Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original paper

Gwladys Steciuk, Jiří Sejkora, Jiří Čejka, Jakub Plášil, Jan Hloušek

Krupičkaite, Cu₆[AsO₃(OH)]₆·8H₂O, a new copper arsenate mineral from Jáchymov (Czech Republic)

Journal of Geosciences, volume 66 (2021), issue 1, 37 - 50

DOI: http://doi.org/10.3190/jgeosci.318

Borčinová Radková A, Jamieson H, Lalinská-Voleková B, Majzlan J, Števko M, Chovan M (2017) Mineralogical controls on antimony and arsenic mobility during tetrahedrite-tennantite weathering at historic mine sites Špania Dolina-Piesky and Ľubietová-Svätodušná, Slovakia. Amer Miner 102: 1091-1100

Brázda P, Palatinus L, Drahokoupil J, Knížek K, Buršík J (2016) Calcium-induced cation ordering and large resistivity decrease in Pr_0.3CoO₂. J Phys Chem Solids 96-97: 10-16
http://doi.org/10.1016/j.jpcs.2016.04.012

Burnham CW (1962) Lattice constant refinement. Carnegie Institute Washington Yearbook 61: 132-135

Burns PC, Hawthorne FC (1995) Coordination geom¬etry structural pathways in Cu²⁺ oxysalt minerals. Canad Mineral 33: 889-905

Čejka J, Sejkora J, Bahfenne S, Palmer SJ, Plášil J, Frost RL (2011) Raman spectroscopy of hydrogen-arsenate group (AsO₃OH) in solid-state compounds: cobalt mineral phase burgessite Co₂(H₂O)₄[AsO₃OH]₂•H₂O. J Raman Spec 42: 214-218
http://doi.org/10.1002/jrs.2675

Christy AG (2015) Causes of anomalous mineralogical diversity in the periodic table. Mineral Mag 79: 33-49
http://doi.org/10.1180/minmag.2015.079.1.04

Clabbers M, Gruene T, van Genderen E, Abrahams JP (2019) Reducing dynamical electron scattering reveals hydrogen atoms. Acta Crystallogr A75: 82-93
http://doi.org/10.1107/S2053273318013918

Cooper MA, Hawthorne FC (1995) The crystal structure of geminite, Cu²⁺(AsO₃OH) (H₂O), a heteropolyhedral sheet structure. Canad Mineral 33: 1111-1118

Đorđević T, Kolitsch U, Serafimovski T, Tasev G, Tepe N, Stöger-Pollach M, Hofmann T, Boev B (2019) Mineralogy and weathering of realgar-rich tailings at a former As-Sb-Cr mine at Lojane, North Macedonia. Canad Mineral 57: 403-423
http://doi.org/10.3749/canmin.1800074

Gagné OC, Hawthorne FC (2015) Comprehensive derivation of bond-valence parameters for ion pairs involving oxygen. Acta Crystallogr B71: 562-578
http://doi.org/10.1107/S2052520615016297

Gemmi M, Lanza AE (2019) 3D electron diffraction techniques. Acta Crystallogr B 75: 495-504
http://doi.org/10.1107/S2052520619007510

Gemmi M, Mugnaioli E, Gorelik TE, Kolb U, Palatinus L, Boullay P, Hovmöller S, Abrahams JP (2019) 3D Electron Diffraction: The Nanocrystallography Revolution. ACS Cent Sci 5: 1315-1329
http://doi.org/10.1021/acscentsci.9b00394

Hloušek J, Plášil J, Sejkora J, Škácha P (2014) News and new minerals from Jáchymov, Czech Republic (2003- 2014). Bull mineral-petrolog Odd Nár Muz (Praha) 22: 155-181 (in Czech)

Horák V, Škácha P, Plašil J (2014) History of mining on the Geister vein in the western part of the Jáchymov ore district. Bull mineral-petrolog Odd Nár Muz (Praha) 22: 192-192 (in Czech)

Keim MF, Staude M, Marquardt K, Bachmann K, Opitz J, Markl G (2018) Weathering of Bi-tennantite. Chem Geol 499: 1-25
http://doi.org/10.1016/j.chemgeo.2018.07.032

Kolb U, Gorelik T, Kubel C, Otten MT, Hubert V (2007) Towards automated diffraction tomography: Part I - Data acquisition. Ultramicroscopy 107: 507-513
http://doi.org/10.1016/j.ultramic.2006.10.007

Kolb U, Gorelik T, Kubel C, Otten MT (2008) Towards automated diffraction tomography. Part II - Cell parameter determination. Ultramicroscopy 108: 763-772
http://doi.org/10.1016/j.ultramic.2007.12.002

Krysiak Y, Barton B, Marler B, Neder RB, Kolb U (2018) Ab initio structure determination and quantitative disorder analysis on nanoparticles by electron diffraction tomography. Acta Crystallogr A74: 93-101

Latychevskaia T, Abrahams JP (2019) Inelastic scattering and solvent scattering reduce dynamical diffraction in biological crystals. Acta Crystallogr B75: 523-531
http://doi.org/10.1107/S2052520619009661

