Original Paper
Oxide minerals in the granitic cupola of the Jálama Batholith, Salamanca, Spain. Part II: Sn, W and Ti minerals in intra-granitic quartz veins
Journal of Geosciences, volume 57 (2012), issue 3, 155 - 171
DOI: http://doi.org/10.3190/jgeosci.119
Amichba TM, Dubakina LS (1974) “Wolframoixiolite” in ores of tungsten deposits of Yakutia. Sborn Nauchn Trud Mosk Otdel Vses Mineral Obshch 1974, pp 11-18 (in Russian)
Antignano A, Manning CE (2008) Rutile solubility in H2O, H2O-SiO2, and H2O-NaAlSi3O8 fluids at 0.7-2.0 GPa and 700-1000 °C: implications for mobility of nominally insoluble elements. Chem Geol 255: 283-293
Audétat A, Keppler H (2005) Solubility of rutile in subduction zone fluids, as determined by experiments in the hydrothermal diamond anvil cell. Earth Planet Sci Lett 232: 393-402
Auriscchio C, De Vito C, Ferrini V, Orlandi P (2002) Nb and Ta oxide minerals in the Fonte del Petre granitic pegmatite dike, Island of Elba, Italy. Canad Mineral 40: 799-814
Ayers JC, Watson EB (1993) Rutile solubility and mobility in supercritical aqueous fluids. Contrib Mineral Petrol 114: 321-330
Barsukov VL, Sushchevskaya TM (1973) On the composition evolution of hydrothermal solutions in the process of the formation of the tin ore deposits. Geokhimiya 4: 491-503 (in Russian)
Beddoe-Stephens B, Fortey NJ (1981) Columbite from the Carrock Fell tungsten deposit. Mineral Mag 44: 217-223
Beurlen H, Da Silva MRR, Thomas R, Soares DR, Olivier P (2008) Nb-Ta- (Ti-Sn) oxide mineral chemistry as tracer of rare-element granitic pegmatite fractionation in the Borborema Province, Northeastern Brazil. Miner Depos 43: 207-228
Bons PD (2000) The formation of veins and their microstructures. In: Jessell MW, Urai JL (eds) Stress, Strain and Structure - A volume in honour of WD Means. J Virtual Expl 2 paper 4, §:10.3809/jvirtex.2000.00007
Breiter K, Škoda R, Uher H (2007) Nb-Ta-Ti-W-Sn-oxide minerals as indicators of peraluminous P- and F-rich granitic system evolution: Podlesí, Czech Republic. Mineral Petrol 91: 225-248
Burt DM (1981) Acidity-salinity diagrams. Application to greisen and porphyry deposits. Econ Geol 76: 832-843
Carruzzo S, Clarke DB, Pelrine KM, MacDonald MA (2006) Texture, composition and origin of rutile in the South Mountain Batholith, Nova Scotia. Canad Mineral 44: 715-729
Clark JR, Williams-Jones AE (2009) Compositional variability of rutile in hydrothermal ore deposits. Am Geophys Union Spring Meeting 2009, abstract #V14A-01
Černý P, Chapman R (2001) Exsolution and breakdown of scandian and tungstenian Nb-Ta-Ti-Fe-Mn phases in niobian rutile. Canad Mineral 39: 93-101
Černý P, Ercit S (1985) Some recent advances in the mineralogy and geochemistry of Nb and Ta in rare-element granitic pegmatites. Bull Minéral 108: 499-532
Černý P, Ercit S (1989) Mineralogy of niobium and tantalum: crystal chemical relationships, paragenetic aspects and their economic implications. In: Möller P, Černý P, Saupé F (eds) Lanthanides, Tantalum and Niobium. SGA Special Publications 7: Springer-Verlag, New York, pp 27-29
Černý P, Ercit TS (2005) The classification of granitic pegmatites revisited. Canad Mineral 43: 2005-2026
Černý P, Meintzer RE, Anderson AJ (1985) Extreme fractionation in rare-element granitic pegmatites: selected examples of data and mechanism. Canad Mineral 23: 381-421
Černý P, Goad BE, Hawthorne C, Chapman R (1986) Fractionation trends of the Nb- and Ta-bearing oxide minerals in the Greer Lake pegmatitic granite and its pegmatite aureole, southeastern Manitoba. Amer Miner 71: 501-517
Černý P, Ercit TS, Wise MA, Chapman R, Buck M (1998) Compositional, structural and phase relationships in titanian ixiolite and titanian columbite-tantalite. Canad Mineral 36 574-561
