Journal of


  (Formerly Journal of the Czech Geological Society)

Original paper

Noemi Mészárosová, Roman Skála, Petr Mikysek, Milan Drábek

Miscibility between synthetic FeS and TiS: An insight into the phase relations in natural Ti-bearing iron monosulfides

Journal of Geosciences, volume 66 (2021), issue 4, 215 - 225


  Abstract References Affiliations

Alsen N (1925) Röentgenographische Untersuchungen der Kristallstrukturen von Magnetkies, Breithauptit, Pentlandit, Millerit und verwandten Verbindungen. Geol fören Stockholm förh 47:19-73

Barkov AY, Laajoki KVO, Men´shikov YP, Alapieti TT, Sivonen AJ (1997) First terrestrial occurrence of titanium-rich pyrrhotite, marcasite and pyrite in fenitized xenolith from the Khibina alkaline complex, Russia. Canad Mineral 35: 875-885

Barkov AY, Martin RF, Men´shikov YP, Savchenko YE, Thibaut Y, Laajoki KVO (2010) Edgarite, FeNb3S6, first natural niobium-rich sulfide from the Khibina alkaline complex, Russian far north: evidence for chalcophile behavior of Nb in a fenite. Contrib Mineral Petrol 138: 229-236

BRUKER AXS (2008) TOPAS V4: General profile and structure analysis software for powder diffraction data. User’s Manual, Bruker AXS, Karlsruhe, Germany

Buseck PR, Holdsworth EF (1972) Mineralogy and petrology of the Yilmia enstatite chondrite. Meteoritics 7: 429-447

de Villiers JPR, Liles DC and Becker M (2009) The crystal structure of naturally occurring 5C pyrrhotite from Sudbury, its chemistry, and vacancy distribution. Amer Miner 94: 1405-1410

de Villiers JPR and Liles DC (2010) The crystal-structure and vacancy distribution in 6C pyrrhotite. Amer Miner 95: 148-152

Evans HT (1970) Lunar troilite: Crystallography. Science 167: 73-92

Fleet ME (1982) Synthetic smythite and monoclinic Fe3S4. Phys Chem Miner 8: 241-246

Fogel RA (1997) On the significance of diopside and oldhamite in enstatite chondrites and aubrites. Meteorit Planet Sci 32: 577-591

Hahn H, Harder B (1957) Zur Kristallstruktur der Titansulfide. Z Anorg Allg Chem 288: 241-256

Harries D, Langenhorst F (2013) The nanoscale mineralogy of Fe,Ni sulfides in pristine and metamorphosed CM and CM/CI-like chondrites: Tapping a petrologic record. Meteorit Planet Sci 48: 879-903

Hochleitner R, Fehr KT, Simon G, Pohl J, Schmidbauer E (2004) Mineralogy of 57Fe Mössbauer spectroscopy of opaque phases in the Neuschwanstein EL6 chondrite. Meteorit Planet Sci 39: 1643-1648

Horstmann M (2013) The Almahata Sitta meteorites: Insights into the nature of selected chondritic and achondritic lithologies and possible genetic relations. PhD thesis, Westfälische Wilhelms-Universität Münster, Münster, Germany

Keil K (1968) Mineralogical and chemical relationships among enstatite chondrites. J Geophys Res 73: 6945-6976

Keil K (1969) Titanium distribution in enstatite chondrites and achondrites, and its bearing to their origin. Earth Planet Sci Lett 7: 243-248

Keil K (1989) Enstatite meteorites and their parent bodies. Meteoritics 24: 195-208

Keil K (2010) Enstatite achondrite meteorites (aubrites) and the histories of their asterodial parent bodies. Chem Erde 70: 295-317

Keil K, Brett R (1974) Heideite, (Fe,Cr)1+x(Ti,Fe)2S4, a new mineral in the Bustee enstatite achondrite. Amer Miner 59: 465-470

Kimura M, Weisberg MK, Lin Y, Suzuki A, Ohtani E, Okazaki R (2005) Thermal history of the enstatite chondrites from silica polymorphs. Meteorit Planet Sci 40: 855-868

Langenhorst F, Harries D, Pollok K (2013) Non-stochiometry, defects and superstructures in sulfide and oxide minerals. In: Nieto F, Livi KJT (eds) Minerals at nanoscale. EMU Notes in Mineralogy 14, London, pp 261-295

Lin Y, Kimura M (1998) Petrographic and mineralogical study of new EH melt rock and a new enstatite chondrite grouplet. Meteorit Planet Sci 33: 501-511

Makovicky E (2006) Crystal structure of sulfides and other chalcogenides. In: Vaughan DJ (ed) Sulfide mineralogy and geochemistry. Rev Mineral Geochem 61, Washington DC, pp 7-125

McCoy TJ (1998) A pyroxene¬ oldhamite clast in Bustee: Igneous aubritic oldhamite and mechanism for Ti enrichment in aubritic troilite. Antarct Meteorite Res 11: 32-48