Majzlan J, Drahota P, Filippi M (2014) Parageneses and crystal chemistry of As minerals. Rev Mineral Geochem 79: 17-184
http://doi.org/10.2138/rmg.2014.79.2

Majzlan J, Kiefer S, Herrmann J, Števko M, Sejkora J, Chovan M, Lánczos T, Lazarov M, Gerdes A, Langenhorst F, Borčinová Radková A, Jamieson H, Milovský R (2018) Synergies in elemental mobility during weathering of tetrahedrite [(Cu,Fe,Zn)₁₂(Sb,As)₄S₁₃]: Field observations, electron microscopy, isotopes of Cu, C, O, radiometric dating, and water geochemistry. Chem Geol 48: 1-20
http://doi.org/10.1016/j.chemgeo.2018.04.021

Majzlan J, Plášil J, Dachs E, Benisek A, Mangold S, Škoda R, Abrosimova N (2021) Prediction and observation of formation of Ca-Mg arsenates in acidic and alkaline fluids: Thermodynamic properties and mineral assemblages at Jáchymov, Czech Republic and Rotgülden, Austria. Chem Geol 559: 119922
http://doi.org/10.1016/j.chemgeo.2020.119922

Mugnaioli E, Gorelik TE (2019) Structure analysis of materials at the order-disorder borderline using three-dimensional electron diffraction. Acta Crystallogr B75: 550-563
http://doi.org/10.1107/S2052520619007339

Mugnaioli E, Gorelik T, Kolb U (2009) “Ab-initio” structure solution from electron diffraction data obtained by a combination of automated diffraction tomography and precession technique. Ultramicroscopy 109: 758-765

Mugnaioli E, Lanza AE, Bortolozzi G, Righi L, Merlini M, Cappello V, Marini L, Athanassiou A, Gemmi M (2020) Electron Diffraction on Flash-Frozen Cowlesite Reveals the Structure of the First Two-Dimensional Natural Zeolite. ACS Cent Sci 6, 9: 1578-1586
http://doi.org/10.1021/acscentsci.9b01100

Neagu A, Tai CW (2017) Local disorder in Na_0.5Bi_0.5TiO₃ - piezoceramic determined by 3D electron diffuse scattering. Sci Rep 7: 1-12
http://doi.org/10.1038/s41598-017-12801-w

Ondruš P (1993) A computer program for analysis of X-ray powder diffraction patterns. Materials Science Forum, EPDIC-2, Enchede, 133-136, 297-300
http://doi.org/10.4028/www.scientific.net/MSF.133-136.297

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V (2003) Geology and hydrothermal vein system of the Jáchymov (Joachimsthal) ore district. J Czech Geol Soc 48: 3-18
Direct link

Palatinus L, Chapuis G (2007) Superflip - a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions. J Appl Cryst 40: 451-456
http://doi.org/10.1107/S0021889807029238

Palatinus L, Petříček V, Correa CA (2015a) Structure refinement using precession electron diffraction tomography and dynamical diffraction: theory and implementation. Acta Crystallogr A71: 235-24
http://doi.org/10.1107/S2053273315001266

Palatinus L, Correa CA, Steciuk G, Jacob D, Roussel P, Boullay P, Klementová M, Gemmi M, Kopeček J, Domeneghetti MCH, Cámara F, Petříček V (2015b) Structure refinement using precession electron diffraction tomography and dynamical diffraction: tests on experimental data. Acta Crystallogr B71: 740-751
http://doi.org/10.1107/S2052520615017023

Palatinus L, Brázda P, Boullay P, perez O, Klementová M, Petit S, Eigner V, Zaarour M, Mintova S (2017) Hydrogen positions in single nanocrystals revealed by electron diffraction. Science 355: 166-169
http://doi.org/10.1126/science.aak9652

Palatinus L, Brázda P, Jelínek M, Hrdá J, Steciuk G, Klementová M (2019) Specifics of the data processing of precession electron diffraction tomography data and their implementation in the program PETS2.0. Acta Crystallogr B75: 512-522

Petříček V, Dušek M, Palatinus L (2014) Crystallographic Computing System Jana 2006: general features. Z Kristallogr 229: 345-352
http://doi.org/10.1515/zkri-2014-1737

Plášil J, Sejkora J, Škoda R, Novák M, Kasatkin AV, Škácha P, Veselovský F, Fejfarová K, Ondruš P (2014a) Hloušekite, (Ni,Co)Cu₄(AsO₄)₂(AsO₃OH)₂(H₂O)₉, a new member of the lindackerite supergroup from Jáchymov, Czech Republic. Mineral Mag 78: 1341-1353
http://doi.org/10.1180/minmag.2014.078.5.16

Plášil J, Kasatkin AV, Škoda R, Škácha P (2014b) Klajite, MnCu₄(AsO₄)₂(AsO₃OH)₂(H₂O)₁₀, from Jáchymov (Czech Republic): the second world occurrence. Mineral Mag 78: 134-143
http://doi.org/10.1180/minmag.2014.078.1.09

