Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original paper

Pavol Myšľan, Martin Števko, Tomáš Mikuš

Mineralogy of metamorphic magnetite-manganese ores at the Prakovce - Zimná Voda prospect (Spišsko-gemerské rudohorie Mts., Slovakia): The occurrence of REE-bearing allanite-subgroup minerals ferriakasakaite and ferriallanite

Journal of Geosciences, volume 69 (2024), issue 4, 231 - 249

DOI: http://doi.org/10.3190/jgeosci.400



Anenburg M, Katzir Y, Rhede D, Jöns N, Bach W (2015) Rare earth element evolution and migration in plagiogranites: a record preserved in epidote and allanite of the Troodos ophiolite. Contrib Mineral Petr 169: 25
http://doi.org/10.1007/s00410-015-1114-y

Armbruster T, Bonazzi P, Akasaka M, Bermanec V, Chopin C, Gieré R, Heuss-Assbichler S, Liebscher A, Menchetti S, Pan Y, Pasero M (2006) Recommended nomenclature of epidote-group minerals. Eur J Mineral 18: 551-567
http://doi.org/10.1127/0935-1221/2006/0018-0551

Bajaník Š, Vozárová A, Hanzel V, Ivanička J, Mello J, Pristaš J, Reichwalder P, Snopko L, Vozár J (1983) Explanations to geological map of the Slovenské Rudohorie Mts.- Eastern part, 1 : 50 000. ŠGÚDŠ, Bratislava, pp 1-223 (in Slovak)

Bataleva YV, Kruk AN, Novoselov ID, Palyanov YN (2020) Formation of spessartine and CO2 via rhodochrosite decarbonation along a hot subduction P-T path. Minerals 10: 703
http://doi.org/10.3390/min10080703

Bethke PH, Barton PB (1971) Distribution of some minor elements between coexisting sulfide minerals. Econ Geol 66: 140-163
http://doi.org/10.2113/gsecongeo.66.1.140

Biagioni C, Bonazzi P, Pasero M, Zaccarini F, Balestra C, Bracco R, Cirriotti ME (2019) Manganiakasakaite-(La) and ferriakasakaite-(Ce), two new epidote supergroup minerals from Piedmont, Italy. Minerals 9: 353
http://doi.org/10.3390/min9060353

Bonazzi P, Holstam D, Bindi L, Nysten P, Capitani GC (2009) Multi-analytical approach to solve the puzzle of an allanite-subgroup mineral from Kesebol, Västra, Götaland, Sweden. Amer Miner 94: 121-134
http://doi.org/10.2138/am.2009.2998

Bosi F, Biagioni C, Pasero M. (2019) Nomenclature and classification of the spinel supergroup. Eur J Mineral 31: 183-192
http://doi.org/10.1127/ejm/2019/0031-2788

Chukanov NV, Zubkova NV, Schäfer C, Varlamov DA, Ermolaeva VN, Polekhovsky YS, Jančev S, Pekov IV, Pushcharovsky DY (2018) New data on ferriakasakaite-(La) and related minerals extending the compositional field of the epidote supergroup. Eur J Mineral 30: 323-332
http://doi.org/10.1127/ejm/2018/0030-2716

Dasgupta S (1997) P-T-X relationships during metamorphism of manganese-rich sediments: current status and future studies. In: Nicholson K, Hein JR, Buhn B, Dasgupta S (eds.) Manganese mineralization: geochemistry and mineralogy of terrestrial and marine deposits. GSL Spec Publ 119: 327-337
http://doi.org/10.1144/GSL.SP.1997.119.01.21

Faryad SW (1991) Metamorphosis of the sediments of the early Paleozoic of Gemericum Unit. Miner Slov 23: 315-324 (in Slovak)

Faryad SW (1994) Mineralogy of Mn-rich rocks from greenschist facies sequences of the Gemericum, West Carpathians, Slovakia. Neu Jb Mineral Mh 10: 464-480
http://doi.org/10.1127/njmm/1994/1994/464

