Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original paper

Sławomir Mederski, Marcin Wojsław, Stanislav Pršek, Juraj Majzlan, Stefan Kiefer, Burim Asllani

A geochemical study of gersdorffite from the Trepça Mineral Belt, Vardar Zone, Kosovo

Journal of Geosciences, volume 66 (2021), issue 2, 97 - 115

DOI: http://doi.org/10.3190/jgeosci.322



Ahmed AH, Arai S, Ikenne M (2009) Mineralogy and paragenesis of the Co-Ni arsenide ores of Bou Azzer, Anti-Atlas, Morocco. Econ Geol 104(2): 249-266
http://doi.org/10.2113/gsecongeo.104.2.249

Bal S, Pršek J, Mederski S, Asllani B, Wojnarowska A, Cieślak A (2019) Nickel mineralization in hydrothermally altered serpentinites (listwaenites) in the broad area of Stan Terg mine, Vardar Zone, Kosovo. Proceedings of the Life with Ore Deposits on Earth: 15th Biennial SGA Meeting, Glasgow, Scotland, August 27-30 2019; University of Glasgow Publicity Services: Glasgow, Scotland, 1: 384-387

Bayliss P (1969) X-ray data, optical anisotropism, and thermal stability of cobaltite, gersdorffite, and ullmannite. Mineral Mag 37(285): 26-33
http://doi.org/10.1180/minmag.1969.037.285.03

Bayliss P (1982) A further crystal structure refinement of gersdorffite. Amer Miner 67: 1058-1064

Bayliss P, Stephenson NC (1967) The crystal structure of gersdorffite. Mineral Mag 36(277): 38-42
http://doi.org/10.1180/minmag.1967.036.277.05

Bayliss P, Stephenson NC (1968) The crystal structure of gersdorffite (III), a distorted and disordered pyrite structure. Mineral Mag 36(283): 940-947
http://doi.org/10.1180/minmag.1968.283.036.04

Belkin HE, Luo K (2008) Late-stage sulfides and sulfarsenides in Lower Cambrian black shale (stone coal) from the Huangjiawan mine, Guizhou Province, People’s Republic of China. Mineral Petrol 92(3-4): 321-340

Borojevic Šoštarić SB, Palinkaš LA, Topa D, Spangenberg JE, Prochaska W (2011). Silver-base metal epithermal vein and listwaenite types of deposit Crnac, Rogozna Mts., Kosovo. Part I: Ore mineral geochemistry and sulfur isotope study. Ore Geol Rev 40(1): 65-80

Borojevic Šoštarić SB, Palinkaš LA, Neubauer F, Hurai V, Cvetković V, Roller-Lutz Z, Genser J (2013) Silver-base metal epithermal vein and listwanite hosted deposit Crnac, Rogozna Mts., Kosovo, part II: A link between magmatic rocks and epithermal mineralization. Ore Geol Rev 50: 98-117
http://doi.org/10.1016/j.oregeorev.2012.10.005

Cvetković V, Šarić K, Pécskay Z (2011) The Rudnik Mt. Volcanic and Metallogenetic Complex: an Example of Pb-Zn Tertiary Deposit in the Central Balkan Peninsula. Annual of the Yugoslav Association of Mineralogy 3: 135--138

Dangić A (1993) Tetriary lead-zinc ore deposits and calco-alcaline magmatism of the serbo-macedonian province: metallogenic and geochemical characteristics, hydrothermal systems and their evolution. Geol An Balk Poluostrva (Ann Geol Penins Balk) 57(1): 257-285

Elezaj Z (2009) Geodynamic evolution of Kosovo during the Triassic and Jurassic. J Earth Sci Application and Research Centre of Hacettepe University 30(2): 113-126

Emam A, Zoheir B (2013) Au and Cr mobilization through metasomatism: microchemical evidence from ore-bearing listvenite, South Eastern Desert of Egypt. J Geochem Explor 125: 34-45
http://doi.org/10.1016/j.gexplo.2012.11.004

Fanlo I, Subías I, Gervilla F, Paniagua A, García B (2004) The composition of Co-Ni-Fe sulfarsenides, diarsenides and triarsenides from the San Juan de Plan deposit, central Pyrenees, Spain. Canad Mineral 2004, 42(4), 1221-1240
http://doi.org/10.2113/gscanmin.42.4.1221

Fanlo I, Subías I, Gervilla F, Manuel J (2006) Textures and compositional variability in gersdorffite from the Crescencia Ni-(Co-U) showing, Central Pyrenees, Spain: primary deposition or re-equilibration? Canad Mineral 44(6): 1513-1528
http://doi.org/10.2113/gscanmin.44.6.1513

