Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original paper

Oleg S. Vereshchagin, Bernd Wunder, Ivan A. Baksheev, Franziska D.H. Wilke, Natalia S. Vlasenko, Olga V. Frank-Kamenetskaya

Ti⁴⁺ and Sn⁴⁺-bearing tourmalines - pressure control and comparison of synthetic and natural counterparts

Journal of Geosciences, volume 67 (2022), issue 2, 163 - 171

DOI: http://doi.org/10.3190/jgeosci.345

Aléonard S, Vicat J (1966) Borates de structure dolomite. Bull Soc franç Minéral Cristallogr 89: 271-272
http://doi.org/10.3406/bulmi.1966.5965

Arif M, Henry DJ, Moon CJ (2010) Cr-bearing tourmaline associated with emerald deposits from Swat, NW Pakistan: Genesis and its exploration significance. Amer Miner 95: 799-809
http://doi.org/10.2138/am.2010.3349

Armstrong JT (1995) CITZAF: a package of correction programs for the quantitative electron microbeam X-ray-analysis of thick polished materials, thin films, and particles. Microbeam Anal 4: 177-200

Baksheev IA, Prokof’ev VY, Ustinov VI (2001) Genesis of metasomatic rocks and mineralized veins at the Berezovskoe deposit, Central Urals: Evidence from fluid inclusions and stable isotopes. Geochem Int 39: S129-S144

Baksheev IA, Prokof’ev VY, Zaraisky GP, Chitalin AF, Yapaskurt VO, Nikolaev YN, Tikhomirov PL, Nagornaya EV, Rogacheva LI, Gorelikova NV, Kononov OV (2012) Tourmaline as a prospecting guide for the porphyry-style deposits. Eur J Mineral 24:957-979
http://doi.org/10.1127/0935-1221/2012/0024-2241

Baksheev IA, Vigasina MF, Yapaskurt VO, Bryzgalov IA, Gorelikova NV (2020) Tourmaline from the Solnechnoe tin deposit, Khabarovsk Krai, Russia. Mineral Mag 84:245-265
http://doi.org/10.1180/mgm.2019.72

Bannikova LA, Sushchevsicaya T, Spasennykh MY, Barsukov VL (1994) Isotopic and geochemical study of the conditions of tin ore formation of Solnechnoye deposit (Far East of Russia). Geochem J 28: 411-428
http://doi.org/10.2343/geochemj.28.411

Berryman EJ, Wunder B, Ertl A, Koch-Müller M, Rhede D, Scheidl K, Giester G, Heinrich W (2016) Influence of the X-site composition on tourmaline’s crystal structure: investigation of synthetic K-dravite, dravite, oxy-uvite, and magnesio-foitite using SREF and Raman spectroscopy. Phys Chem Miner 43: 83-102
http://doi.org/10.1007/s00269-015-0776-3

Berryman EJ, Wunder B, Rhede D (2014) Synthesis of K-dominant tourmaline. Amer Miner 99:539-542
http://doi.org/10.2138/am.2014.4775

Biagioni C, Bosi F, Mauro D, Skogby H, Dini A, Zaccarini F (2020) Dutrowite, IMA 2019-082. CNMNC Newsletter 53, Eur J Mineral 32 https://doi.org/10.5194/ejm-32-209-2020.
http://doi.org/10.5194/ejm-32-209-2020

Butler BCM (1978) Tin-rich garnet, pyroxene, and spinel from a slag. Mineral Mag 42:487-492
http://doi.org/10.1180/minmag.1978.042.324.11

Černý P, Fransolet A-M, Ercit TS, Chapman R (1988) Foordite SnNb₂O₆, a new mineral species, and the foordite-thoreaulite series. Canad Mineral 26: 889-898

Chernyshova IA, Vereshchagin OS, Malyshkina OV, Goncharov AG, Kasatkin IA, Murashko MN, Zolotarev AA, Frank-Kamenetskaya OV (2021) Tourmalines pyroelectric effect depending on the chemical composition and cation oxidation state. J Solid State Chem 303: 122512 https://doi.org/10.1016/j.jssc.2021.122512
http://doi.org/10.1016/j.jssc.2021.122512

Cooper M, Hawthorne F, Novák M, Taylor MC (1994) The crystal structure of tusionite, Mn²⁺Sn⁴⁺(BO₃)₂, a dolomite-structure borate. Canad Mineral 32: 903-907

da Costa IR, Antunes IMHR, Récio C (2021) The Mg/(Fe + Mg) ratio and the Ti and A site contents of tourmaline as promising indicators of granitic magma evolution. J Iber Geol 47:307-321
http://doi.org/10.1007/s41513-020-00158-5

