch RJ, Murakami T (1999) Systematics and paragenesis of uranium minerals. In: Burns PC, Ewing RC (eds) Uranium: Mineralogy, Geochemistry and the Environment. Mineralogical Society of America and Geochemical Society Reviews in Mineralogy and Geochemistry 38, Washington, pp 91-179

Frost RL, Weier ML (2004) Hot-stage Raman spectroscopic study of the thermal decomposition of saléeite. J Raman Spectr 35: 299-307
http://doi.org/10.1002/jrs.1150

Frost RL, Čejka J, Weier M, Martens WM (2006a) A Raman spectroscopic study of the uranyl phosphate mineral parsonsite. J Raman Spectr 37: 879-891
http://doi.org/10.1002/jrs.1517

Frost RL, Čejka J, Weier M, Ayoko GA (2006b) Raman spectroscopic study of the uranyl phosphate mineral dewindtite. J Raman Spectr 37: 1362-1367
http://doi.org/10.1002/jrs.1551

Frost RL , Čejka J, Ayoko GA (2008) Raman spectroscopic study of the uranyl phosphate minerals phosphuranylite and yingjiangite. J Raman Spectr 39: 495-502
http://doi.org/10.1002/jrs.1868

Ginderów D (1988) Structure de l’uranophane alpha, Ca(UO₂)₂(SiO₃OH)₂ . 5 H₂O. Acta Cryst C44: 421-424
http://doi.org/10.1107/S0108270187011491

Grenthe I, Fuger J, Konings RJM, Lemire RJ, Muller AB, Nguyen-Trung Cregu C, Wanner H (2004) Chemical thermo-dynamics of Uranium (reprint). OECD Nuclear Energy Agency, Issy-les-Moulineaux, France, pp 1-715

Hoggart DD, Nuffield EW (1954) Studies of radioactive compounds: VII - phosphuranylite and dewindtite. Amer Miner 39: 444-447

Huynen AM, Piret-Meunier J, van Meerssche M (1963) Structure de la kasolite. Bull Cl Sci (Acad Roy Belg) 49: 192-201

Jansa J, Novák F, Pauliš P, Scharmová M (1998) Supergene minerals of the Sn-W Cínovec deposit, Krušné hory Mts. (Czech Republic). Bull mineral petrolog Odd Nár Muz (Praha) 6: 83-101 (in Czech)

Jingyi Z, Anwa W, Wenshu G (1992) New data on yingjiangite. Acta Petrol Mineral 11: 178-184 (in Chinese with Eng-lish abstract)

Klomínský J (1969) The Krkonoše-Jizera granitoid massif. Sbor Geol Věd 15: 1-134

Kohlmann M, Sowa H, Reithmayer K, Schulz H, Kruger RR, Abriel W (1994) Structure of a Y_(1-x)(Gd,Dy,Er)_xPO₄ . 2H₂O microcrystal using synchrotron radia-tion. Acta Cryst C50: 1651-1652

Langmuir D (1978) Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits. Geochim Cosmochim Acta 42: 547-569
http://doi.org/10.1016/0016-7037(78)90001-7

Locock AJ (2004) Crystal chemistry of uranyl phosphates, arsenates and oxysalts of chromium(V): implications for remediation. Unpublished PhD. thesis, University of Notre Dame, Notre Dame, pp 1-477

Locock AJ, Burns PC (2003) Crystal structures and synthesis of the copper-dominant members of the autunite and meta-autunite groups: torbernite, zeunerite, metatorbernite and metazeunerite. Canad Mineral 41: 498-502

Locock AJ, Burns PC, Flynn TM (2005) The role of water in the structures of synthetic hallimondite, Pb₂[(UO₂)(AsO₄)₂](H₂O)_n and syn-thetic parsonsite, Pb₂[(UO₂)(PO₄)₂](H₂O)_n, 0 <= n <= 0.5. Amer Miner 90: 240-246
http://doi.org/10.2138/am.2005.1705

Makarov ES, Ivanov VI (1960) The crystal structure of meta-autunite, Ca(UO₂)₂(PO₄)₂. 6H₂O. Doklady Akademii Nauk USSR 132: 601-603 (in Russian)

Mereiter K, Preisinger A (1986) Krystallstrukturdaten der Wismutminerale Atelestit, Mixit und Pucherit. Anz Österr Akad Wiss 123: 79-81

Miller SA, Taylor JC (1986) The crystal structure of saléeite Mg[UO₂PO₄]₂ . 10H₂O. Z Kristallogr 177: 247-253
http://doi.org/10.1524/zkri.1986.177.3-4.247

Moenke H (1966) Mineralspektren II. Akademie Verlag Berlin, pp 1-22

Olmi F, Sabelli C, Trosti-Ferroni R (1991) A contribution to the crystal chemistry of mixite group minerals from Sar-dinia (Italy). Neu Jb Mineral, Mh 11: 487-499