Féraud J, Deschamps Y (2009) French scientific cooperation 2007-2008 on the Trepça lead-zinc-silver mine and the gold potential of Novo Brdo/Artana tailings (Kosovo). Final Report, BRGM/RP-57204-FR, pp 1-102

Ferenc S, Uher P, Spisiak J, Simonova V (2016) Chromium-and nickel-rich micas and associated minerals in listvenite from the Muránska Zdychava, Slovakia: products of hydrothermal metasomatic transformation of ultrabasic rock. J Geosci 61(3): 239-254
http://doi.org/10.3190/jgeosci.217

Frenzel M, Hirsch T, Gutzmer J (2016) Gallium, germanium, indium, and other trace and minor elements in sphalerite as a function of deposit type - A meta-analysis. Ore Geol Rev 76: 52-78
http://doi.org/10.1016/j.oregeorev.2015.12.017

Gervilla F, Fanlo I, Colás V, Subías I (2012) Mineral compositions and phase relations of Ni-Co-Fe arsenide ores from the Aghbar mine, Bou Azzer, Morocco. Canad Mineral 50(2): 447-470
http://doi.org/10.3749/canmin.50.2.447

Grapes RH, Challis GA (1999) Gersdorffite with pentlandite, violarite, pyrrhotite, and pyrite, northwest Nelson, New Zealand. New Zealand J Geol Geophys 42(2): 189-204

Harms U (2010) Mineral chemistry of gersdorffite - A powerful tool in the differentiation of hydrothermal systems. Chem Erde 70(2): 175-184
http://doi.org/10.1016/j.chemer.2009.11.002

Hem SR, Makovicky E (2004a) The system Fe-Co-Ni-As-S. I. Phase relations in the (Fe,Co,Ni)As0.5S1.5 section at 650° and 500 °C. Canad Mineral 42(1): 43-62
http://doi.org/10.2113/gscanmin.42.1.43

Hem SR, Makovicky E (2004b) The system Fe-Co-Ni-As-S. II. Phase relations in the (Fe,Co,Ni)As1.5S0.5 section at 650° and 500°C. Canad Mineral 42(1): 63-86
http://doi.org/10.2113/gscanmin.42.1.63

Hyseni S, Durmishaj B, Fetahaj B, Large D (2010a) Trepça ore belt and lead and zinc distribution in Badovc mineral deposit, Kosovo (SE Europe). J Eng Appl Sci 5(8): 1-9

Hyseni S, Durmishaj B, Fetahaj B, Shala F, Berisha A, Large D (2010b) Trepça ore belt and stan terg mine - geological overview and interpretation, Kosovo (SE Europe). Geologija 53(1): 87-92
http://doi.org/10.5474/geologija.2010.006

Janković S, Zarić P (1980) Metallogenetic features of the antimony mineralization in the SE Kopaonik-Yugoslavia (Rajićeva Gora ore field). Trans Fac Min Geol 22: 43-56

Kiefer S, Majzlan J, Chovan M, Števko M (2017) Mineral compositions and phase relations of the complex sulfarsenides and arsenides from Dobšiná (Western Carpathians, Slovakia). Ore Geol Rev 89: 894-908
http://doi.org/10.1016/j.oregeorev.2017.07.026

Kissin SA (1992) Five-element (Ni-Co-As-Ag-Bi) veins. Geoscience Canada 19(3): 113-124

Klemm DD (1965) Synthesen und Analysen in den Dreiecksdiagrammen FeAsS-CoAsS-NiAsS und FeS2-CoS2-NiS2. Neu Jb Mineral, Abh 103: 205-255
http://doi.org/10.1127/njma/103/1965/205

Kołodziejczyk J, Pršek J, Melfos V, Voudouris PC, Maliqi F, Kozub-Budzyń G (2015) Bismuth minerals from the Stan Terg deposit (Trepça, Kosovo). Neu Jb Mineral, Abh 192(3): 317-333
http://doi.org/10.1127/njma/2015/0288

Kołodziejczyk J, Pršek J, Asllani B, Maliqi F (2016a) The paragenesis of silver minerals in the Pb-Zn Stan Terg deposit, Kosovo: an example of precious metal epithermal mineralization. Geol, Geophys Environ 42(1): 19-29
http://doi.org/10.7494/geol.2016.42.1.19

Kołodziejczyk J, Pršek J, Voudouris P, Melfos V, Asllani B (2016b) Sn-bearing minerals and associated sphalerite from lead-zinc deposits, Kosovo: An electron microprobe and LA-ICP-MS study. Minerals 6(2): 42
http://doi.org/10.3390/min6020042