Drivenes K (2021) Sn-rich tourmaline from the Land’s End granite, SW England. In: TUR2021 3rd International Conference on Tourmaline. pp 27-28

Ertl A, Topa D, Giester G, Rossman GR, Tillmanns E, Konzett J (2019) Sr-bearing high-pressure tourmaline from the Kreuzeck Mountains, Eastern Alps, Austria. Eur J Mineral 31:791-798
http://doi.org/10.1127/ejm/2019/0031-2863

Gadas P, Novák M, Škoda R, Cempírek J, Zachař A, Flégr T, Pezzotta F (2019) Titanium in tourmalines from granitic pegmatites and their exocontacts. Canad Mineral 57 (5): 745-747
http://doi.org/10.3749/canmin.AB00011

Grew ES, Hystad G, Hazen RM, Krivovichev SV, Gorelova LA (2017) How many boron minerals occur in Earth’s upper crust? Amer Miner 102: 1573-1587
http://doi.org/10.2138/am-2017-5897

Henry DJ, Novák M, Hawthorne FC, Ertl A, Dutrow BL, Uher P, Pezzotta F (2011) Nomenclature of the tourmaline-supergroup minerals. Amer Miner 96: 895-913
http://doi.org/10.2138/am.2011.3636

Konovalenko SI, Voloshin AV, Pakhomovskiy YA, Anen’yev SS, Perlina GA, Rogachev DL, Kuznetsov VY (1984) Tusionite MnSn(BO₃)₂ - a new borate from granitic pegmatites of the southwest Pamirs. Int Geol Rev 26: 481-485
http://doi.org/10.1080/00206818409466576

Kontak DJ, Clark AH (2002) Genesis of the Giant, Bonanza San Rafael Lode Tin Deposit, Peru: Origin and Significance of Pervasive Alteration. Econ Geol 97: 1741-1777
http://doi.org/10.2113/gsecongeo.97.8.1741

Konzett J, Krenn K, Hauzenberger C, Whitehouse M, Hoinkes G (2012) High-pressure tourmaline formation and fluid activity in Fe-Ti-rich eclogites from the Kreuzeck Mountains, Eastern Alps, Austria. J Petrol 53: 99-125
http://doi.org/10.1093/petrology/egr057

Kudryavtseva OE, Baksheev IA (2003) Compositional variations in tourmalines of the Berezovskoe gold deposit, Central Urals. Zap Ross Miner O-va 3: 108-125 (in Russian)

Kutzschbach M, Wunder B, Krstulovic M, Ertl A, Trumbull R, Rocholl A, Giester G (2017) First high-pressure synthesis of rossmanitic tourmaline and evidence for the incorporation of Li at the X site. Phys Chem Miner 44: 353-363
http://doi.org/10.1007/s00269-016-0863-0

Larson A.C., Von Dreele R.B. (1987) Generalized structure analysis system. LosAlamos National Laboratory Report LAUR: 86-748.

Lai Z, Peng F, Wang H, Yu H, Zhang S, Zhao H (2013) A new insight into regulating high energy facets of rutile TiO₂. J Mater Chem A 1: 4182-4185
http://doi.org/10.1039/c3ta00188a

Li Y, Huang Z, Liu Y, Fang M (2012) Characterization of dielectric performance of tourmaline single crystals from Yunnan, China. CrystEngComm 14: 7153-7156
http://doi.org/10.1039/c2ce25876e

London D (2011) Experimental synthesis and stability of tourmaline: a historical overview. Canad Miner 49: 117-136
http://doi.org/10.3749/canmin.49.1.117

London D, Ertl A, Hughes JM, Morgan VI GB, Fritz EA, Harms BS (2006) Synthetic Ag-rich tourmaline: structure and chemistry. Amer Miner 91: 680-684
http://doi.org/10.2138/am.2006.1959

Ma C, Rossman GR (2009) Tistarite, Ti₂O₃, a new refractory mineral from the Allende meteorite. Amer Miner 94: 841-844 https://doi.org/10.2138/am.2009.3203
http://doi.org/10.2138/am.2009.3203

Marschall H, Jiang S-Y (2011) Tourmaline isotopes: no element left behind. Elements 7: 313-319
http://doi.org/10.2113/gselements.7.5.313