Faryad W (1995) Determination of P-T conditions of metamorphism in the Spiš-Gemer Ore Mts. (Western Carpathians). Miner Slov 27: 9-19 (in Slovak)

Faryad SW, Klápová H, Nosál L (2010) Mechanism of formation of atoll garnet during high-pressure metamorphism. Mineral Mag 74: 111-126
http://doi.org/10.1180/minmag.2010.074.1.111

Geiger CA, Rossman GR (2020) Micro- and nano-size hydrogarnet clusters and proton ordering in calcium silicate garnet: Part I. The quest to understand the nature of “water” in garnet continues. Amer Miner 105, 455-467
http://doi.org/10.2138/am-2020-7256

Girtler D, Tropper P, Hauzenberger C (2013) Androsite-(Ce) and ferriandrosite-(Ce) as indicator for low low-grade REE-mobility in the Veitsch Mn deposit (Styria). Mitt Österr Mineral Gesell 159: 56

Giuntoli F, Lanari P, Engi M (2018) Deeply subducted continental fragments - Part 1: Fracturing, dissolution-precipitation, and diffusion processes recorded by garnet textures of the central Sesia Zone (western Italian Alps). Solid Earth 9: 167-189
http://doi.org/10.5194/se-9-167-2018

Grecula P (1982) Gemericum - a segment of the Paleotethys riftogenic pool. Miner Slov-monograph, Bratislava, pp 1-263 (in Slovak)

Grecula P, Dianiška I, Ďuďa R, Hurný J, Kobulský J, Kusák B, Malachovský P, Matula I, Rozložník O (1977) Geology, tectonics and metallogenesis of the eastern part of the Spišsko-gemerské rudohorie Mts., SGR - east, Cu + comprehensive evaluation. Geol priesk, Spišská Nová Ves, pp 1-390 (in Slovak)

Grecula P, Abonyi A, Abonyiová M, Antaš J, Bartalský B, Bartalský J, Dianiška I, Drzník E, Ďuďa R, Gargulák M, Gazdačko Ľ, Hudáček J, Kobulský J, Lörincz L, Macko J, Návesňák D, Németh Z, Novotný L, Radvanec M, Rojkovič I, Rozložník L, Rozložník O, Varček C, Zlocha J (1995) Mineral deposits of Slovak Ore Mountains. Miner Slov-monograph, pp 1-834 (in Slovak)

Grew ES, Locock AJ, Mills SJ, Galuskina IO, Galuskin EV, Hålenius U (2013) Nomenclature of the garnet supergroup. Amer Miner 98: 785-811
http://doi.org/10.2138/am.2013.4201

Hawthorne FC, Oberti R, Harlow GE, Maresch WV, Martin RF, Schumacher JC, Welch MD (2012) Nomenclature of the amphibole supergroup. Amer Miner 97: 2031-2048
http://doi.org/10.2138/am.2012.4276

Hein JR, Koschinsky A, Halbach P et al. (1997) Iron and Manganese Oxide Mineralization in the Pacific. In: Nicholson K, Hein JR, Buhn B et al. (eds.) Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. Geol Soc Spec Publ, 119: 123-138
http://doi.org/10.1144/GSL.SP.1997.119.01.09

Holtstam D, Andersson UB, Mansfeld J (2003) Ferriallanite-(Ce) from the Bastnäs deposit, Västmanland, Sweden. Canad Mineral 41: 1233-1240
http://doi.org/10.2113/gscanmin.41.5.1233

Hsu LC (1968) Selected phase relationships in the system Al-Mn-Fe-Si-O-H: a model for garnet equilibria. J Petrol 9: 40-83
http://doi.org/10.1093/petrology/9.1.40

Ilavský J (1957) Geology of ore deposits in Spišsko-gemerské rudohorie Mts. Geol Práce, Zoš 46: 51-59 (in Slovak)

Kantor J (1953a) Manganese deposit on Hekerová (Bystrý potok) west of Smolník. Manuscript, ŠGÚDŠ, Bratislava, pp 1-30 (in Slovak)

