Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original paper

Barbara Dutrow, Darrell Henry

Calcium-rich dravite from the Arignac Gypsum Mine, France: Implications for tourmaline development in a sulfate-rich, highly magnesian meta-evaporite

Journal of Geosciences, volume 67 (2022), issue 2, 191 - 207

DOI: http://doi.org/10.3190/jgeosci.352

Adlakha EE, Hattori K (2016) Paragenesis and composition of tourmaline types along the P2 Fault and McArthur River Uranium Deposit, Athabasca Basin, Canada. Canad Mineral 54: 661-679
http://doi.org/10.3749/canmin.1500057

Aleksandrov SM, Troneva MA (2006) Composition, mineral assemblages, and genesis of serendibite-bearing magnesian skarns. Geochem Int 44: 665-680
http://doi.org/10.1134/S0016702906070044

Almeida KMF, Jenkins DM (2019) A comparison between the stability fields of a Cl-rich scapolite and the end-member marialite. Amer Miner 104: 1788-1799
http://doi.org/10.2138/am-2019-6907

Arif M, Henry DJ, Moon CJ (2010) Cr-bearing tourmaline associated with emerald deposits from Swat, NW Pakistan: Genesis and its exploration signficance. Amer Miner 95: 799-809
http://doi.org/10.2138/am.2010.3349

Ayuso RA, Brown CE (1984) Manganese-rich red tourmaline from the Fowler Talc Belt, New-York. Canad Mineral 22: 327-331

Barbosa, CP, Falster, AU, Simmons, WB, Webber, KL, Nizamoff, J Gaines, RV (2000) Minerals of the Brumado magnesite deposits, Serra das Eguas, Bahia, Brazil. Rocks Miner 75: 32-39
http://doi.org/10.1080/00357520009602572

Bačík P, Méres S, Uher P (2011) Vanadium-bearing tourmaline in metacherts from Chvojnica, Slovak Republic: Crystal chemistry and multistage evolution. Canad Mineral 49: 195-206
http://doi.org/10.3749/canmin.49.1.195

Bačík P, Uher P, Cempírek J, Vaculovič T (2012) Magnesian tourmalines from plagioclase-muscovite-scapolite metaevaporite layers in dolomite marble near Prosetín (Olešnice Unit, Moravicum, Czech Republic). J Geosci 57: 143-153
http://doi.org/10.3190/jgeosci.120

Bačík P, Ozdín D, Uher, P, Chovan, M. (2022) Crystal chemistry and evolution of tourmaline in tourmaline-rich rocks from Zlatá Idka, Slovakia. J Geosci 67: XXX-XXX
http://doi.org/10.3190/jgeosci.350

Belley PM, Grice JD, Fayek M, Kowalski PM, Grew ES (2014) A new occurrence of the borosilicate serendibite in tourmaline-bearing calc-silicate rocks, Portage-du-Fort Marble, Grenville Province, Quebec; evolution of boron isotope and tourmaline compositions in a metamorphic context. Canad Mineral 52: 595-616
http://doi.org/10.3749/canmin.1400034

Benisek A, Kroll H, Cemic L (2004) New developments in two-feldspar thermometry. Amer Miner 89: 1496-1504
http://doi.org/10.2138/am-2004-1018

Benisek A, Dachs E, Kroll H (2010) A ternary feldspar-mixing model based on calorimetric data: development and application. Contrib Mineral Petrol 160: 327-337
http://doi.org/10.1007/s00410-009-0480-8

Berryman E, Wunder B, Wirth R, Rhede D, Schettler G, Franz G, Heinrich W (2015) An experimental study on K and Na incorporation in dravitic tourmaline and insight into the origin of diamondiferous tourmaline from the Kokchetav Massif, Kazakhstan. Contrib Mineral Petrol 169: 1-16
http://doi.org/10.1007/s00410-015-1116-9

Berryman EJ, Wunder B, Rhede D, Schettler G, Franz G, Heinrich W (2016) P-T-X controls on Ca and Na distribution between Mg-Al tourmaline and fluid. Contrib Mineral Petrol 171: 31
http://doi.org/10.1007/s00410-016-1246-8

Berryman EJ, Kutzschbach M, Trumbull RB, Meixner A, van Hinsberg V, Kasemann SA, Franz G (2017) Tourmaline as a petrogenetic indicator in the Pfitsch Formation, Western Tauern Window, Eastern Alps. Lithos 284-285: 138-155
http://doi.org/10.1016/j.lithos.2017.04.008