Mirwald PW, Massonne H-J (1980) Quartz-coesite transition and the comparative friction measurements in piston-cylinder apparatus using talc-alsimag-glass (TAG) and NaCl high pressure cell: A discussion. Neu Jb Mineral, Mh 10: 469-477

Mlynarczyk M, Williams-Jones AE (2006) Zoned tourmaline associated with cassiterite: Implications for fluid evolution and tin mineralization in the San Rafael Sn-Cu deposit, southeastern Peru. Canad Mineral 44: 347-365
http://doi.org/10.2113/gscanmin.44.2.347

Nekrasov IY, Grigoriev AP, Grigorieva TA, Brovkin AA, Diman EN, Novgorodov IG, Suknev VS, Nikishova LV (1970) Study of high-temperature borates. Nauka. Moscow, pp 1-288

Novák M, Škoda R, Filip J, Macek I, Vaculovič T (2011) Compositional trends in tourmaline from intragranitic NYF pegmatites of the Třebíč pluton, Czech Republic: an electron microprobe, Mössbauer and LA-ICP-MS study. Canad Mineral 49: 359-380
http://doi.org/10.3749/canmin.49.1.359

Pertlik F, Ertl A, Körner W, Brandstätter F, Schuster R (2003) Na-rich dravite in the marbles from Friesach, Carinthia, Austria: Chemistry and crystal structure. Neu J Mineral, Mh 6:277-288
http://doi.org/10.1127/0028-3649/2003/2003-0277

Pushcharovsky DY, Zubkova NV, Setkova TV, Balitskii VS, Nekrasov AN, Nesterova VA (2020) (Ga,Ge)-analogue of tourmaline: crystal structure and composition. Crystallogr Rep 65: 849-856
http://doi.org/10.1134/S1063774520060279

Ramik RA, Organ RM, Mandarino JA (2003) On type romarchite and hydroromarchite from Boundary Falls, Ontario, and notes on other occurrences. Canad Mineral 41: 649-657
http://doi.org/10.2113/gscanmin.41.3.649

Rozhdestvenskaya IV, Setkova TV, Vereshchagin OS, Shtukenberg AG, Shapovalov YB (2012) Refinement of the crystal structures of synthetic nickel- and cobalt-bearing tourmalines. Crystallogr Rep 57: 57-63
http://doi.org/10.1134/S106377451106023X

Setkova TV, Balitsky VS, Shapovalov YB (2019) Experimental study of the stability and synthesis of the tourmaline supergroup minerals. Geochem Int 57: 1082-1094
http://doi.org/10.1134/S0016702919100094

Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A32: 751-767
http://doi.org/10.1107/S0567739476001551

Schilling F, Wunder B (2004) Temperature distribution in piston-cylinder assemblies: Numerical simulations and laboratory experiments. Eur J Mineral 16: 7-14
http://doi.org/10.1127/0935-1221/2004/0016-0007

Scribner ED, Groat LA, Cempírek J (2018) Mineralogy of Ti-bearing, Al-deficient tourmaline assemblages associated with lamprophyre dikes near the O’Grady Batholith, Northwest Territories, Canada. J Geosci 63 (2): 123-135
http://doi.org/10.3190/jgeosci.259

Slack JF, Ramsden AR, Griffin WL, Win TT, French DH, Ryan CG (1999) Trace elements in tourmaline from the Kidd Creek Massive Sulfide Deposit and Vicinity, Timmins, Ontario: a proton microprobe study. In: Hannington MD, Barrie CT (eds) The Giant Kidd Creek Volcanogenic Massive Sulfide Deposit, Western Abitibi Subprovince, Canada. Society of Economic Geologists, pp 415-430

Trumbull RB, Krienitz M-S, Gottesmann B, Wiedenbeck M (2008) Chemical and boron-isotope variations in tourmalines from an S-type granite and its source rocks: the Erongo granite and tourmalinites in the Damara Belt, Namibia. Contrib Mineral Petrol 155: 1-18
http://doi.org/10.1007/s00410-007-0227-3

van Hinsberg V, Schumacher J (2007) Intersector element partitioning in tourmaline: A potentially powerful single crystal thermometer. Contrib Mineral Petrol 153: 289-301
http://doi.org/10.1007/s00410-006-0147-7