Černý P, Novák M, Chapman R, Ferreira K (2007a) Subsolidus behavior of niobian rutile from the Písek region, Czech Republic: a model for exsolution in W- and Fe2+ >> Fe3+-rich phases. J Geosci 52: 143-159
Černý P, Ercit TS, Smeds S-A, Groat LA, Chapman R (2007b) Zirconium and hafnium in minerals of the columbite and wodginite groups from granitic pegmatites. Canad Mineral 45: 185-202
Dingwell DB, Scarfe CM, Cronin DJ (1985) The effect of fluorine on the viscosities of melts in the system Na2O-Al2O3-SiO2: implications for phonolites, trachytes and rhyolites. Amer Miner 70:80-87
Eadington PJ (1983) A fluid inclusion investigation of ore formation in a tin-mineralized granite, New England, New South Wales. Econ Geol 78: 1204-1221
Ercit TS, Černý P, Hawthorne FC, McCammon CA (1992) The wodginite group. II. Crystal chemistry. Canad Mineral 30: 613-631
Fernández-Leyva C (2007) Metallogenetic Study of the Jálama Batholith and Surroundings. Unpublished Ph.D. thesis, Universidad Politéctnica de Madrid, Madrid, pp 1-188 (in Spanish)
Giordano D, Romano C, Poe B, Dingwell, DB, Behrens H (2004) The combined effects of wáter and fluorine on the viscosity of silicic magmas. Geochim Cosmochim Acta 68: 5159-5168
Giuliani G (1987) La cassitérite zone du gisement de Sokhret Allal (Granite des Zaër; Maroc Central): composition chimique et phases fluides associées. Miner Depos 22: 253-261
Gouanvic Y, Babkine J (1985) Metallogenie du gisement à tunstène-etain de Monteneme (N.W. Galice, Espagne). Miner Depos 20: 8-15
Groves DJ, Baker WE (1972) The regional variation in composition of wolframites from Tasmania. Econ Geol 67: 362-368
Haapala I (1997) Magmatic and postmagmatic processes in tin-mineralized granites: topaz-bearing leucogranite in the Eurajoki Rapakivi Granite Stock, Finland. J Petrol 38: 1645-1659
Hata K, Higuchi M, Takahashi J, Kodaira K (1996) Floating zone growth and characterization of aluminium-doped rutile single crystals. J Cryst Growth 163: 279-284
Horng W-S, Hess PC, Gan H (1999) The interaction between M+5 cations (Nb+5, Ta+5, or P+5) and anhydrous haplogranite melts. Geochim Cosmochim Acta 63: 2419-2428
Johan V, Johan Z (1994) Accessory minerals of the Cínovec (Zinnwald) granite cupola, Czech Republic. Part 1: Nb-, Ta- and Ti-bearing oxides. Mineral Petrol 51: 323-343
Keppler H (1993) Influence of fluorine on the enrichment of high field strength trace elements in granitic rocks. Contrib Mineral Petrol 114: 479-488
Lerouge C, Deschamps Y, Piantone P, Gilles C, Breton J (2007) Metal-carrier accessory minerals associated with W ± Sn mineralization, La Châtaigneraie tungsten ore district, Massif Central, France. Canad Mineral 45: 875-889
Linnen RL (1998) The solubility of Nb-Ta-Zr-Hf-W in granitic melts with Li and Li + F: constraints for mineralization in rare metal granites and pegmatites. Econ Geol 93: 1013-1025
Linnen RL, Keppler H (1997) Columbite stability in granitic melts: consequences for the enrichment and fractionation of Nb and Ta in the Earth crust. Contrib Mineral Petrol 128: 213-227
Llorens T (2011) The Sn-W-(Nb-Ta) Magmatic-Hydrothermal Mineralizations of the Navasfrías District (SW Salamanca). Ph.D. thesis, Salamanca University. Vítor Collection 290: pp 1-353. ISBN 978-84-7800-088-3 (in Spanish)
Llorens T, Moro MC (2007) Preliminary study of intragranitic pegmatites in the Sn-W- (Au) district of Navasfrías (SW of Salamanca, Spain). In: Martins T, Vieira R (eds) Granitic Pegmatites: the State of the Art, Book of Abstracts. Universidad do Porto, Department of Geology, Porto, Memórias 8: 56-57
Llorens T, Moro MC (2008) Al-Fe-Mn phosphates in the intra-granitic pegmatites of the Navasfrías district (SW Salamanca). In: Delgado J, Astilleros JM, Bauluz B, Calvo B, González I, Herrero JM, López J, Proenza J, Rodríguez C (eds) XXVIII Reunión de la Sociedad Española de Mineralogía, XXI Reunión de la Sociedad Española de Arcillas. Sociedad Española de Mineralogía, Macla 9: 145-146 (in Spanish)