Kołodziejczyk J, Pršek J, Voudouris PC, Melfos V (2017) Bi-sulphotellurides associated with Pb-Bi-(Sb±Ag, Cu, Fe) sulphosalts: an example from the Stan Terg deposit in Kosovo. Geol Carpath 68(4): 366-381 5
http://doi.org/10.1515/geoca-2017-0025

Kretschmar U, Scott SD (1976) Phase relations involving arsenopyrite in the system Fe-As-S and their application. Canad Mineral 14: 364-386

Markl G, Burisch M, Neumann U (2016). Natural fracking and the genesis of five-element veins. Miner Depos 51(6): 703-712
http://doi.org/10.1007/s00126-016-0662-z

Mederski S, Pršek J, Asllani B, Kozub-Budzyń G (2018) Bi-sulphosalts from the Mazhiq, Stan Terg area, Kosovo. 5th Central-European Mineralogical Conference and 7th Mineral Sciences in the Carpathians Conference, Banska Štiavnica, June 26-30, book of abstracts: 74

Mederski S, Pršek J, Hincyngier K (2019) Pb−Zn−Sb−Ni−Au mineralization from the Kizhnica area, central Kosovo: new data on the listwaenite type mineralization. Proceedings of the Life with Ore Deposits on Earth: 15th Biennial SGA Meeting, Glasgow, Scotland, August 27-30 2019; University of Glasgow Publicity Services: Glasgow, Scotland. 2: 834-837

Mikuš T, Chovan M, Ponomarenko O, Bondarenko S, Grinchenko O (2013) Hydrothermal nickel mineralization from the black shales in Čierna Lehota (Western Carpathians, Slovakia). Mineral J (Ukraine) 35(3): 27-32

Moroni M, Rossetti P, Naitza S, Magnani L, Ruggieri G, Aquino A, Oggiano G (2019) Factors Controlling Hydrothermal Nickel and Cobalt Mineralization - Some Suggestions from Historical Ore Deposits in Italy. Minerals 9(7): 429
http://doi.org/10.3390/min9070429

Qiu T, Zhu Y (2015) Geology and geochemistry of listwaenite-related gold mineralization in the Sayi gold deposit, Xinjiang, NW China. Ore Geol Rev 70: 61-79
http://doi.org/10.1016/j.oregeorev.2015.03.017

Radosavljević S, Stojanović J, Kašić V (2011) Mineralogical and chemical study of gold in polymetallic ore of the Lece mine -Medvedja. Proceedings of the International October Conference on Mining and Metallurgy 43, Kladovo, Serbia: 437-440

Radosavljević SA, Stojanović JN, Vuković NS, Radosavljević-Mihajlović AS, Kašić VD (2015) Low-temperature Ni-As-Sb-S mineralization of the Pb (Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships. Ore Geol Rev 65: 213-227
http://doi.org/10.1016/j.oregeorev.2014.09.029

Radosavljević SA, Stojanović JN, Radosavljević-Mihajlović AS, Vuković NS (2016) (Pb-Sb)-bearing sphalerite from the Čumavići polymetallic ore deposit, Podrinje Metallogenic District, East Bosnia and Herzegovina. Ore Geol Rev 72: 253-268
http://doi.org/10.1016/j.oregeorev.2015.07.008

Rezazadeh S, Hosseinzadeh MR, Raith JG, Moayyed M (2020). Mineral chemistry and phase relations of Co-Ni arsenides and sulfarsenides from the Baycheh-Bagh deposit, Zanjan province, Iran. Ore Geol Rev 127: 103836
http://doi.org/10.1016/j.oregeorev.2020.103836

Scharrer M, Kreissl S, Markl G (2019) The mineralogical variability of hydrothermal native element-arsenide (five-element) associations and the role of physicochemical and kinetic factors concerning sulfur and arsenic. Ore Geol Rev 113: 1-28
http://doi.org/10.1016/j.oregeorev.2019.103025

Serafimovski T, Stefanova V, Volkov AV (2010) Dwarf copper-gold porphyry deposits of the Buchim-Damjan-Borov Dol ore district, Republic of Macedonia (FYROM). Geol Ore Deposits 52(3): 179-195
http://doi.org/10.1134/S1075701510030013

Sharp ZD, Essene EJ, Kelly WC (1985) A re-examination of the arsenopyrite geobarometry: Pressure considerations and applications to natural assemblages. Canad Mineral 23: 517-534

Stajević B, Zarić P (1984) General characteristics of the ore paragenetic associations at Golija. In Proceeding of the II Symposium of the Yugoslav Association of Mineralogy, 251-260