Ondruš P, Hyršl J (1989) New finds and revision of secondary minerals from Příbram district. Acta Univ Carol, Geol: 521-533

Ondruš P, Veselovský F, Hloušek J, Skála R, Vavřín I, Frýda J, Čejka J, Gabašová A (1997) Secondary minerals of the Jáchymov (Joachimsthal) ore district. J Czech Geol Soc 42: 3-76
Direct link

Pauliš P, Ševců J, Novotný J, Rendl J (1999) Saléeite and minerals of the phosphuranylite-yingjiangite series from the Kladská near Mariánské Lázně uranium deposit. Bull Czech Geol Surv 74: 47-49

Pauliš P, Kopecký S, Novák F (2005) Uranophane from the deposit of uranium ores Medvědín near Špindlerův Mlýn. Opera Corc 42: 69-72 (in Czech)

PDF-2 - Powder diffraction File (ICDD- International Centre for Diffraction Data) ICDD (2003) „Powder Diffraction File“, International Centre for Diffraction Data, edited by Frank McClune, 12 Campus Boulevard, Newton Square, Pennsylvania 19073-3272

Peacor DR, Dunn PJ (1982) Petersite, a REE and phosphate analog of mixite. Amer Miner 67: 1039-1042

Piret P, Deliens M (1980) Nouvelles données sur la saléeite holotype de Shinkolobwe. Bull Minéral 103: 630-632
http://doi.org/10.3406/bulmi.1980.7430

Piret P, Piret-Meunier J (1991) Composition chimique et structure crystalline de la phosphuranylite Ca(UO₂)[(UO₂)₃(OH)₂(PO₄)₂]₂ . 12 H₂O. Eur J Mineral 3: 69-77
http://doi.org/10.1127/ejm/3/1/0069

Piret P, Piret-Meunier J, Deliens M (1990) Composition chimique et structure cristalline de la dewindtite Pb₃[H(UO₂)₃O₂(PO₄)₂]₂.12H₂O. Eur J Mineral 2: 399-405
http://doi.org/10.1127/ejm/2/3/0399

Plášil J (2007) A study of supergene mineralization at the Medvědín uranium deposit, Krkonoše Mts., Czech Republic. Unpublished BSci thesis, Faculty of Science, Charles University, Prague, pp 1-72 (in Czech)

Plášil J, Sejkora J, Ondruš P, Veselovský F, Beran P, Goliáš V. (2006a) Supergene minerals in the Horní Slavkov ura-nium ore district, Czech Republic. J Czech Geol Soc 51: 149-158
http://doi.org/10.3190/jcgs.991

Plášil J, Sejkora J, Škoda R, Goliáš V (2006b) Supergene Y, REE minerals from the Medvědín deposit, The Krkonoše (Giant) Mts., Czech Republic. Miner Pol (Special papers) 28: 181-183

Plášil J, Sejkora J, Goliáš V (2008) Bismuth mineralization from the uranium deposit Medvědín near Špindlerův Mlýn. Opera Corc 45: 5-11 (in Czech with English abstract)

Pluskal O (1993): Uranium mineral resources in the Czech Republic (The uranium world market and the Czech Repub-lic, part II). Faculty of Science, Charles University, Prague, pp 1-99 (in Czech)

Pouchou JL, Pichoir F (1985) “PAP“ procedure for improved quantitative microanalysis. Microbeam Anal 20: 104-105

Rosenzweig A, Ryan RR (1977) Kasolite, Pb(UO₂)(SiO₄)(H₂O). Cryst Struct Comm 6: 617-621

Ross M, Evans HT, Appleman DE (1964) Studies of the torbernite minerals (II): The crystal structure of meta-torbernite. Amer Miner 49: 1603-1621

Sejkora J (1992) Mineralogy of oxidic minerals containing bismuth. Unpublished MSci thesis, Faculty of Science, Charles University, Prague, pp 1-154 (in Czech)

Sejkora J (1993) Phosphuranylite occurrences in the Czech Republic. In: Sbor V min cykl sem (Horní Bečva), Ústí nad Labem, pp 97-99 (in Czech)

Sejkora J, Šrein V (1996) Contribution to crystal chemistry of mixite from localities in the Bohemian Massif. Zpr geol výzk v r 1995: 153-155 (in Czech)

Sejkora J, Veselovský F, Šrein V (1994) The supergene mineralization of uranium occurrence Rýžoviště near Harra-chov (Krkonoše Mts., Czech Republic). Acta Mus Nat Prague, ser B (Historia Nat) 50: 55-91

Sejkora J, Mazuch J, Abert F, Šrein V, Novotná M (1997a) Supergene mineralization of the Slavkovice uranium deposit in western Moravia. Acta Mus Moraviae, Sci Nat 81: 3-24 (in Czech)