Bucher K, Grapes R (2011) Metamorphism of dolomites and limestones. In: Petrogenesis of Metamorphic Rocks, vol. Springer Berlin Heidelberg, Berlin, Heidelberg, pp 191-224
http://doi.org/10.1007/978-3-540-74169-5_6

Clerc C, Lahfid A, Monié P, Lagabrielle Y, Chopin C, Poujol M, Boulvais P, Ringenbach JC, Masini E, de St Blanquat M (2015) High-temperature metamorphism during extreme thinning of the continental crust: a reappraisal of the North Pyrenean passive paleomargin. Solid Earth 6: 643-668
http://doi.org/10.5194/se-6-643-2015

Dai Z, Kan At, Shi W, Zhang N, Zhang F, Yan F, Bhandari N, Zhang Z, Lui L, Ruan G, Tomson G (2017) Solubility measurements and predictions of gypsum, anhydrite and calcite over wide ranges of temperature, pressure and ionic strength with mixed electrolytes. Rock Mech Rock Eng 50: 327-339
http://doi.org/10.1007/s00603-016-1123-9

Descouens D (1984) Les Mines de gypse d’Arnave et Arignac. Monde et Minéraux 62:16-17

Dutrow BL, Henry DJ (2011) Tourmaline: A geologic DVD. Elements 7: 301-306
http://doi.org/10.2113/gselements.7.5.301

Dutrow BL, Henry DJ (2016) Fibrous tourmaline: A sensitive probe of fluid compositions and petrologic environments. Canad Mineral 54: 311-335
http://doi.org/10.3749/canmin.1600019

Dutrow BL, Henry DJ (2018) Tourmaline compositions and textures: reflections of the fluid phase. J Geosci 63: 99-110
http://doi.org/10.3190/jgeosci.256

Dutrow BL, Henry DJ (2021) Petrogenetic utility of magnesian tourmaline: extraordinary origin of everyday tourmaline. Natura 111: 29-30

Dutrow BL, Henry DJ, Sun Z (2019) Origin of corundum-tourmaline-phlogopite rocks from Badakhshan, northeastern Afghanistan: a new type of metasomatism associated with sapphire formation. Eur J Mineral 31: 739-753
http://doi.org/10.1127/ejm/2019/0031-2881

Golani PR, Pandit MK, Sial AN, Fallick AE, Ferreira VP, Roy AB (2002) B-Na rich Palaeoproterozoic Aravalli metasediments of evaporitic association, NW India: A new repository of gold mineralization. Precambrian Res 116: 183-198
http://doi.org/10.1016/S0301-9268(02)00020-7

Golberg JM, Leyreloup AF (1990) High temperature-low pressure Cretaceous metamorphism related to crustal thinning (Eastern North Pyrenean Zone, France). Contrib Mineral Petrol 104: 194-207
http://doi.org/10.1007/BF00306443

Hanor JS, McIntosh JC (2006) Are secular variations in seawater chemistry reflected in the compositions of basinal brines? J Geochem Explor 89: 153-156
http://doi.org/10.1016/j.gexplo.2005.11.054

Henry DJ, de Brodtkorb MK (2009) Mineral chemistry and chemical zoning in tourmalines, Pampa del Tamboreo, San Luis, Argentina. J South Amer Earth Sci 28: 132-141
http://doi.org/10.1016/j.jsames.2009.03.001

Henry DJ, Dutrow BL (1990) Ca substitution in Li-poor aluminous tourmaline. Canad Mineral 28: 111-124

Henry DJ, Dutrow BL (1996) Metamorphic tourmaline and its petrologic applications. In: Grew ES, Anovitz LM (eds) Boron: mineralogy, petrology and geochemistry. Rev Mineral Geochem 33: 503-557

Henry DJ, Dutrow BL (2001) Compositional zoning and element partitioning in nickeloan tourmaline from a metamorphosed karstbauxite from Samos, Greece. Amer Miner 86: 1130-1142
http://doi.org/10.2138/am-2001-1002

Henry DJ, Dutrow BL (2012) Tourmaline at diagenetic to low-grade metamorphic conditions: Its petrologic applicability. Lithos 154: 16-32
http://doi.org/10.1016/j.lithos.2012.08.013

Henry DJ, Dutrow BL (2018) Tourmaline studies through time: contributions to scientific advancements. J Geosci 63: 77-98
http://doi.org/10.3190/jgeosci.255