Vezzoni, S, Biagioni C, D’Orazio M, Pieruccioni D, Galanti Y, Petrelli M., Molli G (2018) Evidence of Permian magmatism in the Alpi Apuane metamorphic complex (Northern Apennines, Italy): New hints for the geological evolution of the basement of the Adria plate. Lithos, 318-319, 104-123
http://doi.org/10.1016/j.lithos.2018.08.003

Vereshchagin OS, Rozhdesstvenskaya IV, Frank-Kamenetskaya OV, Zolotarev AA, Mashkovitsev RI (2013) Crystal chemistry of Cu-bearing tourmalines. Amer Miner 98: 1610-1616
http://doi.org/10.2138/am.2013.4408

Vereshchagin OS, Rozhdestvenskaya IV, Frank-Kamenetskaya OV, Zolotarev AA (2014) Ion substitutions and structural adjustment in Cr-bearing tourmalines. Eur J Mineral 26:309-321
http://doi.org/10.1127/0935-1221/2014/0026-2372

Vereshchagin OS, Frank-Kamenetskaya OV, Rozhdestvenskaya IV (2015) Crystal structure and stability of Ni-rich synthetic tourmaline. Distribution of divalent transition-metal cations over octahedral positions. Mineral Mag 79: 997-1006
http://doi.org/10.1180/minmag.2015.079.4.09

Vereshchagin OS, Frank-Kamenetskaya OV, Rozhdestvenskaya IV, Zolotarev AA (2018) Incorporation of 3d elements in tourmalines: structural adjustments and stability. Eur J Mineral 30: 917-928
http://doi.org/10.1127/ejm/2018/0030-2781

Vereshchagin OS, Wunder B, Britvin SN, Frank-Kamenetskaya OV, Wilke FDH, Vlasenko NS, Shilovskikh VV (2020) Synthesis and crystal structure of Pb-dominant tourmaline. Amer Miner 105: 1589-1592

Vereshchagin OS, Britvin SN, Wunder B, Frank-Kamenetskaya OV, Wilke FDH, Vlasenko NS, Shilovskikh VV, Bocharov VN, Danilov DV (2021) Ln³⁺ (Ln³⁺ = La, Nd, Eu, Yb) incorporation in synthetic tourmaline analogues: Towards tourmaline REE pattern explanation. Chem Geol 584: 120526 https://doi.org/10.1016/j.chemgeo.2021.120526
http://doi.org/10.1016/j.chemgeo.2021.120526

Vikent’eva OV, Bortnikov NS, Vikentyev IV, Groznova EO, Lyubimtseva NG, Murzin VV (2017) The Berezovsk giant intrusion-related gold-quartz deposit, Urals, Russia: Evidence for multiple magmatic and metamorphic fluid reservoirs. Ore Geol Rev 91: 837-863
http://doi.org/10.1016/j.oregeorev.2017.08.018

Warr LN (2021) IMA-CNMNC approved mineral symbols. Mineral Mag 85: 291-320
http://doi.org/10.1180/mgm.2021.43

Williamson BJ, Spratt J, Adams JT, Tindle AG, Stanely CJ (2000) Geochemical constraints from zoned hydrothermal tourmalines on fluid evolution and Sn mineralization: an example from fault breccias at Roche, SW England. J Petrol 41: 1439-1453
http://doi.org/10.1093/petrology/41.9.1439

Wunder B, Berryman E, Plessen B, Rhede D, Koch-Müller M, Heinrich W (2015) Synthetic and natural ammonium-bearing tourmaline. Amer Miner 100: 250-256
http://doi.org/10.2138/am-2015-5055

Xia M, Kang L (2022) Tourmaline with ultraviolet optical nonlinearity: Emergent material discovery from mineral. J Alloys Compd 892: 162235
http://doi.org/10.1016/j.jallcom.2021.162235

Žáček V, Petrov A, Hyršl J (1998) Chemistry and origin of povondraite-bearing rocks from Alto Chapare, Cochabamba, Bolivia. J Czec Geol Soc 43: 59-67

Žáček V, Fryda J, Petrov A, Hyršl J (2000) Tourmalines of the povondraite - (oxy)dravite series from the cap rock of meta-evaporite in Alto Chapare, Cochabamba, Bolivia. J Czech Geol Soc 45: 3-12
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Zachař A, Novák M, Škoda R (2020) Beryllium minerals as monitors of geochemical evolution from magmatic to hydrothermal stage; examples from NYF pegmatites of the Třebíč Pluton, Czech Republic. J Geosci 65: 153-172
http://doi.org/10.3190/jgeosci.307