Sejkora J, Gabašová A, Novotná M (1997b) Mixite from Smrkovec near Mariánské Lázně. Bull mineral-petrolog Odd Nár Muz (Praha) 4-5: 185-187 (in Czech)

Sejkora J, Čejka J, Kotrlý M, Novotná M (1998) Saléeite from uranium exploration dumps at Rýžoviště near Harra-chov. Bull mineral-petrolog Odd Nár Muz (Praha) 6: 217-221 (in Czech)

Sejkora J, Řídkošil T, Šrein V (1999) Zálesíite, a new mineral of the mixite group, from Zálesí, Rychlebské hory Mts., Czech Republic. Neu Jb Mineral, Abh 175: 150-124

Sejkora J, Čejka J, Pauliš P (2003) Dewindtite - a rare phosphate of lead and uranyl from uranium exploration site at Rýžoviště near Harrachov (Krkonoše Mts.). Bull mineral-petrolog Odd Nár Muz (Praha) 11: 177-183 (in Czech)

Sejkora J, Novotný P, Novák M, Šrein V, Berlepsch P (2005) Calciopetersite from Domašov nad Bystřicí, northern Moravia, Czech Republic, a new mineral species of the mixite group. Can Mineral 43: 1393-1400
http://doi.org/10.2113/gscanmin.43.4.1393

Sejkora J, Ondruš P, Fikar M, Veselovský F, Mach Z, Gabašová A, Škoda R, Beran P (2006) Supergene minerals at the Huber stock and Schnöd stock deposits, Krásno ore district, the Slavkovský les area, Czech Republic. J Czech Geol Soc 51: 57-101
http://doi.org/10.3190/jcgs.989

Sejkora J, Čejka J, Šrein V (2007) Supergene uranium mineralization from Horní Halže near Mědenec (Krušné hory Mountains), Czech Republic. J Geosci 52: 199-210
http://doi.org/10.3190/jgeosci.013

Sowder AG, Clark SB, Fjeld RA (2000) Dehydration of synthetic autunite hydrates. Radiochim Acta 88: 533-538
http://doi.org/10.1524/ract.2000.88.9-11.533

Stergiou AC, Rentzeperis PJ, Sklavounos S (1993) Refinement of the crystal structure of metatorbernite. Z Kristallogr 205: 1-7
http://doi.org/10.1524/zkri.1993.205.Part-1.1

Strukov NG (1958) Geological report on closing the deposit. MS Diamo Archive, Příbram, pp 15 (in Czech)

Škácha P, Sejkora J (2001) Kasolite from the Jánská vein, Březové Hory deposit, Příbram. Bull mineral-petrolog Odd Nár Muz (Praha) 9: 272-273 (in Czech)

Taylor SR, McLennan SM (1985) The Continental Crust: its Composition and Evolution. Blackwell Scientific Publish-ers, Oxford, pp 1-321

Thoreau J, Vaes JF (1932) La saléeite, nouveau mineral uranifére. Bull Soc belge Géol 42: 96-99

Veselý T (1982) Small uranium deposits in crystalline units of the Bohemian Massif. Part III.: The region of northwest-ern and northern Bohemia. Geol a hydrometalurg uranu 6: 3-46 (in Czech)

Vochten R, van Haverbeke L, van Springel K (1991) Transformation of chernikovite into parsonsite and study of its solubility product. Neu Jb Mineral, Mh 1991: 551-558.

Walenta K (1965a) Die Uranglimmergruppe. Chem Erde 24: 254-275

Walenta K (1965b) Hallimondite, a new uranium mineral from the Michael Mine near Reichenbach (Black Forest, Germany). Amer Miner 50: 1143-1157

Walenta K, Theye T (2004) Agarit-(Ce) von der Grube Clara im mittleren Schwarzwald, Aufschluss 55: 17-23

Winchester JA, Patočka F, Kachlík V, Melzer M, Nawakovski C, Crowley QG, Floyd PA (2003) Geochemical discrimi-nation of metasedimentary sequences in the Krkonoše-Jizera terrane (West Sudetes, Bohemian Massif): paleotec-tonic and stratigraphic constrains. Geol Carpath 54: 267-280

Wise WS (1978) Parnauite and goudeyite, two new copper arsenate minerals from the Majuba Hill Mine, Pershing County, Nevada. Amer Miner 63: 704-708

Wronkiewicz DJ, Bates JK, Gerding TJ, Veleckis E, Tani BS (1992) Uranium release and secondary phase formation during unsaturated testing of UO₂ at 90 °C. J Nucl Mater 190: 107-127
http://doi.org/10.1016/0022-3115(92)90081-U

Zhangru C, Yuzhu H, Xiaofa G (1990) A new mineral - yingjiangite. Acta Mineral Sin 10: 102-105 (in Chinese with English Abstract)