Kantor J (1953b) Manganese deposit near Čučma. Manuscript, ŠGÚDŠ, Bratislava, pp 1-32 (in Slovak)

Kantor J (1954) On the genesis of manganese ores in the Spišsko-gemerské rudohorie Mts. Geol Práce, Zpr 1: 70-71 (in Slovak)

Kartashov PM, Ferraris G, Ivaldi G, Sokolova E, McCammon CA (2002): Ferriallanite-(Ce) CaCeFe3+AlFe2+(SiO4)(Si2O7)O(OH), a new member of the edpidote group: description, X-ray and Mössbauer study. Canad Mineral 40:1641-1648
http://doi.org/10.2113/gscanmin.40.6.1641

Kasatkin AV, Zubkova NV, Pekov IV, Chukanov NV, Škoda R, Polekhovsky YS, Agakhanov AA, Belakovskiy DI, Kuznetsov AM, Britvin SN, Pushcharovsky DY (2020) The mineralogy of the historical Mochalin Log REE deposit, South Urals, Russia. Part I. New gatelite-group minerals ferriperbøeite-(La), (CaLa3)Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 and perbøeite-(LA), (CaLa3)(Al3Fe2+)[Si2O7][SiO4]3O(OH)2. Mineral Mag 84: 593-607
http://doi.org/10.1180/mgm.2020.42

Kolitsch U, Mills SJ, Miyawaki R, Blass G (2012) Ferriallanite-(La), a new member of the epidote supergroup from the Eifel, Germany. Eur J Mineral 24: 741-747
http://doi.org/10.1127/0935-1221/2012/0024-2210

Konrad-Schmolke M, O´Brien PJ, Heidelbach F (2007) Compositional re-equilibration of garnet: the importance of sub-grain boundaries. Eur J Mineral 19: 431-438
http://doi.org/10.1127/0935-1221/2007/0019-1749

Kuleshov V, Maynard JB (2017) Isotope Geochemistry: The origin and formation of manganese rocks and ores. Elsevier Science, pp 1-427

Leonhard G (1843) Concise dictionary of topographic mineralogy. Heidelberg Academy. Publishing act by J. C. B. Mohr, pp 1-593 (in German)

Mazzoli C, Vozárová A (1989) Further data concerning the pressure character of the Hercynian metamorphism in the West Carpathians (Czechoslovakia). Rc Soc Ital Mineral Petrol 43: 635-342

Melcher F (1995) Genesis of chemical sediments in Birimian greenstone belts: evidence from gondites and related manganese-bearing rocks from Northern Ghana. Mineral Mag 59: 229-251
http://doi.org/10.1180/minmag.1995.059.395.08

Myšľan P, Ružička P (2022) Micas and chlorites as indicators of metamorphic conditions of carbonate rocks of the Gelnica Group in the Souther Gemericum (Slovak Republic). Bull Mineral Petrol 30: 108-123 (in Slovak)
http://doi.org/10.46861/bmp.30.108

Myšľan P, Števko M, Mikuš T (2023) Mineralogy and genetic aspects of the metamorphosed manganese mineralization at the Július ore occurrence near Betliar (Gemeric Unit, Western Carpathians, Slovakia). J Geosci 68: 313-332

Myšľan P, Števko M, Mikuš T, Vrtiška L (2024) Mineralogy and genetic considerations of the metamorphosed As-rich manganese ore mineralization at the Diely occurrence near Poráč (Northern Gemeric Unit, Western Carpathians, Slovakia). Mineral Mag (in press)
http://doi.org/10.1180/mgm.2024.51

Nagashima M, Imaoka T, Nakashima K (2011) Crystal chemistry of Ti-rich ferriallanite-(Ce) from Cape Ashizuri, Shikoku Island, Japan. Amer Miner 96: 1870-1877
http://doi.org/10.2138/am.2011.3830

Nagashima M, Nishio-Hamane D, Tomita N, Minakawa T, Inaba S (2015) Ferriakasakaite-(La) and ferriandrosite-(La): new epidote-supergroup minerals from Ise, Mie Prefecture, Japan. Mineral Mag 79: 735-753
http://doi.org/10.1180/minmag.2015.079.3.16

