Journal of


  (Formerly Journal of the Czech Geological Society)

Original Paper

Sherif Kharbish

Raman spectra of minerals containing interconnected As(Sb)O3 pyramids: trippkeite and schafarzikite

Journal of Geosciences, volume 57 (2012), issue 1, 53 - 62


  Abstract References Affiliations

Beattie IR, Livingston KMS, Ozin GA, Reynolds DJ (1970) Single-crystal Raman spectra of arsenolite (As4O6) and senarmonite (Sb4O6). The gas-phase Raman spectra of P4O6, P4O10, and As4O6. J Chem Soc A: 449-451

Bahfenne S (2011) Single Crystal Raman Spectroscopy of Selected Arsenite, Antimonite and Hydroxyantimonite Minerals. Unpublished Ph.D. thesis, Queensland University of Technology, pp 1-159

Bahfenne S, Rintoul L, Frost, RL (2011) Single crystal Raman spectroscopy of natural schafarzikite FeSb2O4 from Pernek, Slovak Republic. Am Mineral 96: 888-894

Brumbach SB, Rosenblatt GM (1972) In-cavity laser Raman spectroscopy of vapors at elevated temperatures. As4 and As4O6. J Chem Phys 56: 3110-3118

Chater R, Gavarri JR, Genet F (1986) Composes isomorphes MeX2O4E2: I. Etude vibrationnelle de MnSb2O4 entre 4 et 300 K: champ de force et tenseur élastique. J Solid State Chem 63: 295-307

Cotton FA, Wilkinson G (1966) Advanced Inorganic Chemistry (6th edition). John Wiley & Sons, New Jersey, pp 1-1376

Eby RK, Hawthorne FC (1993) Structural relations in copper oxysalt minerals. I. Structural hierarchy. Acta Cryst B49: 28-56

Emmerling F, Röhr C (2003) Die neuen Oxoarsenate(III) AAsO2 (A = Na, K, Rb) und Cs3As5O9. Darstellung, Kristallstrukturen und Raman-Spektren. Z Naturforsch 58: 620-626

Fischer R, Pertlik F (1975) Verfeinerung der Kristallstruktur des Schafarzikits, FeSb2O4. Tschermaks Min Petr Mitt 22: 236-241

Flynn EJ, Solin SA, Papatheodorou GN (1976) Vibrational excitations of As2O3. II. Crystalline phases. Phys Rev B13: 1752-1758

Ghose S, Sen Gupta PK, Schlemper EO (1987) Leiteite, ZnAs2O4: a novel type of tetrahedral layer structure with arsenite chains. Am Mineral 72: 629-632

Gilliam SJ, Merrow CN, Kirkby SJ, Jensen JO, Zeroka D, Banerjeeb A (2003) Raman spectroscopy of arsenolite: crystalline cubic As4O6. J Solid State Chem 173: 54-58

Grzechnik A (1999) Compressibility and vibrational modes in solid As4O6. J Solid State Chem 144: 416-422

Hinrichsen B, Dinnebier RE, Rajiv P, Hanfland M, Grzechnik A, Jansen M (2006) Advances in data reduction of high-pressure X-ray powder diffraction data from two-dimensional detectors: a case study of schafarzikite (FeSb2O4). J Phys Condens Mat 18/25: S1021-S1037

Hirschle C, Röhr C (2000) Alkalimetall-Oxoantimonate: Synthesen, Kristallstrukturen und Schwingungsspektren von ASbO2 (A = K, Rb), A4Sb2O5 (A = K, Rb, Cs) und Cs3SbO4. Z Anorg Allg Chem 626: 1305-1312<1305::AID-ZAA

Jensen JO, Gilliam SJ, Banerjeeb A, Zeroka D, Kirkby SJ, Merrow, CN (2003) A theoretical study of As4O6: vibrational analysis, infrared and Raman spectra. J Mol Struct (Theochem) 664-665: 145-156

Kharbish S (2011) Raman spectroscopic investigations of some Tl-sulfosalt minerals containing pyramidal (As,Sb)S3 groups. Am Mineral 96: 609-616

Kharbish S, Libowitzky E, Beran A (2007) The effect of As-Sb substitution in the Raman spectra of tetrahedrite-tennantite and pyrargyrite-proustite solid solutions. Eur J Mineral 19: 567-574

Kharbish S, Libowitzky E, Beran A (2009) Raman spectra of isolated and interconnected pyramidal XS3 groups (X = Sb,Bi) in stibnite, bismuthinite, kermesite, stephanite and bournonite. Eur J Mineral 21: 325-333

Krenner JA (1921) Schafarzikite, ein neues Mineral. Z Kristallogr 56: 198-200

Lee C, Harrison WTA (2004) The catena-arsenite chain anion, [AsO2]n-n: (H3NCH2CH2NH3)0.5[AsO2] and NaAsO2. Acta Cryst C60: m215-m218

Loehr TM, Plane RA (1968) Raman spectra and structures of arsenious acid and arsenites in aqueous solution. Inorg Chem 7: 1708-1714

Lucovsky G, Galeener FL (1980) Local structure and vibrational spectra of vAs2O3. J Non-Cryst Solids 37: 53-70

Mellini M, Merlino S (1979) Versiliaite and apuanite: derivative structures related to schafarzikite. Am Mineral 64: 1235-1242

Nakamoto K (1997) Infrared and Raman spectra of Inorganic and Coordination Compounds. Part A: Theory and Applications in Inorganic Chemistry (6th edition). John Wiley & Sons, New Jersey, pp 1-419

Origlieri MJ, Downs RT, Pinch WW, Zito, GL (2009) Stibioclaudetite AsSbO3. A New Mineral from Tsumeb, Namibia. Mineral Rec 40: 209-213

Otwinowski Z, Minor W (1997) Processing of X-ray diffraction data collected in oscillation mode. In: Carter CW, Sweet RM (eds) Methods in Enzymology. Academic Press, New York, pp 307-326

Pertlik F (1975) Verfeinerung der Kristallstruktur von synthetischem Trippkeit, CuAs2O4. Tschermaks Min Petr Mitt 22: 221-217

Pertlik F (1988) The single chain arsenites Pb(AsO2)Cl and Pb2(AsO2)3Cl. Preparation and structure investigation. Z Kristallogr 184: 191-201

Sejkora J, Ozdín D, Vitáloš J, Tuček P, čejka J, Duďa R (2007) Schafarzikite from the type locality Pernek (Malé Karpaty Mountains, Slovak Republic). Eur J Mineral 19: 419-427

Wang A, Han J, Guo L, Yu J, Zeng P (1994) Database of standard Raman spectra of minerals and related inorganic crystals. Appl Spectrosc 48: 959-968

Zemann J (1951a) Formel und Kristallstruktur des Schafarzikits. Tschermaks Min Petr Mitt 2: 166-175

Zemann J (1951b) Formel und Kristallstruktur des Trippkeits. Tschermaks Min Petr Mitt 2: 417-423

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