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  (Formerly Journal of the Czech Geological Society)

Original Paper

Vladislav V. Gurzhiy, Olga V. Tyumentseva, Ilya V. Kornyakov, Sergey V. Krivovichev, Ivan G. Tananaev

The role of potassium atoms in the formation of uranyl selenates: the crystal structure and synthesis of two novel compounds

Journal of Geosciences, volume 59 (2014), issue 2, 123 - 133


Alekseev EV, Krivovichev SV, Depmeier W (2008) A crown ether as template for microporous and nanostructured uranium compounds. Angew Chem Int Ed 47: 549-551

Burns PC (2005) U6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. Canad Mineral 43: 1839-1894

Burns PC, Ewing RC, Hawthorne FC (1997) The crystal chemistry of hexavalent uranium: polyhedral geometries, bond-valence parameters, and polymerization of polyhedra. Canad Mineral 35: 1551-1570

Charykova MV, Krivovichev VG, Depmeier W (2010) Thermodynamics of arsenates, selenites, and sulfates in the oxidation zone of sulfide ores: I. Thermodynamic constants at ambient conditions. Geol of Ore Deposits 52: 689-700

Charykova MV, Krivovichev VG, Yakovenko OS, Semenova VV, Semenov KN, Depmeier W (2012) Thermodynamics of arsenates, selenites, and sulfates in the oxidation zone of sulfide ores: VI. Solubility of synthetic analogs of ahlfeldite and cobaltomenite at 25 °C. Geology of Ore Deposits 54: 638-646

Čejka J (1999) Infrared spectroscopy and thermal analysis of the uranyl minerals. In: Burns PC , Finch R (eds) Uranium: Mineralogy, Geochemistry and the Environment. Mineralogical Society of America and Geochemical Society Reviews in Mineralogy and Geochemistry 38: pp 521-620

Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H (2009) OLEX2: a complete structure solution, refinement and analysis program. J Appl Cryst 42: 339-341

Doran MB, Norquist AJ, Stuart SL, O’Hare D (2004) (C8H26N4)0.5[(UO2)2(SO4)3(H2O)]•2H2O, an organically templated uranyl sulfate with a novel layer type. Acta Cryst E60: m996-m998

Finch RJ, Buck EC, Finn PA, Bates JK (1999) Oxidative corrosion of spent UO2 fuel in vapour and dripping groundwater at 90 °C. In: Murakami T, Ewing RC (eds) Scientific Basis for Nuclear Waste Management. XXIIth Materials Research Society Symposium Proceeding. Materials Research Society, Warrendale, PA, Vol 556, pp 431-438

Gurzhiy VV, Bessonov AA, Krivovichev SV, Tananaev IG, Armbruster T, Myasoedov BF (2009) Crystal chemistry of selenates with mineral-like structures: VIII. Butlerite chains in the structure of K(UO2)(SeO4)(OH)(H2O). Geol of Ore Deposits 51: 833-837

Gurzhiy VV, Tyumentseva OS, Krivovichev SV, Tananaev IG, Myasoedov BF (2011) Synthesis and structural study of new potassium uranyl selenates K2(H5O2)(H3O)[(UO2)2(SeO4)4(H2O)2](H2O)4 and K3(H3O)[(UO2)2(SeO4)4(H2O)2](H2O)5. Radiochem 53: 569-575

Gurzhiy VV, Tyumentseva OS, Krivovichev SV, Tananaev IG, Myasoedov BF (2012) Synthesis and structural studies of a new potassium uranyl selenate K(H5O2)[(UO2)2(SeO4)3(H2O)] with strongly deformed layers. Radiochem 54: 43-47

Krivovichev SV (2004) Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two dimensional units with corner-sharing between coordination polyhedra. Crystallography Rev 10: 185-232

Krivovichev SV (2008) Structural Crystallography of Inorganic Oxysalts. Oxford University Press, Oxford, pp 1-308

Krivovichev SV (2010) Actinyl compounds with hexavalent elements (S, Cr, Se, Mo) - structural diversity, nanoscale chemistry, and cellular automata modeling. Eur J Inorg Chem 2010: 2594-2603

Krivovichev SV (2013) Crystal chemistry of uranium oxides and minerals. In: Reedijk J, Poeppelmeier K (eds) Comprehensive Inorganic Chemistry II, Vol 2. Elsevier, Amsterdam, pp 611-640

Krivovichev SV, Kahlenberg V (2005a) Crystal structure of (H3O)2[(UO2)2(SeO4)3(H2O)2](H 2O)3.5. Radiochem 47: 452-455

Krivovichev SV, Kahlenberg V (2005b) Structural diversity of sheets in rubidium uranyl oxoselenates: synthesis and crystal structures of Rb2[(UO2)(SeO4)2(H2O)](H2O), Rb2[(UO2)2(SeO4)3(H2O)2](H2O)4, Rb4[(UO2)3(SeO4)5(H2O)]. Z Anorg Allg Chem 631: 739-744

Krivovichev SV, Plášil J (2013) Mineralogy and crystallography of uranium. In: Burns PC, Sigmon GE (eds) Uranium: Cradle to Grave. Mineralogical Association of Canada Short Courses 43: pp 15-120

Krivovichev SV, Kahlenberg V, Kaindl R, Mersdorf E, Tananaev IG, Myasoedov BF (2005a) Nanoscale tubules in uranyl selenates. Angew Chem Int Ed 44: 1134-1136

Krivovichev SV, Kahlenberg V, Tananaev IG, Kaindl R, Mersdorf E, Myasoedov BF (2005b) Highly porous uranyl selenate nanotubules. J Am Chem Soc 127: 1072-1073

Krivovichev SV, Burns PC, Tananaev IG (2007) Structural Chemistry of Inorganic Actinide Compounds. Elsevier, Amsterdam, pp 1-494

Krivovichev SV, Gurzhiy VV, Tananaev IG, Myasoedov BF (2009) Uranyl selenates with organic templates: principles of structure and characteristics of self-organization. Rus J Gen Chem 79: 2723--730

Krivovichev VG, Charykova MV, Yakovenko OS, Depmeier W (2011a) Thermodynamics of arsenates, selenites, and sulfates in the oxidation zone of sulfide ores: IV. Eh-pH diagrams of the Me-Se-H2O systems (Me = Co, Ni, Fe, Cu, Zn, Pb) at 25 °C. Geol of Ore Deposits 53: 514-527

Krivovichev SV, Gurzhiy VV, Tananaev IG, Myasoedov BF (2011b) Nanoscale chemistry of uranyl selenates. In: Kalmykov SN, Denecke MA (eds) Actinide Nanoparticle Research. Springer-Verlag, Berlin, pp 247-275

Krivovichev VG, Tarasevich DA, Charykova MV, Britvin SN, Siidra OI, Depmeier W (2012) Thermodynamics of arsenates, selenites, and sulfates in the oxidation zone of sulfide ores: V. Chalcomenite and its synthetic analog properties and formation conditions. Geol of Ore Deposits 54: 498-502

Ling J, Sigmon GE, Ward M, Roback N, Burns PC (2010) Syntheses, structures, and IR characterization of new uranyl sulfate/selenate 1D-chain, 2D-sheet and 3D-framework. Z Kristallogr 225: 230-239

Nakamoto K (1997) Infrared and Raman Spectra of Inorganic and Coordination Compounds. John Wiley & Sons, New York, pp 1-387

Sheldrick GM (2007) SADABS, Universität Göttingen (Germany)

Sheldrick GM (2008) A short history of SHELX. Acta Cryst A64: 112-122

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