Llorens T, Moro MC (2010a) Microlite and tantalite in the LCT granitic pegmatites of La Canalita, Navasfrías Sn-W District, Salamanca, Spain. Canad Mineral 48: 549-564
Llorens T, Moro MC (2010b) Columbite-group minerals in the Cruz del Rayo pegmatite dikes, SW Salamanca, Spain. In: Pál-Molnár E, Árkai P, Buda G, Dódony I, Fancsik T, Földessy J, Harangi S, Hetényi M, Koroknai B, Tóth TM, Papp G, Pósfai M, Rózsa P, Sipos P, Szabó C, Szakáll S, Szederkényi T, Viczián I, Zelenka T (eds) IMA 2010, Bonds and Bridges, CD of Abstracts. Department of Mineralogy, Geochemistry and Petrology, University of Szeged. Acta Mineral Petrogr, Abstr Ser, Szeged 6: 167
Llorens T, Moro MC (2010c) Nb-Ta-oxide minerals in the LCT pegmatites of La Canalita, SW Salamanca, Spain. In: Pál-Molnár E, Árkai P, Buda G, Dódony I, Fancsik T, Földessy J, Harangi S, Hetényi M, Koroknai B, Tóth TM, Papp G, Pósfai M, Rózsa P, Sipos P, Szabó C, Szakáll S, Szederkényi T, Viczián I, Zelenka T (eds) IMA2010, Bons and Bridges, CD of Abstracts. Budapest, Department of Mineralogy, Geochemistry and Petrology, University of Szeged. Acta Mineral Petrogr, Abstr Ser, Szeged 6: 167
Llorens T, Moro MC (2012a) Fe-Mn phosphate associations as indicators of the magmatic-hydrothermal and supergene evolution of the Jálama Batholith in the Navasfrías Sn-W District, Salamanca, Spain. Mineral Mag 76: 1-24
Llorens T, Moro MC (2012b) Oxide minerals in the granitic cupola of the Jálama Batholith, Salamanca, Spain. Part I: accessory Sn, Nb, Ta and Ti minerals in leucogranites, aplites and pegmatites. J Geosci 57: 25-43
London D (1987) Internal differentiation of rare-element pegmatites: effects on boron, phosphorus, and fluorine. Geochim Cosmochim Acta 51: 403-420
Manning CE, Wilke M, Schmidt C, Cauzid J (2008) Rutile solubility in albite-H2O and Na2Si3O7-H2O at high temperatures and pressures by in-situ synchrotron radiation micro-XRF. Earth Planet Sci Lett 272: 730-737
Martínez Catalán JR, Martínez Poyatos D, Bea F (2004) Centro-Iberic Zone. In: Vera JA (ed) Geology of Spain. SGE-IGME, Madrid, Spain, pp 68-133 (in Spanish)
Martins T, Lima A, Simmons S, Falster A, Noronha F (2011) Geochemical fractionation of Nb-Ta oxides in Li-bearing pegmatites from the Barroso-Alvão pegmatite field, Northern Portugal. Canad Mineral 49: 777-791
Möller P, Dulski P, Szacki W, Malow G, Riedel E (1988) Substitution of tin in cassiterite by tantalum, niobium, tungsten, iron and manganese. Geochim Cosmochim Acta 52: 1497-1503
Moro MC, Llorens T (2008) Triplite-apatite-isokite in the Sn-W intragranitic quartz veins of La Salmantina (Navasfrías, SW Salamanca). In: Delgado J, Astilleros JM, Bauluz B, Calvo B, González I, Herrero JM, López J, Proenza J, Rodríguez C (eds) XXVIII Reunión de la Sociedad Española de Mineralogía, XXI Reunión de la Sociedad Española de Arcillas. Sociedad Española de Mineralogía, Macla 9: 167-168 (in Spanish)
Moro MC, Villar P, Fadón O, Fernández A, Cembranos ML, Crespo JL (2001) Bismuthinite, pavonite, gustavite and lillianite homologues in the Sn-W deposits of the Navasfrías district (SW Salamanca). Bol Soc Esp Mineral 24-A: 161-162 (abstract, in Spanish)
Müller A, Halls C (2005) Rutile - the tin-tungsten host in the intrusive tourmaline breccia at Wheal Remfry, SW England. In: Mao J, Bierlein FP (eds) Mineral Deposit Research: Meeting the Global Challenge. Proceedings of the Eighth Biennial SGA Meeting, Beijing, pp 441-444
Neiva AMR (1996) Geochemistry of cassiterite and its inclusions and exsolution products from tin and tungsten deposits in Portugal. Canad Mineral 34: 745-768
Neiva AMR (2008) Geochemistry of cassiterite and wolframite from tin and tungsten quartz veins in Portugal. Ore Geol Rev 33: 221-238