Henry DJ, Dutrow BL (2021) Tourmaline crystallography, crystal chemistry and nomenclature: current status. Natura 111: 47-48

Henry DJ, Guidotti CV (1985) Tourmaline as a petrogenetic indicator mineral: an example from the staurolite-grade metapelites of NW Maine. Amer Miner 70: 1-15

Henry DJ, Kirkland BL, Kirkland DW (1999) Sector-zoned tourmaline from the cap rock of a salt dome. Eur J Mineral 11: 263-280
http://doi.org/10.1127/ejm/11/2/0263

Henry DJ, Dutrow BL, Selverstone J (2002) Compositional polarity in replacement tourmaline - an example from the Tauern Window, eastern Alps. Geol Mater Res 4: 1-23 (abstract referenced in Amer Miner, 88, 1399)

Henry DJ, Sun H, Slack JF, Dutrow BL (2008) Tourmaline in meta-evaporites and highly magnesian rocks; perspectives from Namibian tourmalinites. Eur J Mineral 20: 889-904
http://doi.org/10.1127/0935-1221/2008/0020-1879

Henry DJ, Novák M, Hawthorne FC, Ertl A, Dutrow BL, Uher P, Pezzotta F (2011) Nomenclature of the tourmaline-supergroup minerals. Amer Miner 96: 895-913
http://doi.org/10.2138/am.2011.3636

Kosztolanyi C, Mullis J, Weidmann M (1987) Measurements of the phase transformation temperature of gypsum-anhydrite, included in quartz, by microthermometry and Raman microprobe techniques. Chem Geol 61: 19-28
http://doi.org/10.1016/0009-2541(87)90022-2

Lagabrielle Y, Labaume P, de Saint Blanquat M (2010) Mantle exhumation, crustal denudation, and gravity tectonics during Cretaceous rifting in the Pyrenean realm (SW Europe): Insights from the geological setting of the lherzolite bodies. Tectonics 29(4)
http://doi.org/10.1029/2009TC002588

Lagabrielle Y, Asti R, Duretz T, Clerc C, Fourcade S, Teixell A, Labaume P, Corre B, Saspiturry N (2020) A review of cretaceous smooth-slopes extensional basins along the Iberia-Eurasia plate boundary: How pre-rift salt controls the modes of continental rifting and mantle exhumation. Earth Sci Rev 201: 103071
http://doi.org/10.1016/j.earscirev.2019.103071

Lowenstein TK, Hardie LA, Timofeeff MN, Demicco RV (2003) Secular variation in seawater chemistry and the origin of calcium chloride basinal brines. Geol 31, 857-860
http://doi.org/10.1130/G19728R.1

Marger K, Luisier C, Baumgartner LP, Putlitz B, Dutrow BL, Bouvier A-S, Dini A (2019) Origin of Monte Rosa whiteschist from in-situ tourmaline and quartz oxygen isotope analysis by SIMS using new tourmaline reference materials. Amer Miner 104: 1503-1520
http://doi.org/10.2138/am-2019-7012

Mindat website. https://www.mindat.org/loc-67479.html (last accessed December 23, 2021)

Modreski PJ, Foord EE, Barbosa CP (1997) Crystal chemistry of uvite-dravite from the Brumado magnesite deposits, Bahia, Brazil. In: Tourmaline 1997 International Symposium on Tourmaline, Abstract Volume, 59-60

Moore JN, Christenson BW, Allis RG, Browne PRL, Lutz SJ (2004) The mineralogical consequences and behavior of descending acid-sulfate waters: An example from the Karaha-Telaga Bodas geothermal system, Indonesia. Canad Mineral 42: 1483-1499
http://doi.org/10.2113/gscanmin.42.5.1483

Pertlik F, Ertl A, Korner W, Brandstatter F, Schuster R (2003) Na-rich dravite in the marbles from Friesach, Carinthia, Austria: Chemistry and crystal structure. Neu Jb Mineral Mh: 277-288
http://doi.org/10.1127/0028-3649/2003/2003-0277

Pesquera A, Gil-Crespo PP, Torres-Ruiz F, Torres-Ruiz J, Roda-Robles E (2016) A multiple regression method for estimating Li in tourmaline from electron microprobe analyses. Mineral Mag 80: 1129-1133
http://doi.org/10.1180/minmag.2016.080.046a

Pilson MEQ (1998) An Introduction to the Chemistry of the Sea. Prentice Hall, pp 1-431

Putirka KD (2008) Thermometers and barometers for volcanic systems. Rev Mineral Geochem 69: 61-120
http://doi.org/10.2138/rmg.2008.69.3

