Journal of

GEOsciences

  (Formerly Journal of the Czech Geological Society)

Original Paper

Vladimír Žáček, Radek Škoda, František Laufek, Jiří Sejkora, Jakub Haifler

Pertoldite, trigonal GeO₂, the germanium analog of α-quartz: a new mineral from Radvanice, Czech Republic

Journal of Geosciences, volume 67 (2022), issue 3, 243 - 251

DOI: http://doi.org/10.3190/jgeosci.355

Balitsky DV, Balitsky VS, Pisarevsky YV, Philippot E, Silvestrova OY and Pushcharovsky DY (2001) Growth of germanium dioxide single crystals with α-quartz structure and investigation of their crystal structure, optical, elastic, piezoelectric, dielectric and mechanical properties. Ann Chim-Sci Mat 26(1): 183-192
http://doi.org/10.1016/S0151-9107(01)90034-0

Balitsky VS, Balitsky DV, Nekrasov AN, Balitskaya LV (2005) Growth and characterization of Si_xGe_1-xO solid solution single crystals with quartz structure. J Cryst Growth 275(1-2): e807-e811
http://doi.org/10.1016/j.jcrysgro.2004.11.118

Bernstein L R (1985) Germanium geochemistry and mineralogy. Geochim Cosmochim Acta 49(11): 2409-2422
http://doi.org/10.1016/0016-7037(85)90241-8

Bouška V (1981) Coal Science and Technology 1, Geochemistry of Coal. Elsevier, Amsterdam, pp 1-284

Breiter K, Gardenová N, Kanický V, Vaculovič T (2013) Gallium and germanium geochemistry during magmatic fractionation and post-magmatic alteration in different types of granitoids: A case study from the Bohemian Massif (Czech Republic). Geol Carpath 64(3), 171
http://doi.org/10.2478/geoca-2013-0018

Bruker AXS (2014) Topas 5, computing program, Bruker AXS GmbH, Karlsruhe, Germany

Čadková Z (1971) The metal distribution in sediments of the Radvanice measures. Čas Mineral Geol 16(2): 147-157 (in Czech)

Čurda M, Goliáš V, Klementová M, Strnad L, Matěj Z, Škoda R (2017) Radiation damage in sulfides: Radioactive galena from burning heaps, after coal mining in the Lower Silesian basin (Czech Republic). Amer Miner 102(9): 1788-1795
http://doi.org/10.2138/am-2017-6036

Dubanský A, Absolon K, Dvořáček (1988) Selenium from burning dumps of the Stachanov mine. Geol Průzk 3: 308-309 (in Czech)

Dubanský A, Langrová A, Dvořáček P, Čejka J, Kouřimský J (1991) Pyrometamorphic minerals from the Kateřina mine. Geol Průzk 6: 172-173 (in Czech)

Dultz W, Quilichini M, Scott JF, Lehmann G (1975) Phonon spectra of quartz isomorphs. Phys Rev B 11(4): 1648
http://doi.org/10.1103/PhysRevB.11.1648

Gillet P, Le Cléac’h A, Madon M (1990) High-Temperature Raman spectroscopy of SiO₂ and GeO2 Polymorphs: Anharmonicity and thermodynamic properties at high-temperatures. J Geophys Res B: Solid Earth 95(B13), 21635-21655
http://doi.org/10.1029/JB095iB13p21635

Glinnemann J, King HE, Schulz H, Hahn T, la Placa SJ, Dacol F (1992) Crystal structures of the low-temperature quartz-type phases of SiO₂ and GeO₂ at elevated pressure. Z Kristallogr 198: 177-212
http://doi.org/10.1524/zkri.1992.198.3-4.177

Haines J, Cambon O, Philippot E, Chapon L, Hull S (2002) A Neutron Diffraction Study of the Thermal Stability of the α-Quartz-Type Structure in Germanium Dioxide. J Solid State Chem 166: 434-441
http://doi.org/10.1006/jssc.2002.9625

Höll R, Kling M, Schroll E (2007) Metallogenesis of germanium - A review. Ore Geol Rev 30 (3-4): 145-180
http://doi.org/10.1016/j.oregeorev.2005.07.034

Johan Z, Oudin E, Picot P (1983) Analogues germaniféres et galliféresdes silicates et oxydes dans les gisements de zinc des Pyrénees centrales, France; argutite et carboirite, deux nouvelles espéces minérales. Tschermaks mineral petrogr Mitt 31: 97-119
http://doi.org/10.1007/BF01084764

Jorensen JD (1978) Compression mechanisms in α-quartz structures - SiO₂ and GeO₂. J Appl Phys 49: 5473-8
http://doi.org/10.1063/1.324517

Kraus W, Nolze G (1996) POWDER CELL - a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns. J Appl Crystallogr 29: 301-303
http://doi.org/10.1107/S0021889895014920

Kruszewski Ł (2018a) Geochemical Behavior of Trace Elements in the Upper and Lower Silesian Basin Coal-Fire Gob Piles of Poland. Chapter 19. In: Stracher GB, Prakash A, Sokol EV (Eds) Coal and Peat Fires: A Global Perspective, Volume 5 Case Studies-Advances in Field and Laboratory Research. Elsevier, Amsterdam, pp 107-449

Kruszewski Ł, Fabiańska MJ, Ciesielczuk J, Segit T, Orłowski R, Motyliński R, Kusy D, Moszumańska I (2018b) First multi-tool exploration of a gas-condensate-pyrolysate system from the environment of burning coal mine heaps: An in situ FTIR and laboratory GC and PXRD study based on Upper Silesian materials. Sci Total Environ 640-641: 1044-1071
http://doi.org/10.1016/j.scitotenv.2018.05.319