Nyame FK (2001) Petrological significance of manganese carbonate inclusions in spessartine garnet and relation to the stability of spessartine in metamorphosed manganese-rich rocks. Contrib Mineral Petr 141: 733-746
http://doi.org/10.1007/s004100100257

Oberti R, Boiocchi M, Hawthorne FC, Ciriotti ME, Revheim O, Bracco R (2018) Clino-suenoite, a newly approved magnesium-iron-manganese amphibole from Valmalenco, Sondrio, Italy. Mineral Mag 82: 189-198
http://doi.org/10.1180/minmag.2017.081.034

Peterec D, Ďuďa R (2003) Rare minerals of Mn deposit near Čučma. Natur Carpath 44: 229-236 (in Slovak)

Putiš M, Sergeev S, Ondrejka M, Larionov A, Siman P, Spišiak J, Uher P, Paderin I (2008) Cambrian-Ordovician metaigneous rocks associated with Cadomian fragments in the West-Carpathian basement dated by SHRIMP on zircons: A record the Gondwana active margin setting. Geol Carpath 59: 3-18

Radvanec M, Gonda S (2020) Successive formation of Fe and Mn skarns in the Čučma locality (Gemeric unit, W. Carpathians): from metasomatic stage through the amphibolite facies overprint with Ti-rich tephroite to retrograde stilpnomelane-chlorite zone. Miner Slov 52: 103-132

Rojkovič I (1999) Manganese mineralization in the Wester Carpathians, Slovakia. Geol Carpath, Special Issue 50: 191-192

Rojkovič I (2001) Early Paleozoic Manganese ores in the Gemericum Superunit, Western Carpathians, Slovakia. Geolines 13: 34-41

Roy S (1981) Manganese deposits. Academic Press, London; New York, pp 1-458

Roy S (1992) Environments and Processes of Manganese Deposition. Econ Geol 87: 1218-1236
http://doi.org/10.2113/gsecongeo.87.5.1218

Ružička P, Bačík P, Myšľan P, Kurylo S (2020) Grossular and diopside in crystalline limestone from the locality Čučma - Čierna baňa (Slovak Republic). Bull Mineral Petrol 28: 94-104 (in Slovak)
http://doi.org/10.46861/bmp.28.094

Sassi R, Vozárová A (1987) The pressure character of the Hercynian metamorphism in the Gemericum (West Carpathians, Czechoslovakia). Rc Soc Ital Mineral Petrol 42: 73-81

Shchipalkina NV, Chukanov NV, Pekov IV, Aksenov SM, McCammon C, Belakovskiy D, Britvin SN, Koshlykova NN, Schäfer C, Scholz R, Rastsvetaeva RK (2017) Ferrorhodonite, CaMn3Fe[Si5O15], a new mineral species from Broken Hill, New South Wales, Australia. Phys Chem Miner 44: 323-334
http://doi.org/10.1007/s00269-016-0860-3

Shchipalkina NV, Pekov IV, Chukanov NV, Biagioni C, Pasero M (2019) Crystal chemistry and nomenclature of rhodonite-group minerals. Mineral Mag 83: 829-835
http://doi.org/10.1180/mgm.2019.65

Snopko L, Vozárová A (1981) Lithological and petrographic research of the Drnava Formation of the Gelnica Group. Západné Karpaty, Séria Mineralógia, petrografia, geochémia, metalogenéza 9: 111-144 (in Slovak)

Snopková P, Snopko L (1979) Biostratigraphy of the Gelnica series in the Spišsko-gemerské rudohorie Mts. based on palynological results (Western Carpathians, Paleozoic). Západné Karpaty, Sér geol 5: 57-102 (in Slovak)

Sobek K, Losos Z, Škoda Z, Holá M, Nasdala L (2023) Crystal chemistry of ferriallanite-(Ce) from Nya Bastnäs, Sweden: Chemical and spectroscopic study. Mineral Petrol 117: 345-357
http://doi.org/10.1007/s00710-023-00829-y