Riehl, W, Cabral, A.R. (2018) Meta-evaporite in the Carajás mineral province, northern Brazil. Miner Depos 55: 895-902
http://doi.org/10.1007/s00126-018-0810-8

Schertl HP, Schreyer W, Chopin C (1991) The pyrope-coesite rocks and their country rocks at Parigi, Dora Maira Massif, Western Alps - Detailed petrography, mineral chemistry and PT path. Contrib Mineral Petrol 108: 1-21
http://doi.org/10.1007/BF00307322

Schreiber BC, Helman ML (2005) Criteria for distinguishing primary evaporite features from deformation features in sulfate evaporites. J Sediment Res 75: 525-533
http://doi.org/10.2110/jsr.2005.043

Schreyer W, Abraham K (1976) Three-stage metamorphic history of a whiteschist from Sar e Sang, Afghanistan, as part of a former evaporite deposit. Contrib Mineral Petrol 59: 111-130
http://doi.org/10.1007/BF00371302

Schreyer W, Abraham K, Kulke H (1980) Natural sodium phlogopite coexisting with potassium phlogopite and sodian aluminian talc in a metamorphic evaporite sequence from Derrag, Tell Atlas, Algeria. Contrib Mineral Petrol 74: 223-233
http://doi.org/10.1007/BF00371692

Slack JF, Herriman N, Barnes RG, Plimer, IR (1984) Stratiform tourmalinites in metamorphic terranes and their geologic significance. Geol 12, 713-716
http://doi.org/10.1130/0091-7613(1984)12<713:STIMTA>2.0.CO;2

Thiébaut J, Durand-Wackenheim C, Debeaux M, Souquet P (1992) Métamorphisme des évaporites triasiques du versant nord des Pyrénées centrales et occidentales. Bull Soc ’hist nat Toulouse 128: 77-84

Turekian, KK (1968) Oceans. Prentice-Hall, pp 1-120

Warren JK (2016) Meta-evaporites. In: Evaporites: A Geological Compendium. vol. Springer International Publishing, Cham, pp 1375-1468
http://doi.org/10.1007/978-3-319-13512-0_14

Uher P, Janak M, Ozdin D (2002) Calcian dravite from metacarbonate rocks of the Mutnik magnesite-talc deposit, Hnusta, Slovakia. Neu Jb Mineral Mh: 68-84
http://doi.org/10.1127/0028-3649/2002/2002-0068

van Hinsberg VJ, Schumacher JC (2009) The geothermobarometric potential of tourmaline, based on experimental and natural data. Amer Miner 94: 761-770
http://doi.org/10.2138/am.2009.3022

van Hinsberg VJ, Henry DJ, Dutrow BL (2011a) Tourmaline as a petrologic forensic mineral: A unique recorder of its geologic past. Elements 7: 327-332
http://doi.org/10.2113/gselements.7.5.327

van Hinsberg VJ, Henry DJ, Marschall HR (2011b) Tourmaline: An ideal indicator of its host environment. Canad Mineral 49: 1-16
http://doi.org/10.3749/canmin.49.1.1

van Hinsberg VJ, Franz G, Wood BJ (2017) Determining subduction-zone fluid composition using a tourmaline mineral probe. Geochem Perspect Lett 3: 160-169
http://doi.org/10.7185/geochemlet.1719

Vanko DA, Bishop FC (1982) Occurrence and origin of marialitic scapolite in the Humboldt Lopolith, NW Nevada. Contrib Mineral Petrol 81: 277-289
http://doi.org/10.1007/BF00371682

von Goerne G, Franz G, Heinrich W (2001) Synthesis of tourmaline solid solutions in the system Na₂O-MgO-Al₂O₃-SiO₂-B₂O₃-H₂O-HCl and the distribution of Na between tourmaline and fluid at 300 to 700 °C and 200 MPa. Contrib Mineral Petrol 141: 160-173
http://doi.org/10.1007/s004100100243

von Goerne G, Franz G, van Hinsberg VJ (2011) Experimental determination of Na-Ca distribution between tourmaline and fluid in the system CaO-Na₂O-MgO-Al₂O₃-SiO₂-B₂O₃-H₂O. Canad Mineral 49: 137-152
http://doi.org/10.3749/canmin.49.1.137

Yamamoto H, Kennedy GC (1969) Stability relations in the system CaSO₄-H₂O at high temperatures and pressures. Amer J Sci 267-A: 550-557