Kruszewski Ł, Fabiańska MJ, Segit T, Kusy D, Motyliński R, Ciesielczuk J, Deput E (2020) First multi-tool exploration of a gas-condensate-pyrolysate system from the environment of burning coal mine heaps: An in situ FTIR and laboratory GC and PXRD study based on Upper Silesian materials. Sci Total Environ 698: 134274
http://doi.org/10.1016/j.scitotenv.2019.134274

Kudělásek V (1959a) Trace elements of coal of the Intra-Sudetic Basin. Part I. Sbor věd Prací Vys Šk báň (Ostrava), Ř horn-geol 5(3): 319-347 (in Czech)

Kudělásek V (1959b) Trace elements of coal of the Intra-Sudetic Basin. Part II. Sbor věd Prací Vys Šk báň (Ostrava), Ř horn-geol 5(4): 457-479 (in Czech)

Laufek F, Veselovský F, Drábek M, Kříbek B, Klementová M (2017) Experimental formation of Pb, Sn, Ge and Sb sulfides, selenides and chlorides in the presence of sal ammoniac: A contribution to the understanding of the mineral formation processes in coal wastes self-ignition. Int J Coal Geol 176-177: 1-7
http://doi.org/10.1016/j.coal.2017.04.008

Lewis RJ Sr., ed (1993) Hawley’s Condensed Chemical Dictionary. 12th ed. New York, NY: Van Nostrand Rheinhold Co

Merlet C (1994) An Accurate Computer Correction Program for Quantitative Electron Probe Microanalysis. Microchim Acta 114/115: 363-376
http://doi.org/10.1007/BF01244563

Micoulaut M, Cormier L, Henderson GS (2006) The structure of amorphous, crystalline and liquid GeO₂. J Phys: Condens Matter 18 (45): R753-R784
http://doi.org/10.1088/0953-8984/18/45/R01

Miyawaki R, Hatert F, Pasero M, Mills SJ (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC), NEWSLETTER 50 New minerals and nomenclature modifications approved in 2019. Mineral Mag 83: 615-620
http://doi.org/10.1180/mgm.2019.46

Nickel EH, Grice JD (1998) The IMA Commission on New Minerals and Mineral Names: procedures and guidelines on mineral nomenclature. Mineral Petrol 64(1-4): 237-263

Pešek J, Sýkorová I, Jelínek E, Michna O, Forstová J, Martínek K, Vašíček M, Havelcová M (2010): Major and minor elements in the hard coal from the Czech Upper Paleozoic basins. Czech Geol Surv Spec Pap 10: 1-48

Rietveld HM (1967) Line profiles of neutron powder-diffraction peaks for structure refinement. Acta Crystallogr 22: 151-152
http://doi.org/10.1107/S0365110X67000234

Scott JF (1970) Raman Spectra of GeO2. Phys Rev B 1(8): 3488-3493
http://doi.org/10.1103/PhysRevB.1.3488

Sejkora J, Makovicky E, Balić-Zunić T, Berlepsch P (2020) Stangersite, a new tin germanium sulfide, from the Kateřina mine, Radvanice near Trutnov, Czech Republic. J Geosci 65(3): 141-152
http://doi.org/10.3190/jgeosci.306

Sejkora J, Žáček V, Škoda R, Laufek F, Dolníček Z (2022): Radvaniceite, GeS₂, a New Germanium Sulphide, from the Kateřina Mine, Radvanice near Trutnov, Czech Republic. Minerals 12: 222
http://doi.org/10.3390/min12020222

Seredin VV, Finkelman RB (2008): Metaliferous coals: A review of the main genetic and geochemical types. Int J Coal Geol 76,4: 253-289

Smith GS, Isaacs PB (1964) The crystal structure of quartz-like GeO₂. Acta Crystallogr 17: 842-846
http://doi.org/10.1107/S0365110X64002262

Tásler R, Čadková Z, Dvořák J, Fediuk F, Chaloupský J, Jetel J, Kaiserová-Kalibová M, Prouza V, Schovánková-Hrdličková D, Středa J, Střída M, Šetlík J (1979) Geology of Czech part of the Intrasudetic Basin. Academia, Praha, pp 1-292 (in Czech)

Weast RC, ed (1979) Handbook of Chemistry and Physics. 60th ed. Boca Raton, Florida: CRC Press Inc

Winkler C (1887) Mittheilungen über des Germanium. Zweite Abhandlung. J Prakt Chem 36(1): 177-209
http://doi.org/10.1002/prac.18870360119

Yamanaka Y, Ogata K (1991) Structure Refinement of GeO2 Polymorphs at High Pressures and Temperatures by Energy-Dispersive Spectra of Powder Diffraction. J Appl Crystallogr 24: 111-118
http://doi.org/10.1107/S0021889890011153

Žáček V, Ondruš P (1997a) Mineralogy of recently formed sublimates from Kateřina colliery in Radvanice, Eastern Bohemia, Czech Republic. Bull Czech Geol Surv 72(3): 289-302

Žáček V, Ondruš P (1997b) Naturally occurring germanium compounds, GeSnS₃ and GeO₂ from Radvanice, Eastern Bohemia. Bull Czech Geol Surv 72(2): 189-191

Žáček V, Skála R (2015) Mineralogy of Burning-Coal Waste Piles in Collieries of the Czech Republic. In: Stracher GB, Prakash A, Sokol EV Coal and Peat Fires: A Global Perspective, Volume 3 Case Studies-Coal Fires. Elsevier, Amsterdam, pp 109-159

Žáček V, Škoda R, Laufek F, Sejkora J, Haifler J (2021) Pertoldite, IMA 2021-074. CNMNC Newsletter 64. Eur J Mineral 33, 139-143.