Števko M, Sejkora J (2020) Sb-enriched association of Ni arsenides and sulfarsenides from the Zemberg-Terézia vein system near Dobšiná (Western Carpathians, Slovak Republic). Bull Mineral Petrolog 28: 105-115
http://doi.org/10.46861/bmp.28.105

Stojanović JN, Radosavljević SA, Tošović RD, Pačevski AM, Radosavljević-Mihajlović AS, Kašić VD, Vuković NS (2018) A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia. Geol An Balkan Poluostr 79(1): 47-69
http://doi.org/10.2298/GABP1879047S

Strmić Palinkaš S, Palinkaš LA, Renac C, Spangenberg JE, Lüders V, Molnar F, Maliqi G (2013) Metallogenic model of the Trepča Pb-Zn-Ag skarn deposit, Kosovo: evidence from fluid inclusions, rare earth elements, and stable isotope data. Econ Geol 108(1): 135-162
http://doi.org/10.2113/econgeo.108.1.135

Strmić Palinkaš S, Palinkaš L, Mandić M, Roller-Lutz Z, Pécskay Z, Maliqi G, Bermanec V (2016) Origin and K-Ar age of the phreatomagmatic breccia at the Trepča Pb-Zn-Ag skarn deposit, Kosovo: Implications for ore-forming processes. Geol Croatica 69(1): 121-142
http://doi.org/10.4154/GC.2016.10

Tombros S, St. Seymour K, Williams-Jones AE, Spry PG (2007) The genesis of epithermal Au-Ag-Te mineralization, Panormos Bay, Tinos Island, Cyclades, Greece. Econ Geol 102(7): 1269-1294
http://doi.org/10.2113/gsecongeo.102.7.1269

Vavelidis M, Melfos V (2004). Bi-Ag-bearing tetrahedrite-tennantite in the Kapsalina copper mineralisation, Thasos island, Northern Greece. N Jb Minerl, Abh 180(2): 149-170
http://doi.org/10.1127/0077-7757/2004/0180-0149

Voudouris P, Melfos V, Spry PG, Bonsall TA, Tarkian M, Solomos C (2008) Carbonate-replacement Pb-Zn-Ag±Au mineralization in the Kamariza area, Lavrion, Greece: Mineralogy and thermochemical conditions of formation. Mineral Petrol 94(1-2): 85
http://doi.org/10.1007/s00710-008-0007-4

Voudouris P, Mavrogonatos C, Rieck B, Kolitsch U, Spry PG, Scheffer C, Zaimis S (2018) The gersdorffite-bismuthinite-native gold association and the skarn-porphyry mineralization in the Kamariza mining district, Lavrion, Greece. Minerals 8(11): 531
http://doi.org/10.3390/min8110531

Watkinson DH, Heslop JB, Ewert WD (1975) Nickel sulphide-arsenide assemblages associated with uranium mineralization, Zimmer Lake area, northern Saskatchewan. Canad Mineral 13(2): 198-204

Węgrzynowicz J, Pršek J, Mederski S, Asllani B, Kwiecień K, Kanigowski J (2019) Pb−Bi(−Cu) and Pb−Sb sulfosalts from Stan Terg area, Kosovo. Proceedings of the Life with Ore Deposits on Earth: 15th Biennial SGA Meeting, Glasgow, Scotland, August 27-30 2019; University of Glasgow Publicity Services: Glasgow, Scotland 1, 380-383

Wojsław M, Pršek J, Mederski S, Asllani B, Kanigowski J (2019) Chemical characteristic of gersdorffite solid solutions in Stan Terg area, Kosovo. Proceedings of the Life with Ore Deposits on Earth: 15th Biennial SGA Meeting, Glasgow, Scotland, August 27-30 2019; University of Glasgow Publicity Services: Glasgow, Scotland 4, 1875-1878

Yund RA (1962) The system Ni-As-S; phase relations and mineralogical significance. Amer J Sci 260: 761-782
http://doi.org/10.2475/ajs.260.10.761

Journal of Geosciences, Published by © Czech Geological Society, with support from the Czech Geological Survey.
Webdesign inspired by aTeo. Hosted at the server of the Institute of Petrology and Structural Geology, Charles University, Prague.
ISSN: 1803-1943 (online), 1802-6222 (print)
email: jgeosci(at)jgeosci.org
cover_rotated.gif, 15kB

SNIP (Scopus, 2022): 0.826

IF (WoS, 2022): 1.4

5 YEAR IF (WoS, 2022): 1.8

Policy: Open Access

ISSN: 1802-6222

E-ISSN: 1803-1943