Plášil J, Škácha P, Sejkora J, Škoda R, Novák M, Veselovský F, Hloušek J (2017) Babánekite, Cu₃(AsO₄)₂•8H₂O, from Jáchymov, Czech Republic - a new member of the vivianite group. J Geosci 62: 261-270
http://doi.org/10.3190/jgeosci.248

Pouchou JL, Pichoir F (1985) “PAP” (φρZ) procedure for improved quantitative microanalysis. In: Armstrong J T (ed) Microbeam Analysis. San Francisco Press, San Francisco, 104-106

Prencipe M, Pushcharovskii DYu, Sarom H, Ferraris D (1996) Comparative crystal chemistry of geminite Cu(AsO₃OH)·(H₂O) and minerals related to it. Vestnik Moskovskogo Universiteta, Seriya 4: Geologiya 4: 66-74

Sarp H, Černý R (1998) Description and crystal structure of yvonite. Amer Miner 83: 383-389
http://doi.org/10.2138/am-1998-3-423

Sejkora J, Plášil J, Veselovský F, Císařová I, Hloušek J (2011) Ondrušite, CaCu₄(AsO₄)₂(AsO₃OH)₂·10H₂O, a new mineral species from the Jáchymov ore district, Czech Republic: Description and crystal-structure determination. Canad Mineral 49: 885-897
http://doi.org/10.3749/canmin.49.3.885

Sejkora J, Plášil J, Ondruš P, Veselovský F, Císařová I, Hloušek J (2010c) Slavkovite, Cu₁₃(AsO₄)₆(AsO₃OH)₄·23H₂O, a new mineral species from Horní Slavkov and Jáchymov, Czech Republic: description and crystal-structure determination. Canad Mineral 48: 1157-1170
http://doi.org/10.3749/canmin.48.5.1157

Sejkora J, Čejka J, Frost RL, Bahfenne S, Plášil J, Keeffe EC (2010b) Raman spectroscopy of hydrogen-arsenate group (AsO₃OH) in solid-state compounds: copper mineral phase geminite Cu(AsO₃OH)·H₂O from different geological environments. J Raman Spectrosc 41: 1038-1043
http://doi.org/10.1002/jrs.2538

Sejkora J, Ondruš P, Novák M (2010a) Veselovskýite, triclinic (Zn,Cu,Co)Cu₄(AsO₄)₂(AsO₃OH)₂·9H₂O, a Zn-dominant analogue of lindackerite. N Jb Mineral Abh 187: 83-90
http://doi.org/10.1127/0077-7757/2010/0165

Sejkora J, Plášil J, Čejka J, Dolníček Z, Pavlíček R (2020) Molecular structure of the arsenate mineral chongite from Jáchymov - a vibrational spectroscopy study. J Geosci 65: 111-120
http://doi.org/10.3190/jgeosci.292

Škácha P, Plášil J, Horák V (2019) Jáchymov - mineralogická perla Krušnohoří. Academia, Praha, pp 1-688

Steciuk G, Ghazisaeed S, Kiefer B, Plášil J (2019a) Crystal structure of vyacheslavite, U(PO₄)(OH), solved from natural nanocrystal: a precession electron diffraction tomography (PEDT) study and DFT calculations. RSC Adv 9: 19657
http://doi.org/10.1039/C9RA03694F

Steciuk G, Palatinus L, Rohlíček J, Ouhenia S, Chateigner D (2019b) Stacking sequence variations in vaterite resolved by precession electron diffraction tomography using a unified superspace model. Sci Rep 9: 1-12
http://doi.org/10.1038/s41598-019-45581-6

Steciuk G, Škoda R, Rohlíček J, Plášil J (2020) Crystal structure of the uranyl-molybdate mineral calcurmolite Ca[(UO₂)₃(MoO₄)₂(OH)₄](H₂O)_˜5.0: insights from a precession electron-diffraction tomography study. J Geosci 65: 15-25
http://doi.org/10.3190/jgeosci.297

Steciuk G, Majzlan J, Plášil J (2021) Hydrogen disorder in kaatialaite Fe[AsO₂(OH)₂]5H₂O from Jáchymov, Czech Republic: determination from low-temperature 3D electron diffraction. IUCr Journal 8: 2052-2525
http://doi.org/10.1107/S2052252520015626

Vansant FK, Van Der Veken BJ, Desseyn HD (1973) Vibrational analysis of arsenic and its anions I. Description of the Raman spectra. J Mol Struct 15: 425-437
http://doi.org/10.1016/0022-2860(73)80012-2

Vincent R, Midgley PA (1994) Double conical beam-rocking system for measurement of integrated electron diffraction intensities. Ultramicroscopy 53: 271-282
http://doi.org/10.1016/0304-3991(94)90039-6

Zhao H, Krysiak Y, Hoffmann K, Barton B, Molina-Luna L, Neder RB, Kleebe HJ, Gesing TM, Schneider H, Fischer RX, Kolb U (2017) Elucidating structural order and disorder phenomena in mullite-type Al₄B₂O₉ by automated electron diffraction tomography. J Solid State Chem 249: 114-123
http://doi.org/10.1016/j.jssc.2017.02.023