Novák M, Johan Z, Škoda R, Černý P, Šrein V, Veselovský F (2008) Primary oxide minerals in the system WO3-Nb2O5-TiO2-Fe2O3-FeO and their breakdown products from the pegmatite No. 3 at Dolní Bory-Hatě, Czech Republic. Eur J Mineral 20: 487-499
Pal DC, Mishra B, Bernhardt H-J (2007) Mineralogy and geochemistry of pegmatite-hosted Sn-, Ta-Nb-, and Zr-Hf-bearing minerals from the southeastern part of the Bastar-Malkangiri pegmatite belt, Central India. Ore Geol Rev 30: 30-55
Pirajno F (1992) Hydrothermal mineral deposits. Principles and Fundamental Concepts for the Exploration Geologist. Springer-Verlag, Heidelberg, pp 1-710
Pollard PJ (1983) Magmatic and postmagmatic processes in the formation of rocks associated with rare-element deposits. Trasn Inst Min Metall 92: B1-B9
Polya DA (1988) Compositional variation in wolframites from the Barroca Grande mine, Portugal: evidence for fault-controlled ore formation. Mineral Mag 52: 497-503
Ramírez JA (1996) Petrological, Geochemical and Isotopic Study of the Jálama Batholith (North of Extremadura). Unpublished Ph.D. thesis, University of Granada, pp 1-201 (in Spanish)
Ramírez JA, Grundvig S (2000) Causes of geochemical diversity in peraluminous granitic plutons: the Jálama Pluton, Central-Iberian Zone (Spain and Portugal). Lithos 50: 171-190
Rapp JF, Klemme S, Butler IB, Harley SL (2010) Extremely high solubility of rutile in chloride and fluoride-bearing metamorphic fluids: an experimental investigation. Geology 38: 323-326
René M, Škoda R (2011) Nb-Ta-Ti oxides fractionation in rare-metal granites: Krásno-Horní Slavkov ore district, Czech Republic. Mineral Petrol 103: 37-48
Rice CM, Darke KE, Still JW (1998) Tungsten-bearing rutile from the Kori Kollo gold mine, Bolivia. Mineral Mag 62: 421-429
Ruiz C, Fernández-Leyva C, Locutura J (2008) Geochemistry, geochronology and mineralisation potential of the granites in the Central Iberian Zone: the Jálama Batholith. Chem Erde 68: 413-429
Ryzhenko B, Kovalenko N, Prisyagina N (2006) Titanium complexation in hydrothermal systems. Geochem Int 44: 879-895
Spilde MN, Shearer CK (1992) A comparison of tantalum-niobium oxide assemblages in two mineralogically distinct rare-element granitic pegmatites, Black Hills, South Dakota. Canad Mineral 30: 719-737
Suwinonprecha P, Černý P, Friedrich G (1995) Rare metal mineralization related to granites and pegmatites, Phuket, Thailand. Econ Geol 90: 603-615
Tindle AG, Breaks FW (1998) Oxide minerals of the Separation Rapids rare-element granitic pegmatite group, northwestern Ontario. Canad Mineral 36: 609-635
Tindle AG, Webb PC (1989) Niobian wolframite from Glen Gairn in the eastern Highlands of Scotland: a microprobe investigation. Geochim Cosmochim Acta 53: 1921-1935
Tindle AG, Breaks FW, Webb PC (1998) Wodginite-group minerals from the Separation Rapids rare-element granitic pegmatite group, northwestern Ontario. Canad Mineral 36: 637-658
Tropper P, Manning CE (2005) Very low solubility of rutile in H2O at high pressure and temperature, and its implications for Ti mobility in subduction zones. Amer Miner 90: 502-505
Webster JD, Holloway JR (1990) Partitioning of F and Cl between magmatic hydrothermal fluids and highly evolved granitic magmas. In: Stein HJ, Hannah JL (eds) Ore-Bearing Granite Systems: Petrogenesis and Mineralizing Processes. Geological Society of America Special Papers 246: 21-34
Williamson BJ, Spratt J, Adams JT, Tindle AG, Stanley CJ (2000) Geochemical constraints from zoned hydrothermal tourmalines on fluid evolution and Sn mineralization: an example from fault breccias at Roche, SW England. J Petrol 41: 1439-1453
IF (WoS, 2023): 1.1
5 YEAR IF (WoS, 2023): 1.5
Policy: Open Access
ISSN: 1802-6222
E-ISSN: 1803-1943