Mitsui H, Sasaki T, Oikawa K, Ishida K (2009) Phase equilibra in FeS-XS and MnS-XS (X=Ti, Nb and V) systems. J Iron Steel Inst Jpn 49: 936-941

Nagahara H, El Goresy A (1984) Yamato 74370: A new enstatite chondrite (EH4) (abstr.) 15th Lunar and Planetary Science Conference pp 583

Nakajima S, Horiuchi H, Morimoto N (1972) Crystal structures of (Fe,Ti)3S4 (abstr.). Acta Crystallogr A28: pp 61

Nakamura-Messenger K, Clemett SJ, Rubin AE, Choi B-G, Zhang S, Rahman Z, Oikawa K, Keller LP (2012) Wassonite: A new titanium monosulfide mineral in the Yamato 691 enstatite chondrite. Amer Miner 97: 807-812

Nakano A, Tokonami M, Morimoto N (1979) Refinement of 3C Pyrrhotite, Fe7S8. Acta Crystallogr B35: 722-724

Nehru CE, Prinz M, Weisberg MK, Delaney JS (1984) Parsa: An unequilibrated enstatite chondrite (uec) with an aubrite like impact melt clast (abstr.) 15th Lunar and Planetary Science Conference pp 597

Olsen EJ, Bunch TE, Jarosewich E, Noonan AF, Huss GI (1977) Happy Canyon: a new type of estatite achondrite. Meteoritics 12: 109-123

Ondruš P, Skála R (1997) New quasi-empirical channel Search/Match algorithm for ICDD PDF2 Database: A tool for qualitative X-ray powder diffraction analysis. EPDIC-5, Parma: pp 193

Powell AV, Vaqueiro P, Knight KS, Chapon C, Sánchez RD (2004) Structure and magnetism in synthetic pyrrhotite Fe7S8: A powder neutron-diffraction study. Phys Rev B 70: 014415-12

Rambaldi ER, Housley RM, Rajan RS, Cirlin E, El Goresy A, Wang D (1983) Unusual mineral assemblages and textures in Qingzhen enstatite chondrites. Meteoritics 18: 380-381

Rubin AE, Ma C (2017) Meteoritic minerals and their origins. Chem Erde 77: 325-385

Rubin AE, Wasson JT (2011) Shock effects in “EH6” enstatite chondrites and implications for collisional heating of the EH and EL parent asteroids. Geochim Cosmochim Acta 75: 3757-3780

Schrader DL, Davidson J, McCoy TJ, Zega TJ, Russel SS, Domanik KJ, King AJ (2021) The Fe/S ratio of pyrrhotite group sulfides in chondrites: An indicator of oxidation and implications for return samples from asteroids Ryugu and Bennu. Geochim Cosmochim Acta 303: 66-91

Skála R, Drábek M (2005) Influence of titanium content on crystal structure of iron monosulfide (abstr.). 68th Annual Meeting of the Meteoritical Society, Meteorit Planet Sci 40: A143-A143

Skála R, Císarová I, Drábek M (2006) Inversion twinning in troilite. Amer Miner 91: 917-921

Thompson P, Cox DE, Hastings JB (1987) Rietveld refinement of Debye-Scherrer synchrotron X-ray data from Al2O3. J Appl Crystallogr 20:79-83.

Töpel-Schadt J, Müller WF (1982) Transmission electron microscopy on meteoritic troilite. Phys Chem Miner 8: 175-179

Vieane W, Kullerud G (1971) The Ti-S and Fe-Ti-S systems. Carnegie Inst Wash 70: 297-299

Watters TR, Prinz M (1979) Aubrites: their origin and relationships to enstatite chondrites. Proc Lunar Planet Sci Con 10: 1073-1093

Weisberg MK, Fogel RA, Prinz M (1997) QUE 94204: An EH chondritic melt rock (abstr. #1768) 28th Lunar and Planetary Science Conference: CD-ROM

Weyrauch M, Horstmann M, Bischoff A (2018) Chemical variations of sulfides and metal in enstatite chondrites-Introduction of a new classification scheme. Meteorit Planet Sci 53: 394-415

Yakovleva OS, Pekov IV, Bryzgalov IA, Men´shikov YP (2010) Chalcogenide mineralization in the alumina-rich fenites of the Khibiny alkaline complex (Kola Peninsula, Russia). New Data on Minerals 5: 33-49

Zhang Y, Benoit PH, Sears DW (1995) The classification and complex thermal history of the enstatite chondrites. J Geophys Res 100: 9417-9438

Journal of Geosciences, Published by © Czech Geological Society, with support from the Czech Geological Survey.
Webdesign inspired by aTeo. Hosted at the server of the Institute of Petrology and Structural Geology, Charles University, Prague.
ISSN: 1803-1943 (online), 1802-6222 (print)
email: jgeosci(at)
cover_rotated.gif, 15kB

SNIP (Scopus, 2022): 0.826

IF (WoS, 2022): 1.4

5 YEAR IF (WoS, 2022): 1.8

Policy: Open Access

ISSN: 1802-6222

E-ISSN: 1803-1943