Spišiak J, Hovorka D (2000) Piemontite and spessartine in lower paleozoic metasediments of the inner Western Carpathians. Acta Mineral Petrogr 41: 102

Spišiak J, Hovorka D, Rybka R, Turan J (1989) Spessartine and piemontite in Lower Paleozoic metasediments of the Inner West Carpathians. Čas Mineral Geol 34: 17-30 (in Slovak)

Števko M, Plecháček J, Venclík V, Malíková R (2015) Hausmannite a manganosite from the Čučma-Či¬erna baňa manganese deposit (Slovak Republic). Bull Mineral Petrol 23: 39-42

Števko M, Myšľan P, Biagioni C, Mauro D, Mikuš T (2023) Ferriandrosite-(Ce), a new member of the epidote supergroup from Betliar, Slovakia. Mineral Mag 87: 887-895
http://doi.org/10.1180/mgm.2023.62

Theye T, Schreyer W, Fransolet A-M (1996) Low-temperature, low-pressure metamorphism of Mn-rich rocks in the Lienne Syncline, Venn-Stavelot Massif (Belgian Ardennes) and the role of carpholite. J Petrol 37: 767-783
http://doi.org/10.1093/petrology/37.4.767

Uher P, Broska I (1996) Post-orogenic Permian granitic rocks in the Western Carpathian-Pannonian area: Geochemistry, mineralogy and evolution. Geol Carpath 47: 311-321

Uher P, Ondrejka M, Bačík P, Broska I, Konečný P (2015) Britholite, monazite, REE carbonates, and calcite: Products of hydrothermal alteration of allanite and apatite in A-type granite from Stupné, Western Carpathians, Slovakia. Lithos 236-237: 212-225
http://doi.org/10.1016/j.lithos.2015.09.005

Varlamov DA, Ermolaeva VN, Chukanov NV, Jančev S, Vigasina MF, Plechov PYu (2019) New data on epidote-supergroup minerals: Unusual chemical composition, typochemistry, and Raman spectroscopy. Geol Ore Deposits 61: 827-842
http://doi.org/10.1134/S1075701519080130

Vlach SRF (2022) On the morphology and geochemistry of hydrothermal crypto-and microcrystalline zircon aggregates in a peralkaline granite. Minerals 12: 628
http://doi.org/10.3390/min12050628

Vozárová A, Rodionov N, Šarinová K, Presnyakov S (2017) New zircon ages on the Cambrian-Ordovician volcanism of the Southern Gemericum basement (Western Carparthians, Slovakia): SHRIMP dating, geochemistry and provenance. Int J Earth Sci 106: 2147-2170
http://doi.org/10.1007/s00531-016-1420-2

Warr LN (2021) IMA-CNMNC approved mineral symbols. Mineral Mag 85: 291-320
http://doi.org/10.1180/mgm.2021.43

Whitney DL, Mechum TA, Dilek Y, Kuehner SM (1996) Modification of garnet by fluid infiltration during regional metamorphism in garnet through sillimanite-zone rocks, Dutchess County, New York. Amer Miner 81: 696-705
http://doi.org/10.2138/am-1996-5-617

Zipser CA (1817) An attempt at a topographical-mineralogical handbook of Hungary. Carl Friedrich Wigand, Oedenburg, pp 1-440 (in German)

Journal of Geosciences, Published by © Czech Geological Society, with support from the Czech Geological Survey.
Webdesign inspired by aTeo. Hosted at the server of the Institute of Petrology and Structural Geology, Charles University, Prague.
ISSN: 1803-1943 (online), 1802-6222 (print)
email: jgeosci(at)jgeosci.org
cover_rotated.gif, 15kB

SNIP (Scopus, 2023): 0.6

IF (WoS, 2023): 1.1

5 YEAR IF (WoS, 2023): 1.5

Policy: Open Access

ISSN: 1802-6222

E-ISSN: 1803-1943